Hydrohalogenation - Alkene Reaction Mechanism

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  • Опубликовано: 5 окт 2024
  • This organic chemistry video tutorial provides a basic introduction into hydrohalogenation of alkenes. It provides the reaction mechanism as well. Examples include carbocation rearrangements such as hydride shifts, methyl shifts, and the stereochemistry of the products are mentioned as well.
    Alkene Reaction - Stereochemistry Test Question:
    • Meso Compounds, Enanti...
    Simmons Smith Reaction Test Question:
    • Cyclopropane Ring Form...
    Syn Vs Anti Addition Test Question:
    • Anti Addition vs Syn A...
    Alkene Epoxidation Test Question:
    • Halohydrin Formation a...
    Alkoxymercuration Demercuration Test Question:
    • Alkene + Hg(OAc)2 - Al...
    Ozonolysis Test Question:
    • Oxidative Cleavage of ...
    ________________________________
    Stereochemistry R/S Configuration:
    • Stereochemistry - R S ...
    Optical Activity & Specific Rotation:
    • Optical Activity - Spe...
    SN1, SN2, E1, E2 Reaction Mechanisms:
    • SN2 SN1 E1 E2 Reaction...
    SN1, SN2, E1, E2 - Practice Test:
    • SN1 SN2 E1 E2 Reaction...
    Alkene Reactions Review:
    • Alkene Reactions
    ________________________________
    Alkyne Reactions Review:
    • Alkyne Reactions
    Organic Chemistry PDF Worksheets:
    www.video-tuto...
    Organic Chemistry 1 Exam 2 Playlist:
    bit.ly/3PKEApB
    Organic Chemistry 1 Final Exam Review:
    • Organic Chemistry 1 Fi...
    Full-Length Videos and Worksheets:
    / collections

Комментарии • 61

  • @TheOrganicChemistryTutor
    @TheOrganicChemistryTutor  Год назад +2

    Organic Chemistry PDF Worksheets: www.video-tutor.net/orgo-chem.html
    Full-Length Exams and Worksheets: www.patreon.com/MathScienceTutor/collections
    Next Video: ruclips.net/video/6O-xSRC5Wg8/видео.html
    Alkene Reactions: ruclips.net/video/lKROX1C0JRs/видео.html

  • @saliksyd4714
    @saliksyd4714 5 лет назад +51

    God bless you.

  • @ingridd7111
    @ingridd7111 6 лет назад +65

    I think at 9:52, we have a primary carbon and a tertiary carbon. Thank you so much for making these videos. They have been saving me.

  • @maiwanmussa1238
    @maiwanmussa1238 5 лет назад +8

    I credit my Ochem success this semester to your videos. THANK YOU!

  • @lebronjames5176
    @lebronjames5176 4 года назад +12

    My professor had to go through multiple examples and I was still confused at the end. I watch your 12 minute videos and understand everything I should know by now. Thanks 🙏🏼

  • @Ralovelyb
    @Ralovelyb 6 лет назад +132

    Do I understand this video? Hell yeah
    Does my teacher teach to make me understand? NaBro

    • @jcmick8430
      @jcmick8430 4 года назад

      XD

    • @SIZLIANO
      @SIZLIANO 4 года назад +2

      him not explaning it properly dosen't mean he dont want you to understand, that's kinda mean.

    • @gaurishbhatia7010
      @gaurishbhatia7010 3 года назад

      @@SIZLIANO a😂ap😂😂

  • @tomatrix7525
    @tomatrix7525 4 года назад +6

    I like the explanations. My teacher just explains this as ‘ok so simply, hydrogen attaches to end breaking the double bond, carbocation in middle, that bonds with negative bromine. Done , easy see...’ and that’s her done...

  • @sambrailsford3800
    @sambrailsford3800 6 лет назад +45

    At 9:50 you label a carbon that's connected to three other carbons as secondary carbon. Shouldn't it be a tertiary carbon?

    • @ethanlittlestone1122
      @ethanlittlestone1122 5 лет назад +2

      yes

    • @janichka95
      @janichka95 5 лет назад +1

      @@ethanlittlestone1122 No, double bonds cannot be classified.

    • @raeanne5793
      @raeanne5793 4 года назад

      @shyl venk he did in the example prior..if you "cant consider the carbon attached to double bond", then the last example would only have primary carbocations sooo

    • @someone-yj2im
      @someone-yj2im 3 года назад +1

      @@raeanne5793 So is it actually tertiary carbon or second?? Can you explain?

    • @raeanne5793
      @raeanne5793 3 года назад +7

      @@someone-yj2im it would be a tertiary carbon, I believe he just made a mistake in the video. It is a tertiary carbon because when the electrons from the double bond attacks the H-Br, that double bond goes away and you are left with two possible carbocations. I think viewing the skeletal structure makes it easier to see this so I linked the google doc I created that shows you. here is the link: docs.google.com/document/d/1QXvka44V0s5bEpC-orfS9ECNug5IbPx2CXonhBiCBzE/edit?usp=sharing
      Carbocation #1 in the google doc shows that it is a tertiary carbon, and Carbocation #2 is a primary carbon. Let me know if this helped, or if you need it explained differently! (:

  • @britneymack8664
    @britneymack8664 3 года назад +3

    Shouldn't that be a tertiary carbon instead of a secondary carbon in the last example?

  • @prestonemulala7645
    @prestonemulala7645 2 года назад +2

    How do you determine the major product for the Alkene where the both carbons in the double bond are secondary carbons.

  • @sofzhuk1188
    @sofzhuk1188 3 года назад +1

    ahh yes, here I am again, after attending lecture and reading my book and still not understanding :)

  • @RawDoggin_78
    @RawDoggin_78 2 года назад

    you are my saviour

  • @alvarez321
    @alvarez321 2 года назад +5

    Ahhh, ok....I still don't get it

  • @jaquelinerios2740
    @jaquelinerios2740 5 лет назад +5

    What's an MTP orbital?

    • @nourelshabassy8158
      @nourelshabassy8158 5 лет назад +9

      Jaqueline Rios you heard a little wrong;
      it’s an empty ‘p’ orbital

  • @Shahboyy
    @Shahboyy 5 лет назад +2

    8:12 its actually 2-bromoPENtane

  • @eliyahbohadana3172
    @eliyahbohadana3172 Год назад

    In the second reaction, correct me if I’m wrong but it isn’t you major product because u had to do a hydride shift

  • @amnalayth1841
    @amnalayth1841 6 лет назад +1

    thank you very much ✌

  • @talyaxagh5291
    @talyaxagh5291 6 месяцев назад

    When do we perform hydrogen shift and when do we do methyl shift?

  • @olamideajayi247
    @olamideajayi247 4 года назад +1

    How do i identify the secondary carbon and the primary carbon?

  • @夸父逐日-i2p
    @夸父逐日-i2p 4 года назад

    In last example for HBr, there is 3rd carbonation, and a primary one, there is no 2ndery carbonation in the question, while you keep say 2nd ....

  • @amacgregor92
    @amacgregor92 3 года назад +2

    Anyone know what application he uses to draw?

  • @prestonemulala7645
    @prestonemulala7645 2 года назад

    Dwell much on explaining how oxygen stabilizes the primary carbocation

  • @JayPatel-ql1pj
    @JayPatel-ql1pj 5 лет назад +1

    Is there a chiral center on the last example, resulting in racemic enantiomers?

  • @anilkumarsharma8901
    @anilkumarsharma8901 2 года назад

    Gannaa key rus ko khumbhi sey sadao to kya methane nahin ban jayegi??? Hydrogen mix karo kuch ghee jaise ban jayegi😇😇😇😇

  • @karanghuman3336
    @karanghuman3336 6 лет назад

    Thank you for being helpful but do you have any videos on general organic chemistry reactions? I'm in first year Chemistry.

  • @janeb9986
    @janeb9986 3 года назад +1

    What are the products formed when Bromine Water reacts with 2-methylpropene ?

    • @NguyenNhan-yk3sr
      @NguyenNhan-yk3sr 2 года назад

      I think besides the hydrobromination,the alkene also undergo a reaction with the hydroxyl group,forming pentanol as well.

    • @ArshSahu
      @ArshSahu 7 месяцев назад

      When alkene react with bromine water anti addition takes place and it proceeds though cyclic transition state

  • @sanchez5963
    @sanchez5963 6 лет назад +8

    You helped me through out hard times please don’t ignore me and respond it I’ll mean much more than a reply to me.

  • @Andrew-kh7rz
    @Andrew-kh7rz 4 года назад +3

    11:53 isn't that tertiary?

  • @strugglingcollegestudent
    @strugglingcollegestudent 2 года назад

    6:22 how did you know the structure switched like that

  • @alhassanmichael306
    @alhassanmichael306 2 года назад

    👏👏👏👏am crazy about you!!

  • @sphanie
    @sphanie 4 года назад

    why is the major structure more stable?

  • @jessiez2807
    @jessiez2807 3 года назад

    Why doesn't Br ever make a bond that's in the plane of the page: why is it always either dashed or wedged?

    • @werewolwolf
      @werewolwolf Год назад

      Csp3 is planar, the P orbitals are the only ones which can react, so it goes either up or down

  • @cilened.s1788
    @cilened.s1788 5 лет назад

    Is that Br going to have and enantiomer since theres a chiral center

  • @ArshSahu
    @ArshSahu 7 месяцев назад

    Why are you ignoring hyperconjugation effect

  • @adhitya3573
    @adhitya3573 2 года назад

    wbat if HBR is in excess

  • @siobhanquinn4635
    @siobhanquinn4635 3 года назад

    a what kind of mixture? receding????

  • @annatropez
    @annatropez Год назад

    I LOVE YOU

  • @huxiao4656
    @huxiao4656 4 года назад

    Going to National sains competition

  • @gowthamthevipre2609
    @gowthamthevipre2609 4 года назад

    this nothing but carbocatiom rearangement mechanism

  • @MissPhilemon
    @MissPhilemon 5 месяцев назад

    I’m cooked bro

    • @CANALIMG
      @CANALIMG 23 дня назад

      We're all Cooked

  • @captaingovind5983
    @captaingovind5983 5 лет назад

    Nabro