Total Synthesis of Dragocins A−C through Electrochemical Cyclization
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- Опубликовано: 7 сен 2024
- An organic chemistry minilecture on the 'Total Synthesis of Dragocins A−C through Electrochemical Cyclization' by Brendyn P. Smith, Nathanyal J. Truax, Alexandros S. Pollatos, Michael Meanwell, Pranali Bedekar, Alberto F. Garrido-Castro, Phil S. Baran* It features an Electrochemical Oxidative Cyclization, an Barton-McCombie Chlorination and a divergent Moc carbamate reduction.
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References:
Angew. Chem. Int. Ed. 2024, e202401107 (this work)
Org. Lett. 2019, 21, 1, 266-27 (discovery)
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Tetrahedron 2018, 74 , 4969e4979 (Barton-McCombie Mechanism(s))
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