Spherical harmonics for Schrodinger equation

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  • Опубликовано: 12 сен 2024
  • Spherical harmonics are special mathematical functions defined on the angular coordinates, the azimuthal and polar angles, phi and theta, as shown in the box. Why are spherical harmonics important in quantum mechanics? As we will see, the spherical harmonics make up part of the electron’s wavefunctions in a hydrogen atom. Just like the spatial and time harmonics we have seen earlier are consequences of the spatial and time translation symmetry, the spherical harmonics is a consequence of the rotational symmetry of the hydrogen problem. In this video, we shall review how the spherical harmonics solutions is obtained, and how one can visualize them.
    Technical Content: Tony Low
    Video Production: Katie Low, Tony Low
    Erratum.
    In 2.22, the angles \phi and \theta in the equations on the right should be interchanged. Thanks to ‪@cinemaclips4497‬ for pointing out this typo.

Комментарии • 13

  • @tgocamargo
    @tgocamargo 5 месяцев назад +1

    The way you explain the sequence of solutions made understanding much easier. Congratulations on the quality material you have on your channel.

  • @aravindsai2409
    @aravindsai2409 3 месяца назад +1

    Thank you. You made it so easy to understand.

  • @cinemaclips4497
    @cinemaclips4497 11 месяцев назад +4

    It should be z=rcosθ from the way you labeled your axes.

    • @professornanoscience
      @professornanoscience  11 месяцев назад +2

      thanks! I added an erratum in the video description and point out this typo. Pls check.

  • @kisho2679
    @kisho2679 Месяц назад

    While spherical harmonics are the eigenfunctions of the hydrogen atom to describe its state, which are the eigenfunctions for the other 117 chemical elements (helium, etc.)?

  • @ManojKumar-cj7oj
    @ManojKumar-cj7oj Год назад +1

    cant belive how easy u made it for me , thank u so much

  • @Zoro-fl2mn
    @Zoro-fl2mn 2 месяца назад

    Can you give a source for the mathematical derivation of the polar solution?

  • @kisho2679
    @kisho2679 10 месяцев назад

    how about the spherical harmonicals for the other chemical elements in the periodic table (not just is Hydrogen)?

    • @professornanoscience
      @professornanoscience  10 месяцев назад +1

      Spherical harmonics is just the solutions of the Laplacian with spherical symmetry. It applies to other elements to the extent that the one electron picture is valid, and that is a hairy thing to discuss here.

  • @EdVidService
    @EdVidService 3 дня назад

    The Phi and Theta should be corrected. You wrote them upsidedown