Reaction of Aldehydes and ketones

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[@Afripol]

Aldehydes and ketones undergo a variety of reactions that lead to many different products. The most common reactions are nucleophilic addition reactions, which lead to the formation of alcohols, alkenes, diols, cyanohydrins (RCH(OH)C&tbond;N), and imines R 2C&dbond;NR), to mention a few representative examples.

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Miss please do exercise solutions on this chapter

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[@Alex-sq7il]

Acyl chlorides do react with NaBH4! They undergo 2 succesive reactions with NaBH4.
(Source: Organic Chemistry P.Y Bruice 7th edition)

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[@hanajb8317]

thank you ... sorry but i have a quick question :
in the last example you reacted ketone with ( CH3Li ) not with (CH3MgLi ) my question is does it the same i mean it doesn't matter if i react ketone with grignard or with alkyl-Li ?
:)

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[@karrinagesu8802]

Thank you but aldehydes react with griganard to get primary alcohols .ketones react with griganard to get

[@Dennis-io1ku]

Karri Nagesu the only grignard to get a primary alkohol is with formaldehyd, if you use another aldehyd youll get a secondary alk. and if you use a keton youll get a tertriary alk.

[@huzafah]

what happened to the hydrogen in example 3 ?
at 5:52

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[@jorgelasprilla1568]

In the minute 9:56 you obtain OH? Or is H2O

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[@1man1sam]

Is CH3Li (last example) considered as a hydride reagent. Does it work like LiAlH4? Thank you by the way! Very clear

[@kumudtyagi1518]

Samuel Swanzy no. it works just like grignard's reagent. the oh- obtained from hydroysis will combine with lithium.

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[@apoorvtyagi7441]

Will not there be rearrangement in the second example and the hydroxide will attach to the benzene ring?

[@Imubozuu]

There is no carbocation formation thus there won't be rearrangement.
-in any case it would remove the aromaticity of the benzene making it less stable -hypothetically speaking

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[@apoorvtyagi7441]

What will happen if I react 1 degree alkyl halide with LiAlH4 and NaBH4 separately?

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Apoorv Tyagi if u treat that then reaction padkinxa

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