Thank you, sir - I love this method! I mean, the idea of reclaiming and refining precious metals with laboratory equipment and chemicals is cool. But doing it with stuff from the local hardware store, garden supply store and thrift stores is badass. This is even cooler than acid-peroxide. You're a steely-eyed man of science for sharing this with us
@@BillAnt yes, they're the gold plated pins like the ones old hard drives had for the cable to connect to, or the tabs on video cards that slide into a socket on the motherboard
Ah! Just the video I was looking for. Was wondering if distillation in order to concentrate nitric acid was completely necessary when adding a nitrate salt to sulfuric acid for gold recovery.
If you only have calcium nitrate, you can add sodium sulfate or some other sulfate, then heat it while leading the vapors over in a beaker with water forming nitric acid without the crystallization of calcium sulfate, saving your glassware.
Yes. Ive used a stainless steel spoon to recover copper from acid solution, but after a while the spoon dissolves. I guess iron is a cheaper alternative.
Yes. Any metal that's more reactive than copper will "cement" the copper from solution. Aluminum is faster but gets hot quickly. Iron is cheaper and slower and doesn't heat up as much.
I think that drain opener is only 53-70% concentrated from what I've read online. I have some I'm getting ready to distill and looked it up. Still strong enough for most uses.
Depends on what drain opener. Around here we have 97-98% virgin concentrated sulfuric acid for $9.99 a quart. Even if you dont have that concentration and or additives in your acid you can clean it by heating you h2so4 and adding drop wise cold concentrated hydrogen peroxide. Continue heating to steaming off water until you reach the maximum concentration of 98%.
Will dye in sulfuric acid complicate your ability to make iron sulfate? Because I have failed at every attempt and doing so. But I've always used a sulfuric acid with a dye in it. NOT really the subject of this video, just side tracked I suppose.
Great vid man. And dang how much simpler can it get?? Lol. I am just starting to get in to Gold recovery and researching all I can before hand. Thanx for the entertainment 🤘👍🇺🇸🇺🇸
What % proof is the mixture as I believe it needs to be 70% so silver can be processed properly? I'm in the UK so it's nearly impossible to get hold of nitric so if this works for refining scrap sterling silver then that would be great? But it does depend on the %
It does work with silver. 100 grams of sodium nitrate and 30 ml's of 98% sulfuric acid and 1000 ml's of distilled water should dissolve 200 grams of sterling.
As it's a salt of a strong acid, ammonium nitrate is mildly acidic to begin with, unlike sodium nitrate. I wonder if it might work faster than the sodium salt?
Sir, in your opinion, could you explain, at least how much comparison in volum to be poured for making the solution when I will use HCl : HNO3 such that it can proper in the work (remain to able to dissolving copper) and safe for environmental? Thanks in advance
No. The calcium will rob the solution of sulfuric acid by producing calcium sulfate. Calcium sulfate is a off white, pearlescent solid that will clog filters.
I love the video about how to break down the metal and get the gold separated. But then how do you produce Accra Fria to liquefy the gold to make it more pure without nitric acid if you can
After the base metal is leached from the gold, a solution of aqua regia is made using HCl (muriatic acid) and sodium nitrate from this video. Use 1g of sodium nitrate for 1 ml of nitric acid.
One more quick question GOO did a pretty good batch of chips and crumble I’m still showing gold in solution but it looks like Sam has dropped should I just keep add an SMB until it all drops out I really appreciate your help
Usually the white material is tin that is dissolved by the nitric acid that is formed. It is called metastannic acid. Once the foils are gathered, dissolve the foils in what ever acids you like and the white should be left unchanged. Filter the solution well and make sure it's clear before dropping the gold.
GEO - A fun (and informative) video to watch. QUESTION: I would love to do this with some of my concentrated filter cake I collected from leaching actual ore. I've got some 250 mesh cake that is 2%+ Au. Do you think I could I run the material in this solution to remove the copper, lead and silver in the first go around. Then run the leftover material in another batch of the poor-man's nitric mix but add some HCl (to make poor-man's A/R) to put the Au into solution before dropping it with SMB. I really want to do this after watching you.....THANK YOU
@@GeoONE I am opening a PGM mine this year and am looking for refinement methods that are inexpensive and safer than amalgam. I want to be able to remove the ferrous with magnets from our concentrates and put them right into solution and drop out each valuable metal and recover the acids and precipitates for future use and reduce environmental impact and lower overheads. The mine was an amalgam operation in the 1800s, so there is mercury present. There is also lanthanides and thorium. Any suggestions are greatly appreciated. I was very excited to see this video. Thank you kindly, sir!
No. There is a gentleman on my facebook group Ewaste And Precious Metal Refining that I have helped him with the process of working with silver. Substitute tap water for distilled water for silver.
@@GeoONE geo thanks for the reply, the reason I asked is that there's loads of people that use distillation first to make a concentrate Nitric. So this process that you have shown will refine things like scrap silver bars? Worn scrap coins, flatwear etc? Regards
V good sirr i want to dissolve the tree leaves to extract the gold base metal my question is that which acid i used to extract or digest the enitre leaves in acid???
I'm not sure that I understand your question. Gold will dissolve in hydrochloric acid and several different oxidizers. Aqua regia is a combination of hydrochloric acid (3 parts) and nitric acid (1 part).
Sir there is gold in the eucalptus tree leaves and stem my question is which acid is better to distroy the leaves organic matter sir you can search how to make gold from tree leaves and stem???? Sirr you can also see an indian scientist precipated the gold from tree leaves
Sirr all the medcinal tree include 12 tree leaves have gold silver and plantium my question is the if we burnt the tree leaves in any acid then which acid or other thing like smb copperas ferrous sulphate or iron sulphate oxalic acid or pei_ls solution or EDTA solution is used to percipated the gold??
@@shoukatbabar739 you might try incinerating the leaves first and leaching the ash......then SMB.....look up sreetips on youtube.... he demonstrates several precipitants......i heard about the euc trees down under and gold uptake.....fascinating.... would love to know your results
Yeah the reason I ask is coz there is Silver in some CPUs so wanted to know how I can get to that too after I've removed the gold. Absolutely love your video. Thanks so much for sharing. I'm thinking ahead to the next step to see how I can get the silver from the waste.
Geo I can t find soda of nitrite...at my local hardware or feed n seeds....can I use...hi-yield brand (blood meal) 12% water insoluble organic nitrogen?
Hi Geo I appreciate your videos my name is Marco Ramirez I am new to gold recovery but I am a trying this process with coffee Parts as my heat source how long does it have to soak and break down it’s been about three hours on my end and it’s bubbling and I see a little bit of gold but not a lot is it because the heat isn’t hot enough thank you
You answered your own question. It needs to be hot enough for the nitrate to decompose to nitrogen dioxide (red fumes). Somewhere around 230°F is minimum. I normally crank my cheap burners wide open. They run around 350°F and it works really well.
Hey Jill this is Marco Ramirez I have a quick question phoria I don’t know how you feel about maybe giving me a call 907-299-7766 I’m in Homer Alaska I wanna run something by you thank you
@@GeoONE So when you say "done properly," you mean use distilled water instead of tap water, correct? Is there anything else to do when using with silver? Thanks
@@GeoONE thanks Geo..I wish I seen your video earliar.i just purchased a distillation kit litrelly last night for making nitric acid.its hard to get it nitric acid in Ireland...it won't go to waste.i seen in the comments that you will recover your hydrocloric acid and your nitric acid.have you got videos of that or will you be making one on recovering acids.look forward to more new videos.keep up the great work geo
Sodium hydroxide is lye. Drain opener can be either sodium hydroxide or sulfuric acid. It should say on the label which chemical it is. Sulfuric acid drain opener will normally be in a sealed plastic bag.
Hi there, probably a dumb question, but how much gold fingers did you start with by weight? I think I have the rest of the process down for using the poor mans nitric. Also, as you mentioned the list of other metals this can be used for, for silver recovery and refining this process is ok except distilled water needs to be used, but then the rest of the process is that same right? adding distilled water, and a chunk o copper to cement out the silver? Lastly, cpu pins, kovar, I am guessing this works on that as well? Thanks my friend!
On this particular batch, close to 8 pounds. It will dissolve silver but works better on impure silver such as sterling. Not sure why anyone would want to dissolve pure silver any way. :-D Use distilled water and the process works exactly the same way. Copper is what I use to cement my silver with. Make sure to denoxx well before cementing. Yes, it works very well when working with processors.
@@GeoONE Sorry, I should have been more precise, yes, i was referring to silver from contact points, broken sterling jewelry etc. Can this be used to make AR for gold recovery from ceramic cpus, IC's, and eproms?
Chemistry is not your strong point because you put the dry stuff in first and ad liquids next and if you don't put so much water in. It will generate your own heat.
So use this just like if it was nitric acid for silver, then dilute solution add copper to bring back silver ??? I wonder what kind of lost u would have?! I’m wanting to refine my 925 silver to 999 silver!!! I have about 4 ounces of 925 DANGIT IT! iTS HARD BEING APOUR MAN
No loses that I know of. Experiments have shown that it works well for silver. Members of my fabebook group have been using it for a couple of years now.
Geo well i got some acid it turned my finger yellow! I was kind of trying to distill it and that didn’t work. I poured off what I had and it dissolved copper so I stuck a silver quarter in it, the reactions going real slow even with heat. looks like some black stuff around the quarter and guess to what I might want to do next ??
If you are dissolving pins, most pins are brass or phosphor bronze and contain tin in the base metal. Dissolving tin this way will make metastannic acid. It's a gooey, sloppy mess that clogs filters and traps foils. I know how to deal with it but that will be in another video.
Geo that's what I was thinking. Sure would like to know how to get rid of it. I mostly do pins with rev- electro. But tried it with this method worked great other than the powder.
I used pot nitrate sulfuric acid and water if mixed heated by themselves btw I mixed this method up and haven't used heat yet my pyrex overflow pan shattered on burner haha getting a replacement soon stainless steel big dog dish soon as I can get past the neighbors dog just kidding
hir sir i start to recover gold that have i collect pin pinger and old cellphone board i've been used salt,vinegar and peroxide 3%, it is good or not, thank u
Not recommended for beginners working with material with high tin content due to the formation of metastannic acid. It will dissolve the base metal from the material you described and leave the gold untouched, the foils will be mixed with a white jello looking mess that's hard to separate from the gold.
The acids and base metal can be reclaimed. I'm not worried about the chemicals at the moment but I reclaim the copper by cementing the copper out of solution on steel.
Hello Geo, amazing video and explanation. I also cannot find 16-0-0 and the cost to buy it and ship it to me is just as much as buying nitric, which I have a case of but would rather not use up so fast. Would 16-0-1 work? Will that 1% potassium be an issue?
Geo, i wanted to clarify that this method would remove the base metals from gold plated pins and or circuit boards? and using sodium bicarbonate as the acid neutralizer?
This material will not have silver. If you are working with material that has silver, the silver will dissolve just as it would using nitric acid. To recover the silver, add a chloride such as non-iodized salt or hydrochloric acid. Or you could cement the silver out of solution as a metal using a piece of copper metal.
@@GeoONE thank u for your fast reply. Which is better using hcl or copper. With hcl dont u need to convert it? But the copper will contaminate the cemented silver a alil
Did it work on the silver? And I’ll be bringing it back with copper I think that might be best, but I could be wrong! And should I leave it heating up as the copper is in. I have about 4 ounces of 925silver ???
The sodium nitrate will not decompose and release NO2 without the sulfuric acid. The sulfuric acid is a catalyst. It decomposes the nitrate salt releasing nitrogen dioxide which is absorbed by the water creating nitric acid in the process. It will not work without the sulfuric acid.
The sulfuric acid breaks the bonds between the sodium and the nitrogen releasing nitrogen dioxide. The NO2 is absorbed by the water in solution and is turned into nitric acid all in one go. Yes, heat is required for the reaction to take place.
3 parts Muriatic acid (HCl/hydrochloric 31.45%) 1 part regular 3% hydrogen peroxide. No bubbler, a couple days, does not dissolve gold. This one doesn't help you much with the pins, but does the fingers, cell phones, etc if you don't happen to have a bubbler laying around. GREAT VIDEO!!! I learned a great deal thank you, kind sir!!! Keep it up
@@GeoONE so if you were to do ic chips would u still need to try and get the metal out before using it? Or just leave everything and it'll dissolve it?
Sincerely! Thank you! Worked WAY WAY better than expected. I did 3 baths... MF'N WOW! You sir get my internet glory golf clap of the year!! Ive been doing this a while, conventionally anyway.. This method is way easier and safer for first timers and old timers have NOT A F'ING CLUE! Ohh and it WORKS!!!.... P.S..... IT WORKS!. I owe you several beers sir! msg me :) Good things for good people ;)
Hi Geo so after doing this process and filtering to have just the gold coils how would we dissolve the gold. I thought Nitric acid dissolves gold. Isn't this poormans nitric acid?
Gold foils can be dissolved a couple of ways. Hydrochloric acid and chlorine bleach will dissolve gold foils and powders. Hydrochloric acid and nitric acid will dissolve gold of any type. Nitric acid alone will not dissolve gold. It must be in combination with hydrochloric acid. Aqua regia is a mixture of 3 parts hydrochloric acid and 1 part nitric acid.
Nice I thought i was the only doing it this way actually I add peroxide to it when doing doing silver. Which was found by accident while making piranha solution for a batch pins my bag of nitrates had a hole in bottom and while I stood up a decent amount fell right in my piranha I thought it was trashed but I let it go on low heat and in 2 hours nothing but gold foils and some cool looking copper sulfate crystals. 2 times faster with the peroxide. And no gold in solution 🤑
Peroxide is an oxidizer i use it just to speed up the process wether it is gold or silver or any mettal it makes it faster .however peroxide and hydrochloric acid when heated will dissolve your gold.
Short answer is, yes. But safety concerns says, no. Ammonia and dissolved precious metals do not react well together and there is a chance of creating an unstable compound.
Since I don't premix, it would be hard to say. Solid sodium nitrate equals nitric acid very closely though the needs 1.2 gram to 1 gram of nitric acid. The sulfuric acid is mixed in relation to the water used. I normally mix it 10% concentration roughly. A gallon is 3,785 ml's. A gallon of tech grade nitric acid will dissolve 2.5 pounds of copper. 2.5 pounds is 1,132 grams. It takes 3.3 ml of tech grade nitric acid to dissolve 1 gram of copper metal. 1.2 X 3.3 = 3.9 grams of sodium nitrate to dissolve 1 gram of copper metal.
in his beaker from what I can see, it is a 16:1:1 (1600 ml of tap water, 100 ml of Sulfuric, and 2x 50ml beakers of Nitrate for 100 "ml" of Nitrate to approximately 800 'ml' of material to be dissolved. Best I could guess.
There is a very fast way to strip the gold away less than two hours with A.P. would like to talk to you in person about it. I work In Decatur and Huntsville almost every day. But live in Cullman as for now. Retired electrician/a/c and refrigeration work below radar on the side I think we can help each other out with recovery and refining 😎😎💻🔬keep scrapping 😎😎
I use copper(II) chloride (AP) all the time. I just don't use peroxide because it can dissolve some gold. This is just a demonstration for people that like using nitric acid but nitric is expensive and hard to find for some people. You can catch me on my facebook group at facebook.com/groups/GeoMetals/ Be sure to answer all three security questions or my admin will just delete the request to join.
Hey geo I like what u do I've got something for you. Can sulfuric at the auto parts store cheap it's what they use in batterys thanks I've enjoyed ur video's hope u get this
There's way easier ways toake nitric acid. Get some calcium nitrate or some other water retning nitrate salt. Then just add sodium bicarbonate, boil it down to supersaturation and let it cool down to room temperature. Collect the sodium nitrate crystals and biol it down some more to crystallize the rest. Edit: it has to be distilled with H2SO4 to get 68% nitric.
Thank you, sir - I love this method! I mean, the idea of reclaiming and refining precious metals with laboratory equipment and chemicals is cool. But doing it with stuff from the local hardware store, garden supply store and thrift stores is badass. This is even cooler than acid-peroxide. You're a steely-eyed man of science for sharing this with us
What the heck is "gold finger" he's talking about? Are they gold plated metal pieces?
@@BillAnt yes, they're the gold plated pins like the ones old hard drives had for the cable to connect to, or the tabs on video cards that slide into a socket on the motherboard
Thanks for sharing. I am new to this and I am a extremely poor man and just trying to better my family situation so again thank you for sharing.
Love it Geo, thank you for sharing your techniques. More appreciated than I think you know!
I miss you brother. I wish you would have talked to me before you ended it.
Ah! Just the video I was looking for. Was wondering if distillation in order to concentrate nitric acid was completely necessary when adding a nitrate salt to sulfuric acid for gold recovery.
Distillation of vapers = pure nitric acid... Due believe....
Poor Man's nitric acid, known otherwise in chemistry as a double salt substitution.
If you only have calcium nitrate, you can add sodium sulfate or some other sulfate, then heat it while leading the vapors over in a beaker with water forming nitric acid without the crystallization of calcium sulfate, saving your glassware.
All you have to do is stick a chunk of IRON in the copper solution to make it crash out as copper metal.
Yes. Ive used a stainless steel spoon to recover copper from acid solution, but after a while the spoon dissolves. I guess iron is a cheaper alternative.
Yes. Any metal that's more reactive than copper will "cement" the copper from solution. Aluminum is faster but gets hot quickly. Iron is cheaper and slower and doesn't heat up as much.
Your video added Great knowledge to my study,thankyou!
Can't find the hi yeild stuff.
Any source of potassium nitrate or sodium nitrate will work.
Geo incredible processes. Glad to finally put a process to the gold refining forums!
Do you have a video to reclaim you acids from this solution? This is very interesting, thank you for sharing
I think that drain opener is only 53-70% concentrated from what I've read online. I have some I'm getting ready to distill and looked it up.
Still strong enough for most uses.
Depends on what drain opener. Around here we have 97-98% virgin concentrated sulfuric acid for $9.99 a quart. Even if you dont have that concentration and or additives in your acid you can clean it by heating you h2so4 and adding drop wise cold concentrated hydrogen peroxide. Continue heating to steaming off water until you reach the maximum concentration of 98%.
Will this process work for gold fill junk jewelry ? Thanks..
Yes.
Very nice demonstration. Do you or can you denox with urea? Thank you
Yes. It works exactly like nitric acid.
Geo thank you
Will dye in sulfuric acid complicate your ability to make iron sulfate? Because I have failed at every attempt and doing so. But I've always used a sulfuric acid with a dye in it. NOT really the subject of this video, just side tracked I suppose.
Great vid man. And dang how much simpler can it get?? Lol. I am just starting to get in to Gold recovery and researching all I can before hand. Thanx for the entertainment 🤘👍🇺🇸🇺🇸
Smart man💯
What % proof is the mixture as I believe it needs to be 70% so silver can be processed properly? I'm in the UK so it's nearly impossible to get hold of nitric so if this works for refining scrap sterling silver then that would be great? But it does depend on the %
It does work with silver. 100 grams of sodium nitrate and 30 ml's of 98% sulfuric acid and 1000 ml's of distilled water should dissolve 200 grams of sterling.
@@GeoONE and then do you drop the silver back out using hydrochloric acid?
Excuse me but yes you are responsible for the explanation of and knowledgeable information give .....that is one of the best I've seen..thanks buddy
As it's a salt of a strong acid, ammonium nitrate is mildly acidic to begin with, unlike sodium nitrate. I wonder if it might work faster than the sodium salt?
Adding organics to refining is not a good idea unless you know what you are doing. There is the possibility of creating an unstable compound.
Sir, in your opinion, could you explain, at least how much comparison in volum to be poured for making the solution when I will use HCl : HNO3 such that it can proper in the work (remain to able to dissolving copper) and safe for environmental? Thanks in advance
Solid sodium nitrate can be calculated at 1.1 gram of solid nitrate equals 1 ml of liquid nitric acid.
@@GeoONE 1 mL nitrit acid for how much HCl ?
Geo I like your video very interesting quick question for you will this work on fully plated pins and partially plated pins thank u for your time.
Yes. Keep in mind that heat is required to drive the reaction to completion.
Hi nice video, can I use calcium nitrate instead of sodium nitrate? Thanks
No. The calcium will rob the solution of sulfuric acid by producing calcium sulfate. Calcium sulfate is a off white, pearlescent solid that will clog filters.
Did you even watch the video? 😂
Can you make poor man's aqua regia also by substituting muratic acid for the sulfuric acid?
Yes.
So basically very dilute sulfuric acid ?🤔
Yes.
can you add hydrochloric acid and create aqua regia?
Yes.
I did just this and ended up with Cooper (11) sulfate crystals cemented in the bottom of my jar. What can I do about that now?
Well thankfully, copper sulfate is water soluble so the crystals will dissolve in water.
I love the video about how to break down the metal and get the gold separated. But then how do you produce Accra Fria to liquefy the gold to make it more pure without nitric acid if you can
After the base metal is leached from the gold, a solution of aqua regia is made using HCl (muriatic acid) and sodium nitrate from this video. Use 1g of sodium nitrate for 1 ml of nitric acid.
Thanks for your reply
Thanks for explaining how to make Acura Ferrari.
One more quick question GOO did a pretty good batch of chips and crumble I’m still showing gold in solution but it looks like Sam has dropped should I just keep add an SMB until it all drops out I really appreciate your help
One more quick question my solution is bluish green with a whitish gray film once I start decanting
Usually the white material is tin that is dissolved by the nitric acid that is formed. It is called metastannic acid. Once the foils are gathered, dissolve the foils in what ever acids you like and the white should be left unchanged. Filter the solution well and make sure it's clear before dropping the gold.
GEO - A fun (and informative) video to watch. QUESTION: I would love to do this with some of my concentrated filter cake I collected from leaching actual ore. I've got some 250 mesh cake that is 2%+ Au. Do you think I could I run the material in this solution to remove the copper, lead and silver in the first go around. Then run the leftover material in another batch of the poor-man's nitric mix but add some HCl (to make poor-man's A/R) to put the Au into solution before dropping it with SMB. I really want to do this after watching you.....THANK YOU
It should work okay.
@@GeoONE I am opening a PGM mine this year and am looking for refinement methods that are inexpensive and safer than amalgam. I want to be able to remove the ferrous with magnets from our concentrates and put them right into solution and drop out each valuable metal and recover the acids and precipitates for future use and reduce environmental impact and lower overheads. The mine was an amalgam operation in the 1800s, so there is mercury present. There is also lanthanides and thorium. Any suggestions are greatly appreciated. I was very excited to see this video. Thank you kindly, sir!
Hey geo great video im just askin how concentrated is the nitric acid
Concentration varies on available sulfuric acid.
Hi, would this not need to be distilled first for refining scrap silver? Regards
No. There is a gentleman on my facebook group Ewaste And Precious Metal Refining that I have helped him with the process of working with silver. Substitute tap water for distilled water for silver.
@@GeoONE geo thanks for the reply, the reason I asked is that there's loads of people that use distillation first to make a concentrate Nitric. So this process that you have shown will refine things like scrap silver bars? Worn scrap coins, flatwear etc? Regards
@@thewatchers9620 Yes. It will dissolve silver and then you can cement onto copper just like nitric acid does.
Oh, the good old days, back when you could get nitrate of soda.
V good sirr i want to dissolve the tree leaves to extract the gold base metal my question is that which acid i used to extract or digest the enitre leaves in acid???
I'm not sure that I understand your question. Gold will dissolve in hydrochloric acid and several different oxidizers. Aqua regia is a combination of hydrochloric acid (3 parts) and nitric acid (1 part).
Sir there is gold in the eucalptus tree leaves and stem my question is which acid is better to distroy the leaves organic matter sir you can search how to make gold from tree leaves and stem???? Sirr you can also see an indian scientist precipated the gold from tree leaves
Sirr all the medcinal tree include 12 tree leaves have gold silver and plantium my question is the if we burnt the tree leaves in any acid then which acid or other thing like smb copperas ferrous sulphate or iron sulphate oxalic acid or pei_ls solution or EDTA solution is used to percipated the gold??
Sirr i have a video to percipate the gold bt material not mensioned
@@shoukatbabar739 you might try incinerating the leaves first and leaching the ash......then SMB.....look up sreetips on youtube.... he demonstrates several precipitants......i heard about the euc trees down under and gold uptake.....fascinating.... would love to know your results
Great video. What happens to the silver if there is any? Does it dissolve in the solution or come out with the gold?
There's no silver in fingers. Although if there had been silver, it would dissolve. The gold does not dissolve in poor mans nitric acid.
Yeah the reason I ask is coz there is Silver in some CPUs so wanted to know how I can get to that too after I've removed the gold. Absolutely love your video. Thanks so much for sharing. I'm thinking ahead to the next step to see how I can get the silver from the waste.
I'm guessing same ingredients again but adding a copper base to cement the silver
@@shshgaming189 true..
Geo I can t find soda of nitrite...at my local hardware or feed n seeds....can I use...hi-yield brand (blood meal)
12% water insoluble organic nitrogen?
See if they can get Hi-Yield Nitrate of Soda. Duda-Energy is sold out at the moment.
Did you ever try the bone meal? I'm trying it now. We will see what happens.
Hmm...
I had no idea Sneed’s Feed and Seed (formerly Chuck’s) sold such useful products... good to know!
Couldn't you get potassium nitrate? I mean as a farmer , I'm sure you heard about stump remover!
Any nitrate can be used although calcium nitrate is not recommended due to the formation of calcium sulfate.
Hi Geo I appreciate your videos my name is Marco Ramirez I am new to gold recovery but I am a trying this process with coffee Parts as my heat source how long does it have to soak and break down it’s been about three hours on my end and it’s bubbling and I see a little bit of gold but not a lot is it because the heat isn’t hot enough thank you
You answered your own question. It needs to be hot enough for the nitrate to decompose to nitrogen dioxide (red fumes). Somewhere around 230°F is minimum. I normally crank my cheap burners wide open. They run around 350°F and it works really well.
Hey Jill this is Marco Ramirez I have a quick question phoria I don’t know how you feel about maybe giving me a call 907-299-7766 I’m in Homer Alaska I wanna run something by you thank you
Great description Geo. I assume that you can add HCl to make AR for the next step. Not sure how much HCl would be ideal to dissolve the Au. Thanks!
Yes, exactly.
Do you think this might work on crushed gold ore that has a lot of pyrite and lots of other metals?
No
Thank you my good sir! You have inspired me to repeated success!
Will this work to refine silver and then dropping it with copper?
Yes. If done properly, it works just like nitric acid.
@@GeoONE So when you say "done properly," you mean use distilled water instead of tap water, correct? Is there anything else to do when using with silver? Thanks
love your videos.i can get 85% sulphuric acid.its a fed liquid.could I use that instead.i see yr sulphuric acid is 98% and a white liquid
Yes. Drain cleaner will work just fine.
@@GeoONE thanks Geo..I wish I seen your video earliar.i just purchased a distillation kit litrelly last night for making nitric acid.its hard to get it nitric acid in Ireland...it won't go to waste.i seen in the comments that you will recover your hydrocloric acid and your nitric acid.have you got videos of that or will you be making one on recovering acids.look forward to more new videos.keep up the great work geo
hi there ace, i use this stuff all the time, can i use amonium sulfate in a glass still to make nitric acid...???Anyone ???
Ammonia and nitric acid creates an explosive compound. It is possible but not anything I would recommend.
@@GeoONE roger that i disolved some & nothing recrystalized. thanx, bill.
Just curious: can nitrate of soda be used to work with silver recovery?
Yes. Use distilled water and either potassium nitrate or sodium nitrate.
This video needs to be watched at 1.5 speed. Otherwise you will get a brain damage.
lol
lmao it works
ya'all come back now?
it does! much better! LMAO!!
WONDERFUL TIP.
sir is soduim hydroxide lye and drain opener are the Same?
Sodium hydroxide is lye. Drain opener can be either sodium hydroxide or sulfuric acid. It should say on the label which chemical it is. Sulfuric acid drain opener will normally be in a sealed plastic bag.
Hi there, probably a dumb question, but how much gold fingers did you start with by weight? I think I have the rest of the process down for using the poor mans nitric. Also, as you mentioned the list of other metals this can be used for, for silver recovery and refining this process is ok except distilled water needs to be used, but then the rest of the process is that same right? adding distilled water, and a chunk o copper to cement out the silver? Lastly, cpu pins, kovar, I am guessing this works on that as well?
Thanks my friend!
On this particular batch, close to 8 pounds. It will dissolve silver but works better on impure silver such as sterling. Not sure why anyone would want to dissolve pure silver any way. :-D Use distilled water and the process works exactly the same way. Copper is what I use to cement my silver with. Make sure to denoxx well before cementing. Yes, it works very well when working with processors.
@@GeoONE Sorry, I should have been more precise, yes, i was referring to silver from contact points, broken sterling jewelry etc. Can this be used to make AR for gold recovery from ceramic cpus, IC's, and eproms?
Chemistry is not your strong point because you put the dry stuff in first and ad liquids next and if you don't put so much water in. It will generate your own heat.
So use this just like if it was nitric acid for silver, then dilute solution add copper to bring back silver ??? I wonder what kind of lost u would have?! I’m wanting to refine my 925 silver to 999 silver!!! I have about 4 ounces of 925 DANGIT IT! iTS HARD BEING APOUR MAN
No loses that I know of. Experiments have shown that it works well for silver. Members of my fabebook group have been using it for a couple of years now.
I got it set up now wish I could show u picture lol I just started it and it’s with sulfuric acid and stump remover wish me luck thanks
Geo well i got some acid it turned my finger yellow! I was kind of trying to distill it and that didn’t work. I poured off what I had and it dissolved copper so I stuck a silver quarter in it, the reactions going real slow even with heat. looks like some black stuff around the quarter and guess to what I might want to do next ??
Can this be used to dissolve gold?
When I use this process I get a white - grey silver chloride looking powder that is a real pain "not silver either". Any idea?
If you are dissolving pins, most pins are brass or phosphor bronze and contain tin in the base metal. Dissolving tin this way will make metastannic acid. It's a gooey, sloppy mess that clogs filters and traps foils. I know how to deal with it but that will be in another video.
Geo that's what I was thinking. Sure would like to know how to get rid of it. I mostly do pins with rev- electro. But tried it with this method worked great other than the powder.
Remove solder from pins with a boil in hydrochloric acid first to get rid of tin
boy I like this way much better than distilling a nitric acid 1st
I think it is.
@@GeoONE will this make aqua regia when mixed with hcl
I used pot nitrate sulfuric acid and water if mixed heated by themselves btw I mixed this method up and haven't used heat yet my pyrex overflow pan shattered on burner haha getting a replacement soon stainless steel big dog dish soon as I can get past the neighbors dog just kidding
hir sir i start to recover gold that have i collect pin pinger and old cellphone board i've been used salt,vinegar and peroxide 3%, it is good or not, thank u
Not recommended for beginners working with material with high tin content due to the formation of metastannic acid. It will dissolve the base metal from the material you described and leave the gold untouched, the foils will be mixed with a white jello looking mess that's hard to separate from the gold.
Geo, Do you know what is wrong with the goldrefiningforum? It seems to be offline for many days now...
It is a problem with Noxx not paying the server fees.
Thanks for the quick answer. Do you know how we can help him? Or is there a way to get in to contact with him?
He was mountain climbing in Peru. He may be able to straighten it out when he gets back. No one but Noxx can do anything about it.
What kind of nitrate is that? Potassium or sodium?
Sodium nitrate.
So what do you do with the byproduct chemicals?
The acids and base metal can be reclaimed. I'm not worried about the chemicals at the moment but I reclaim the copper by cementing the copper out of solution on steel.
Great info. I can't find 16-0-0. Would 32-0-0 do?
Since it will dissolve silver, I would not use urea as it can form an explosive compound with dissolved silver.
Hello Geo, amazing video and explanation. I also cannot find 16-0-0 and the cost to buy it and ship it to me is just as much as buying nitric, which I have a case of but would rather not use up so fast. Would 16-0-1 work? Will that 1% potassium be an issue?
@@davew3649 I don't think so. Calcium is a real pain though.
@@GeoONE i think you replied to the wrong post😨
how do you reclaim the sulfuric acid from the solution
It can be distilled carefully.
@@GeoONE how
Geo, Your the best buddy. Love the video. Thank you
Geo, i wanted to clarify that this method would remove the base metals from gold plated pins and or circuit boards? and using sodium bicarbonate as the acid neutralizer?
It will dissolve base metal but neutralizing is not necessary until treated as waste.
Does it have to be hot to get tge silver out?? Or how
This material will not have silver. If you are working with material that has silver, the silver will dissolve just as it would using nitric acid. To recover the silver, add a chloride such as non-iodized salt or hydrochloric acid. Or you could cement the silver out of solution as a metal using a piece of copper metal.
@@GeoONE thank u for your fast reply. Which is better using hcl or copper. With hcl dont u need to convert it? But the copper will contaminate the cemented silver a alil
I am trouble telling when its done. It is finely divided material and its hot. Some bubblez but i cant tell if its from heat or reaction
Did it work on the silver? And I’ll be bringing it back with copper I think that might be best, but I could be wrong! And should I leave it heating up as the copper is in. I have about 4 ounces of 925silver ???
What are "trimmed fingers?"
On the edge of cards that plug into a computer. The fingers are the gold plated part.
Why do u need sulfuric if ur usng nitrate
The sodium nitrate will not decompose and release NO2 without the sulfuric acid. The sulfuric acid is a catalyst. It decomposes the nitrate salt releasing nitrogen dioxide which is absorbed by the water creating nitric acid in the process. It will not work without the sulfuric acid.
Geo im sorry i dont understand, other ppl do it different or use different nitrate???
Also is heat required for a reaction
The sulfuric acid breaks the bonds between the sodium and the nitrogen releasing nitrogen dioxide. The NO2 is absorbed by the water in solution and is turned into nitric acid all in one go. Yes, heat is required for the reaction to take place.
Great video very informative. You can complete the same process . by Combining salt , vinegar , peroxide . With a bubbler hose. Best wishes .
Salt vinegar peroxide remove.disolve gold????????
3 parts Muriatic acid (HCl/hydrochloric 31.45%) 1 part regular 3% hydrogen peroxide. No bubbler, a couple days, does not dissolve gold. This one doesn't help you much with the pins, but does the fingers, cell phones, etc if you don't happen to have a bubbler laying around. GREAT VIDEO!!! I learned a great deal thank you, kind sir!!! Keep it up
Large disaster when phone and laptop went out, back on line, re subed
Hey, don't quit now! I come back to your channel over and over. I would love to see you process the copper out of circuit boards.
It's actually in the works.
@@GeoONE That is awesome! Thanks so much!
Why would you go through that much trouble for such a small amount of copper? It's less than $3.00 a pound.
@@E-BikingAdventures eviroment in pack then you can pull out the silver lead and neutralize the solution and dispose it's an easy process.
Geo , what will this mix do to I.C. chips?
It will dissolve base metal and silver leaving the gold metal intact. I've used it for this purpose many times.
@@GeoONE so if you were to do ic chips would u still need to try and get the metal out before using it? Or just leave everything and it'll dissolve it?
Sincerely! Thank you! Worked WAY WAY better than expected. I did 3 baths... MF'N WOW! You sir get my internet glory golf clap of the year!! Ive been doing this a while, conventionally anyway.. This method is way easier and safer for first timers and old timers have NOT A F'ING CLUE! Ohh and it WORKS!!!.... P.S..... IT WORKS!. I owe you several beers sir! msg me :) Good things for good people ;)
Thank you very much.
I did ur process exactly but it turned yellow not blue is that cuz there was trace amount of hcl...?
Are there foils showing? If not. test the solution with stannous chloride. Yes, HCl contamination will cause the gold to dissolve.
Hey Geo, just curious how much base material by weight you had in the beaker, if you know.
Approximately 1 kg of trimmed fingers.
Hi Geo so after doing this process and filtering to have just the gold coils how would we dissolve the gold. I thought Nitric acid dissolves gold. Isn't this poormans nitric acid?
Gold foils can be dissolved a couple of ways. Hydrochloric acid and chlorine bleach will dissolve gold foils and powders. Hydrochloric acid and nitric acid will dissolve gold of any type. Nitric acid alone will not dissolve gold. It must be in combination with hydrochloric acid. Aqua regia is a mixture of 3 parts hydrochloric acid and 1 part nitric acid.
Okay I see what you did there... Hmm. Thank you
Hi yield how are you
Nice I thought i was the only doing it this way actually I add peroxide to it when doing doing silver. Which was found by accident while making piranha solution for a batch pins my bag of nitrates had a hole in bottom and while I stood up a decent amount fell right in my piranha I thought it was trashed but I let it go on low heat and in 2 hours nothing but gold foils and some cool looking copper sulfate crystals. 2 times faster with the peroxide. And no gold in solution 🤑
It does work with silver.
So if you're recovering silver too you add peroxide? I didn't get that part.
Peroxide is an oxidizer i use it just to speed up the process wether it is gold or silver or any mettal it makes it faster .however peroxide and hydrochloric acid when heated will dissolve your gold.
Can you use ammonium nitrite?
Short answer is, yes. But safety concerns says, no. Ammonia and dissolved precious metals do not react well together and there is a chance of creating an unstable compound.
@@GeoONE thanks ....
pretty good
Nitrat of soda ? Hidroxid of soda? Caustic soda?
Sodium nitrate. Sodium hydroxide. Lye.
@@GeoONE tenk yu mein frend
very good video geo
Can this poormans nitric be Pre made and stored?
Yes, store in a cool place out of the sun lightly capped. Do not seal completely. It only reacts when there's metal that can be dissolved.
Geo what would the mix ratio be?
Since I don't premix, it would be hard to say. Solid sodium nitrate equals nitric acid very closely though the needs 1.2 gram to 1 gram of nitric acid. The sulfuric acid is mixed in relation to the water used. I normally mix it 10% concentration roughly. A gallon is 3,785 ml's. A gallon of tech grade nitric acid will dissolve 2.5 pounds of copper. 2.5 pounds is 1,132 grams. It takes 3.3 ml of tech grade nitric acid to dissolve 1 gram of copper metal. 1.2 X 3.3 = 3.9 grams of sodium nitrate to dissolve 1 gram of copper metal.
in his beaker from what I can see, it is a 16:1:1 (1600 ml of tap water, 100 ml of Sulfuric, and 2x 50ml beakers of Nitrate for 100 "ml" of Nitrate to approximately 800 'ml' of material to be dissolved. Best I could guess.
Correct
Very good 🎉 16:39
I bought a drain opener but it says it has lie it doesn't say anything about sulfuric acid
Drain opener was made with both chemicals. You have to find the kind with sulfuric acid.
Geo will it say on the bottle? Isnt lye the opposite of sulfuric acid?
Yes. It will say "contains virgin sulfuric acid" on the label. Yes, sodium hydroxide is a strong base and is the opposite of acid.
Found it thanx
Your welcome.
geo, can you process some monolithic capcitors for me
Contact me on facebook or messenger.
facebook.com/jeff.massey.507
I DONT USE FACEBOOK HOW DO I USE MESSENGER?
email is the best for me
email not going to work?
Thank you
My Leader
Time to pop some hexamine tablets into that and have lots of fun
Good info!
Thank you!
There is a very fast way to strip the gold away less than two hours with A.P. would like to talk to you in person about it. I work In Decatur and Huntsville almost every day. But live in Cullman as for now. Retired electrician/a/c and refrigeration work below radar on the side I think we can help each other out with recovery and refining 😎😎💻🔬keep scrapping 😎😎
I use copper(II) chloride (AP) all the time. I just don't use peroxide because it can dissolve some gold. This is just a demonstration for people that like using nitric acid but nitric is expensive and hard to find for some people. You can catch me on my facebook group at
facebook.com/groups/GeoMetals/
Be sure to answer all three security questions or my admin will just delete the request to join.
@@GeoONE I don't find gold in solution by testing
Can I please ask you if I can use a metal container instead of glass to make poormans nitric acid
Can't find nowhere
You got my sub sir
GEO!! GEO!! GEO!!
Awesome brother
Good ringtone! Lol
very well explained and well showed thanks for sharing cool thank you
Hey geo I like what u do I've got something for you. Can sulfuric at the auto parts store cheap it's what they use in batterys thanks I've enjoyed ur video's hope u get this
Yes. 10% battery electrolyte will work.
Get your money right
thanks fella!
There's way easier ways toake nitric acid. Get some calcium nitrate or some other water retning nitrate salt. Then just add sodium bicarbonate, boil it down to supersaturation and let it cool down to room temperature. Collect the sodium nitrate crystals and biol it down some more to crystallize the rest.
Edit: it has to be distilled with H2SO4 to get 68% nitric.
Distilation isnt easier than this.
THAT AIN'T EASY!!
god vare vare god tankyo
I can't do that, because the nitric acid in the Philippines is so expensive.