This is a MUCH better explanation of the actual concepts behind the chloralkali process than anything else I've seen in just youtube videos. Amazing work.
Have you ever thought about making a text book? You do a very good job explaining and teaching. It's hard for me to follow along with a lot of other people and I personally follow along with what you say quite well. Thank you
Thanks so much! That means a lot. Making a textbook might be something I do one day, but I feel like it's probably something to work on after I finish my chemistry degree (which seems like it might be a long way off at this stage...).
Awesome. I had also thought and experimented before but I got to know that it makes bleach instead of NaOH. So then i used two separate cells and it generated sodium hydroxide very nicely. Thanks so much bro. Now I know what is really happening during the electrolysis.
Not really. NaOH does eat through the gelatin. However, it eats through the ‘vegetarian gelatine’ or agar at a MUCH slower rate. Hence why we’re using it instead of the regular stuff.
@@ScrapScience Makes sense, I had one that I made with regular gelatin that completely dissolved after a couple hours. The flower pot diaphragm you showed seems to work best for me in most cases.
Tldw for up to 9:20 If you just perform electrolysis in a glass, the products NaOH and Cl2 will react with each other to form NaClO and then continue up to NaClO3
Glad you found it helpful! There's nothing too complicated about neutralising chlorine. In this video, we just lead the chlorine into a sodium hydroxide solution. As it passes through, it reacts with the solution to form bleach, preventing the chlorine from being released as a gas.
@@ScrapScience thank you so much… iv bin trying to understand that for few days lol!! Im going to try this experiment today:) iv learned alot from you.. keep up the good work friend!
Very nice, I've always found KOH very difficult to find. As for your questions, I'm actually in Australia, and I believe I got the alligator clips from Jaycar electronics, it was a while ago though so I might be wrong.
I'd love to eventually, I'm currently working on a larger scale cell which should produce Cl2/H2/NaOH at a faster rate, and if I ever figure out how to combine H2 and Cl2 safely, I'll definitely give it a go. I think I already have a UVC LED which should be ideal for initiating the reaction.
@@ScrapScience what about you burn the hydrogen, add chlorine to water to get hydrochloric acid and hypochlorous acid, and put it under strong sunlight for hypochlorous acid to break down into hydrochloric acid and oxygen gas H2O (l) + Cl2 (g) -----> HCl (aq) + HClO (aq) 2HCl(aq) ----sunlight----> 2HCl (aq) + O2 (g)
@@ScrapScience the reason why i suggest this method is because mixed hydrogen gas and chlorine gas can explode under sunlight, so i would suggest a safer process. Hope this helps.
29:16 I used this method to generate chlorine. To do this, I cut some Plexiglas into a circle so that it would fit about 1 CM below the top of the clay pot. I drilled a hole in the center of the Plexiglas to fit a carbon rod. Also a hole to place a small gas fitting and sealed the whole thing with electrician's putty. The chlorine was dried with some calcium chloride in a glass tube. In the pot, was very concentrated salt solution.
Seawater generally isn't a good idea, as your product will always contain some impurity as a result. If you want to make a bigger cell, you can watch my other video on the topic: ruclips.net/video/iZH5fB0iM7U/видео.html
You can use a sheep cecum, a lambskin condom if can tolerate PRICE think have to wash surface, used with palladuim diluted acids. Was looking for a longer term solution, test tube shaped porous ion exchange proton well hydrogenation. H2. Probably cost him 12-20 🇺🇸 $ or conversion as of now where live fiat numbers. Could heat and drop tube pipe borosilicate 3.3. Only have 8 inch 20mm 8mm left gas tube. Hope can make palladium electrode needs high surface area. Can't find but in grams, and expensive for hobby. Neverctsught green electrochemistry or microwave ultrasonic. Just organic, lab had all guy drove into ground to steal ipo money and make golden parachute. Told me to sabotage steal precious metals spend, neverxdid made neural growth factor as undergrad with MD PhD. We could all use or know one could. Love folks sharing knowledge, when world is so poor outside west.
Wouldn't chlorine gas be reduced to chlorine ions at the anode and the hydrogen molecules beging oxidised into hydrogen gas ?? Plss solve my confusion I've got exams nearby in 2 days bro Love from india 🇮🇳🇮🇳
No. Oxidation occurs on the anode, and reduction occurs on the cathode. The anode oxidises chloride ions to chlorine gas, and the cathode reduces water molecules into hydrogen gas and hydroxide ions.
Hi pretty cool experiment you did there ! I found articles about how to make H2O2 with electrolysis in alkaline solution. Did you try that ? Do you think it´s possible as experiment ? Your pot would be a good seperator indeed :)
That's definitely very cool! I did a quick search for some articles on the topic and as far as I can tell, it looks relatively feasible to do without too much fancy equipment (though the yield might be considerably reduced when using clay pot separators instead of ion exchange membranes). Hopefully I'll get onto trying to make some gas diffusion electrodes soon, then I'll definitely be keen to give this a go. Thanks for the idea!
Yes the gas diffusion electrodes and membranes seem to be somewhat expensive. Do they last a long time ? Take a look at this Patent it´s very interesting US4357217A. You are welcome I am curious to see more videos from you :)
Sorry for the late reply, only just saw your second comment. The patent certainly looks very doable I think, as does the paper linked with it. Hopefully the electrodes should last a while, as cathodes I think they should as they aren't under oxidising conditions and don't seem to contain a catalyst. I've just finished making a simple gas diffusion electrode which should hopefully work for this, so once I get a little more equipment I'll definitely give this a go.
No worries it´s ok. As it seems 9% is made in the paper but it doesn´t say you can´t make 30%. So it would be really cool If it goes that high. You don´t need to buy it anymore just switch on your power and make some :D I also have an idea how to store it forever. Do you know If H2O2 reacts with carbonates ?. You could make barium peroxide from barium carbonate and store it dry until you need H2O2 then you just have to dissolve it in water and filter the barium hydroxyde out again and use it later.
I have few questions but before i aske them i wanna really to thank you alot for making such clear video:1.Why we dont pour brine in both sides,i mean it will improve conductivity?shouldnt chlorine ion pass trough membrane just like sodium ion?2nd question is:how you protect your copper electrode,shouldnt it react with formed NaOH?
Great questions! 1) Putting brine in both chambers would work perfectly fine, the sodium ions would migrate to the cathode and chloride ions would migrate to the anode as you'd expect. The problem, however, is that this migration of ions never actually reaches completion, so there will always be some residual chloride contamination in the NaOH product when performing the reaction this way. Just putting the salt into the anode chamber avoids this, as the only reactant entering the cathode chamber becomes the sodium ions, allowing for pure NaOH to be generated. 2) Copper doesn't actually react with NaOH solutions under normal conditions, so corrosion/dissolution doesn't occur. Even if copper did react with NaOH, being used as a cathode makes it 'cathodically protected', making it much more resistant to oxidation.
@@ScrapScience I was wandering about this as well. Most of the sources I've found describing the diaphragm method state that brine is introduced into the anode chamber and allowed to flow into the cathode chamber. There's no suggestion of anything initially being in the latter. And, since historically the diaphragm of choice was asbestos, wouldn't the brine find it's way to the cathode sooner or later in any case? As I've understood it, the contamination of NaOH is simply dealt with afterwards when using this method. I did try your method successfully, but I used gelatinized potato starch in place of vegetable gelatin, and it took a long time to get going properly. Will be using in the future though should I want to make clean NaOH, for now I'm more interested in the chlorine and hydrogen :)
A few decades ago. I operated a small membrane cell commercial chlor-alkali plant for the production of sodium hypochorite (the cholrine and sodium hydroxide were combined in a seperate reactor). On startup, we would put sodium hydroxide in the cathode side. This would keep the conductivity up until it started producing its own sodium hydroxide.
@@michaelgates991 The biggest disadvantage to the old asbestos diaphragm cells was that the NaOH produced had quite a bit of salt contamination. Most of the salt would precipitate out when the NaOH was concentrated, but there would still be a significant amount of salt in a 50% NaOH solution.
A shorter (or a larger cross sectional area) membrane will drastically decrease the resistance of the cell at a given voltage. This allows for the cell to be run at a lower voltage for any given production rate, increasing the efficiency (based on energy usage). Basically, a shorter membrane makes the process quicker, and more efficient.
Ay bro, can you please tell me all the materials needed to make a model of this? I really need it for a science exhibition project. (Sorry for bad grammar)
From the back of the box: Dried Glucose Syrup (From Corn), Gelling Agents: Carrageenan. Locust Bean Gum, Stabilisers: Potassium Chloride, Calcium Acetate. If you don't have access to vegetarian gelatin, you also have the option of using agar or carboxymethyl cellulose which work in a similar fashion. If you're really stuck, you can use any semi-porous membrane like cotton, fibreglass, or even a clay pot, which all last much longer than any gel (but at the cost of slight contamination between the cells).
I have some strontium chloride that I want to turn into strontium hydroxide. Do you reckon this process will work for separating the chlorine from the hydroxide in it as well?
Would a ptfe tube with pin holes in it work? Fluid would be restricted pretty well but a currant would go through? I could put it in a coil on the bottom with both ends connected to cathode so its a semi closed loop.
Ideally, no, it shouldn’t have a hole. Those types are pretty tricky to find though, so it’s often necessary to simply plug the hole with a stopper or some silicone.
The fourth anode option is stainless steel, but at high currents it tends to oxidize as well. You can use stainless steel wool for both electrodes (like the kind in dish scrubbers) because it has a lot of surface area, and same current/larger surface area = less corrosion.
I'm afraid stainless steel isn't really an option for the chloralkali process. While stainless steel does well under anodic potential in extremely basic solutions, a chloride solution is a whole different story. When used as an anode in a chloride solution (regardless of current density), the corrosion rate is so fast that virtually no chlorine is generated, and instead the solution fills with soluble iron and chromium which contaminate your hydroxide product considerably. There are many things that stainless steel works well for, but chloride electrolysis is such a harsh environment that it doesn't quite cut it.
@@ScrapScience The commercial chor-alkali plant I operated used titanium anodes with a proprietary coating (contained platinum and rhodium and maybe some other exotic metals). We still had to be careful, as even these would break down if operated at too high a voltage. It used mild steel cathodes, though the cathodes were problematic, as any leakage of chlorine to the cathode side would cause corrosion, and contaminate the product with rust.
Not quite. It would be very similar, but in that case, the cathode should actually be the mercury itself (ie. instead of having the cathode on the right hand side sitting above the mercury, it should directly contact the mercury to supply current straight to the liquid metal). For a mercury cell like this, it is only in the left chamber that electrolysis should occur, where chlorine is liberated on the carbon anode, and sodium metal is dissolved in the mercury cathode. Once dissolved in the mercury, the sodium should migrate over (this would probably require stirring the mercury somehow) and redissolve into the water of the right hand chamber, forming sodium hydroxide. It's definitely a process I'd avoid to stay clear of any mercury contamination.
@@ScrapScience I hear ya lol. Thankyou for reply. However I ask to explore the science behind it. But I doubt I will. You should check out my channel. It's a chemistry channel also I'm still very small yet. Got some good videos tho. Stay safe mate.
Only a small amount, as the hypochlorite ions are oxidised to chlorate quickly after they are generated. The electrolysis never really generates a useful quantity of bleach, nor is it ever pure enough for use as bleach.
@@ScrapScience The chor-alakli plant I operated was used to make sodium hypochlorite. But it used membrane cells, and the chlorine and NaOH were reacted in a seperate vessel. For one thing the cells operated at too high a temperature (150-170 degrees F) for hypochorite production, the NaOH solution was cooled and then the chlorine from the anode side was bubbled into it. Another consideration is that, in order to be stable, sodium hypochlorite requires excess NaOH. The system I operated had a pH probe and additional NaOH was added for stability. In order to make stabe hypochlorite with a chlor-alkali system, you have to either use additional NaOH or divert some of the chlorine to another use. Higher temperatures and lower pH favor chlorate over hypochlorite. Sodium hypochlorite under the best conditions (low temperature, low concentration, high pH, no metal contaminants) is not very stable. It tends to break down either to sodium chlorate, or to salt and oxygen.
I hope u still there iam using diaphgram of claypot, sucessfully made about 1.5 L , but iam not sure if it was NaOH or NaClO because i smell Chlorine inside my claypot solution, corroded aluminum, but yellow-ish color, do you have any suggestion?
What you've made really depends on a few factors. What were your electrodes made of? Which one was the cathode/anode? Which chamber did you expect to get product in? What was the container made from in which you ran the cell? And, how much current did you run through the cell and for how long? I'm afraid I can't really help without more info.
Chlorine smell and yellowish color is consistent with sodium hypochlorite. Color could also be iron or other metal contamination from anode or cathode.
Yep, the hypochlorite sure does. At concentrations like this, it's usually slow enough such that you can still get a pH reading if you're quick though.
Liked and Subbed I have some questions 1. Will increasing the volts through power supply speed up the NaOH production ? 2. Is there some way to calculate the volts required for electrolysis of X amount of salt / Or salt water / Or Electrolyte Thanks in Advance
As a matter of fact, I have an entire video on optimising this reaction in terms of the concentration, voltage, current, and reaction times. You can find it here: ruclips.net/video/OrEQkBOxmxg/видео.html On top of that, you can also find a video where I build a functioning cell for producing reasonable quantities of hydroxide here: ruclips.net/video/iZH5fB0iM7U/видео.html
Well, technically yes. However, the dissolution of chlorine in water will be very slow (hydrogen peroxide won't help anything here), and taper off over time, so the concentration of acid at the end of the reaction will be very low. Also, the dissolution of chlorine also produces hypochlorous acid in equal amounts as it generates hydrochloric acid, which is a considerable and highly undesirable impurity in most cases.
Here is a link I found. Needs to be revised, involves electrolysis of salt water I don't know how that would work. Hope it helps you get closer to what you need. sciencing.com/make-sodium-chlorite-5188671.html
I'm afraid it's not feasible. Even if it were legal and I actually wanted to do it, a self-sustaining nuclear reaction from the americium in smoke detectors would require at least ten billion smoke detectors, and that's being very generous with the numbers.
The benefit is not the sodium hydroxide, it is the chlorine. You could make massive amounts of chlorine for dirt cheap and for very long periods of time. Every other process for generating chlorine, if used over days or weeks it is very expensive.
If you choose to watch any of the more recent videos I've made (anything within the past 20 months or so), I'm sure you'll be a lot more satisfied with the stability of the footage.
You are a million times more helpful than Google...
^
Realmente así es...
Más útil y más eficiente
I had great success using cotton balls as a filter membrane and a 30 watt solar panel. Most excellent series!
really we can use cotton and it gives us the same result ?
This is a MUCH better explanation of the actual concepts behind the chloralkali process than anything else I've seen in just youtube videos. Amazing work.
Fantastic! Now I have something I can build with some confidence that it won't fall apart.
Have you ever thought about making a text book? You do a very good job explaining and teaching. It's hard for me to follow along with a lot of other people and I personally follow along with what you say quite well. Thank you
Thanks so much! That means a lot.
Making a textbook might be something I do one day, but I feel like it's probably something to work on after I finish my chemistry degree (which seems like it might be a long way off at this stage...).
Awesome. I had also thought and experimented before but I got to know that it makes bleach instead of NaOH. So then i used two separate cells and it generated sodium hydroxide very nicely. Thanks so much bro. Now I know what is really happening during the electrolysis.
Absolutely great you answered many question in my head, thanks
Glad it was helpful!
i am from India i saw this video i am to understand this activity in my ncert class 10 book....
thank you.
Shaandeep Singh (Techno Trigger).
Thanks Herry! I always learn a lot from your videos.
awesome video
Does normal gelatin work for the diaphragm? If so, why not? Also, does the NaOH/ OH- eat through the gelatin?
Not really.
NaOH does eat through the gelatin. However, it eats through the ‘vegetarian gelatine’ or agar at a MUCH slower rate. Hence why we’re using it instead of the regular stuff.
@@ScrapScience Makes sense, I had one that I made with regular gelatin that completely dissolved after a couple hours. The flower pot diaphragm you showed seems to work best for me in most cases.
Tldw for up to 9:20
If you just perform electrolysis in a glass, the products NaOH and Cl2 will react with each other to form NaClO and then continue up to NaClO3
I am here for chlor alkali process then i found that amazing experiments and i just click the subscribe button
Realy informative!!!! Thank you!! Having a hard time understanding neutralizing the chlorine gas?
Glad you found it helpful!
There's nothing too complicated about neutralising chlorine. In this video, we just lead the chlorine into a sodium hydroxide solution. As it passes through, it reacts with the solution to form bleach, preventing the chlorine from being released as a gas.
@@ScrapScience thank you so much… iv bin trying to understand that for few days lol!! Im going to try this experiment today:) iv learned alot from you.. keep up the good work friend!
I've subscribed your channel, it's pretty cool!
Please make more videos.
Helpful video, I was thinking of using this process to generate KOH.
Two questions: are you in NZ?
Where did you find the little alligator clips?
Very nice, I've always found KOH very difficult to find.
As for your questions, I'm actually in Australia, and I believe I got the alligator clips from Jaycar electronics, it was a while ago though so I might be wrong.
That's easy, he got the alligator clips from an alligator. There's one species whose jaw is made of stainless steel, just go hunt that one.
This is just what I was looking for!👍. Thanks
Great video. Any plans to combine the H2 and Cl2 into HCL?
I'd love to eventually, I'm currently working on a larger scale cell which should produce Cl2/H2/NaOH at a faster rate, and if I ever figure out how to combine H2 and Cl2 safely, I'll definitely give it a go. I think I already have a UVC LED which should be ideal for initiating the reaction.
@@ScrapScience what about you burn the hydrogen, add chlorine to water to get hydrochloric acid and hypochlorous acid, and put it under strong sunlight for hypochlorous acid to break down into hydrochloric acid and oxygen gas
H2O (l) + Cl2 (g) -----> HCl (aq) + HClO (aq)
2HCl(aq) ----sunlight----> 2HCl (aq) + O2 (g)
@@ScrapScience the reason why i suggest this method is because mixed hydrogen gas and chlorine gas can explode under sunlight, so i would suggest a safer process. Hope this helps.
29:16
I used this method to generate chlorine.
To do this, I cut some Plexiglas into a circle so that it would fit about 1 CM below the top of the clay pot.
I drilled a hole in the center of the Plexiglas to fit a carbon rod.
Also a hole to place a small gas fitting and sealed the whole thing with electrician's putty.
The chlorine was dried with some calcium chloride in a glass tube.
In the pot, was very concentrated salt solution.
Salt solution?
@@GrocaR
OK, brine
Hi nice video.
If you would make 2 kg of sodium hydroxide.
How would you make the setup.
And using seawater.
Regards.
Seawater generally isn't a good idea, as your product will always contain some impurity as a result.
If you want to make a bigger cell, you can watch my other video on the topic:
ruclips.net/video/iZH5fB0iM7U/видео.html
Can we use clay pot as a membrane?
Yep. In fact, I talk about doing that at 29:04
I've also made another video where we give it a go:
ruclips.net/video/iZH5fB0iM7U/видео.html
@@ScrapScience Thanks
You can use a sheep cecum, a lambskin condom if can tolerate PRICE think have to wash surface, used with palladuim diluted acids. Was looking for a longer term solution, test tube shaped porous ion exchange proton well hydrogenation. H2. Probably cost him 12-20 🇺🇸 $ or conversion as of now where live fiat numbers. Could heat and drop tube pipe borosilicate 3.3. Only have 8 inch 20mm 8mm left gas tube. Hope can make palladium electrode needs high surface area. Can't find but in grams, and expensive for hobby. Neverctsught green electrochemistry or microwave ultrasonic. Just organic, lab had all guy drove into ground to steal ipo money and make golden parachute. Told me to sabotage steal precious metals spend, neverxdid made neural growth factor as undergrad with MD PhD. We could all use or know one could. Love folks sharing knowledge, when world is so poor outside west.
Wouldn't chlorine gas be reduced to chlorine ions at the anode and the hydrogen molecules beging oxidised into hydrogen gas ??
Plss solve my confusion I've got exams nearby in 2 days bro
Love from india 🇮🇳🇮🇳
No. Oxidation occurs on the anode, and reduction occurs on the cathode.
The anode oxidises chloride ions to chlorine gas, and the cathode reduces water molecules into hydrogen gas and hydroxide ions.
excelent video! congratulations
Hi . and what was the percentage of chlorine. ? Was it a success or was it a failure?
it was sucsexful.
Hi pretty cool experiment you did there ! I found articles about how to make H2O2 with electrolysis in alkaline solution. Did you try that ? Do you think it´s possible as experiment ? Your pot would be a good seperator indeed :)
That's definitely very cool! I did a quick search for some articles on the topic and as far as I can tell, it looks relatively feasible to do without too much fancy equipment (though the yield might be considerably reduced when using clay pot separators instead of ion exchange membranes). Hopefully I'll get onto trying to make some gas diffusion electrodes soon, then I'll definitely be keen to give this a go. Thanks for the idea!
Yes the gas diffusion electrodes and membranes seem to be somewhat expensive. Do they last a long time ? Take a look at this Patent it´s very interesting US4357217A. You are welcome I am curious to see more videos from you :)
Sorry for the late reply, only just saw your second comment. The patent certainly looks very doable I think, as does the paper linked with it. Hopefully the electrodes should last a while, as cathodes I think they should as they aren't under oxidising conditions and don't seem to contain a catalyst.
I've just finished making a simple gas diffusion electrode which should hopefully work for this, so once I get a little more equipment I'll definitely give this a go.
No worries it´s ok. As it seems 9% is made in the paper but it doesn´t say you can´t make 30%. So it would be really cool If it goes that high. You don´t need to buy it anymore just switch on your power and make some :D I also have an idea how to store it forever. Do you know If H2O2 reacts with carbonates ?. You could make barium peroxide from barium carbonate and store it dry until you need H2O2 then you just have to dissolve it in water and filter the barium hydroxyde out again and use it later.
Wow U-R a Genius...
I have few questions but before i aske them i wanna really to thank you alot for making such clear video:1.Why we dont pour brine in both sides,i mean it will improve conductivity?shouldnt chlorine ion pass trough membrane just like sodium ion?2nd question is:how you protect your copper electrode,shouldnt it react with formed NaOH?
Great questions!
1) Putting brine in both chambers would work perfectly fine, the sodium ions would migrate to the cathode and chloride ions would migrate to the anode as you'd expect. The problem, however, is that this migration of ions never actually reaches completion, so there will always be some residual chloride contamination in the NaOH product when performing the reaction this way. Just putting the salt into the anode chamber avoids this, as the only reactant entering the cathode chamber becomes the sodium ions, allowing for pure NaOH to be generated.
2) Copper doesn't actually react with NaOH solutions under normal conditions, so corrosion/dissolution doesn't occur. Even if copper did react with NaOH, being used as a cathode makes it 'cathodically protected', making it much more resistant to oxidation.
@@ScrapScience thanks alot!Yesterday i made some NaOH in quite small quanities buit it worked!Thanks for great video and thanks for great explanation.
@@ScrapScience I was wandering about this as well. Most of the sources I've found describing the diaphragm method state that brine is introduced into the anode chamber and allowed to flow into the cathode chamber. There's no suggestion of anything initially being in the latter. And, since historically the diaphragm of choice was asbestos, wouldn't the brine find it's way to the cathode sooner or later in any case? As I've understood it, the contamination of NaOH is simply dealt with afterwards when using this method. I did try your method successfully, but I used gelatinized potato starch in place of vegetable gelatin, and it took a long time to get going properly. Will be using in the future though should I want to make clean NaOH, for now I'm more interested in the chlorine and hydrogen :)
A few decades ago. I operated a small membrane cell commercial chlor-alkali plant for the production of sodium hypochorite (the cholrine and sodium hydroxide were combined in a seperate reactor). On startup, we would put sodium hydroxide in the cathode side. This would keep the conductivity up until it started producing its own sodium hydroxide.
@@michaelgates991 The biggest disadvantage to the old asbestos diaphragm cells was that the NaOH produced had quite a bit of salt contamination. Most of the salt would precipitate out when the NaOH was concentrated, but there would still be a significant amount of salt in a 50% NaOH solution.
Can unglazed terracotta be used as a membrane instead?
It certainly can, and it'll work very well. Unglazed terracotta is essentially the same stuff as the clay pot I talked about at 29:04.
Does the length of the permeable substance matter?
A shorter (or a larger cross sectional area) membrane will drastically decrease the resistance of the cell at a given voltage. This allows for the cell to be run at a lower voltage for any given production rate, increasing the efficiency (based on energy usage).
Basically, a shorter membrane makes the process quicker, and more efficient.
@@ScrapScience Does a shorter membrane not hinder the effectivity, making OH travel to the anode even easier?
Hello, good content, You use titanium anode, right?
no its carbon
no it's teat-anium. or tight-anium.
Ay bro, can you please tell me all the materials needed to make a model of this? I really need it for a science exhibition project. (Sorry for bad grammar)
Can you please make a video showing what occurs what you apply a current to typical hydroponic nutrient?
what are the ingredients of the vegetarian gelatin? We don't have that brand here.
From the back of the box:
Dried Glucose Syrup (From Corn), Gelling Agents: Carrageenan. Locust Bean Gum, Stabilisers: Potassium Chloride, Calcium Acetate.
If you don't have access to vegetarian gelatin, you also have the option of using agar or carboxymethyl cellulose which work in a similar fashion. If you're really stuck, you can use any semi-porous membrane like cotton, fibreglass, or even a clay pot, which all last much longer than any gel (but at the cost of slight contamination between the cells).
I have some strontium chloride that I want to turn into strontium hydroxide. Do you reckon this process will work for separating the chlorine from the hydroxide in it as well?
Yes, but it would be easier to use a double displacement reaction since the solubility of strontium hydroxide is so low.
Would a ptfe tube with pin holes in it work? Fluid would be restricted pretty well but a currant would go through? I could put it in a coil on the bottom with both ends connected to cathode so its a semi closed loop.
It would work, but having such small channels for current to pass through would diminish the reaction rate significantly.
Could I use the clay pot method that you used generating sulfuric acid?
Yep. In fact, I talk about just that at 29:04
@@ScrapScience won't the sulph-uric acid react with the clay pot and damage it or probly carry impurities with it?
@Divad Ignawm It turns out that the clay in clay pots won't actually react with sulfuric acid, they hold up very well to most acids and bases.
Should the clay pot not have a hole in it?
Ideally, no, it shouldn’t have a hole. Those types are pretty tricky to find though, so it’s often necessary to simply plug the hole with a stopper or some silicone.
The fourth anode option is stainless steel, but at high currents it tends to oxidize as well.
You can use stainless steel wool for both electrodes (like the kind in dish scrubbers) because it has a lot of surface area, and same current/larger surface area = less corrosion.
I'm afraid stainless steel isn't really an option for the chloralkali process. While stainless steel does well under anodic potential in extremely basic solutions, a chloride solution is a whole different story.
When used as an anode in a chloride solution (regardless of current density), the corrosion rate is so fast that virtually no chlorine is generated, and instead the solution fills with soluble iron and chromium which contaminate your hydroxide product considerably.
There are many things that stainless steel works well for, but chloride electrolysis is such a harsh environment that it doesn't quite cut it.
@@ScrapScience ah, didn't know that. thanks for the tip!
@@ScrapScience The commercial chor-alkali plant I operated used titanium anodes with a proprietary coating (contained platinum and rhodium and maybe some other exotic metals). We still had to be careful, as even these would break down if operated at too high a voltage. It used mild steel cathodes, though the cathodes were problematic, as any leakage of chlorine to the cathode side would cause corrosion, and contaminate the product with rust.
Do you have solve a problem. ..
How to liquify tallow fat in to room temperature. .just like oil. .
So to do this with mercury you'd use mercury in place of your jellatin membrane. Is that correct? With the same setup you used.
Not quite.
It would be very similar, but in that case, the cathode should actually be the mercury itself (ie. instead of having the cathode on the right hand side sitting above the mercury, it should directly contact the mercury to supply current straight to the liquid metal).
For a mercury cell like this, it is only in the left chamber that electrolysis should occur, where chlorine is liberated on the carbon anode, and sodium metal is dissolved in the mercury cathode. Once dissolved in the mercury, the sodium should migrate over (this would probably require stirring the mercury somehow) and redissolve into the water of the right hand chamber, forming sodium hydroxide.
It's definitely a process I'd avoid to stay clear of any mercury contamination.
@@ScrapScience I hear ya lol. Thankyou for reply. However I ask to explore the science behind it. But I doubt I will. You should check out my channel. It's a chemistry channel also I'm still very small yet. Got some good videos tho. Stay safe mate.
Packed parchment paper works as a diaphragm separator.
Hi. New subscriber. Whjen you conducted the electrolysis without the membrane was that bleach you made ? Thanks
Only a small amount, as the hypochlorite ions are oxidised to chlorate quickly after they are generated. The electrolysis never really generates a useful quantity of bleach, nor is it ever pure enough for use as bleach.
@@ScrapScience Do the hypochlorite and chlorate (and hydrogen) ions not go through the gelatin membrane? Because Cl2 dissolves in HCl and HClO
@@ScrapScience The chor-alakli plant I operated was used to make sodium hypochlorite. But it used membrane cells, and the chlorine and NaOH were reacted in a seperate vessel. For one thing the cells operated at too high a temperature (150-170 degrees F) for hypochorite production, the NaOH solution was cooled and then the chlorine from the anode side was bubbled into it. Another consideration is that, in order to be stable, sodium hypochlorite requires excess NaOH. The system I operated had a pH probe and additional NaOH was added for stability. In order to make stabe hypochlorite with a chlor-alkali system, you have to either use additional NaOH or divert some of the chlorine to another use. Higher temperatures and lower pH favor chlorate over hypochlorite. Sodium hypochlorite under the best conditions (low temperature, low concentration, high pH, no metal contaminants) is not very stable. It tends to break down either to sodium chlorate, or to salt and oxygen.
Can i make NHO3 by this process
Kind of, but the efficiency is terrible. I have a video on that here:
ruclips.net/video/2aRf0tSu6mc/видео.htmlsi=U7B-zK0Wmdge1Nb1
I hope u still there iam using diaphgram of claypot, sucessfully made about 1.5 L , but iam not sure if it was NaOH or NaClO because i smell Chlorine inside my claypot solution, corroded aluminum, but yellow-ish color, do you have any suggestion?
What you've made really depends on a few factors. What were your electrodes made of? Which one was the cathode/anode? Which chamber did you expect to get product in? What was the container made from in which you ran the cell? And, how much current did you run through the cell and for how long?
I'm afraid I can't really help without more info.
Chlorine smell and yellowish color is consistent with sodium hypochlorite. Color could also be iron or other metal contamination from anode or cathode.
I think Herry it is time you write a book. I will be the first to order. Look how many followers you have
Thanks
Wouldn't it bleach your pH paper?
Yep, the hypochlorite sure does. At concentrations like this, it's usually slow enough such that you can still get a pH reading if you're quick though.
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I have some questions
1. Will increasing the volts through power supply speed up the NaOH production ?
2. Is there some way to calculate the volts required for electrolysis of X amount of salt / Or salt water / Or Electrolyte
Thanks in Advance
As a matter of fact, I have an entire video on optimising this reaction in terms of the concentration, voltage, current, and reaction times. You can find it here:
ruclips.net/video/OrEQkBOxmxg/видео.html
On top of that, you can also find a video where I build a functioning cell for producing reasonable quantities of hydroxide here:
ruclips.net/video/iZH5fB0iM7U/видео.html
If the chlorine gas is bubbled through regular water or hydrogen peroxide, will it produce hydrochloric acid?
(Edit Spelling)
Well, technically yes. However, the dissolution of chlorine in water will be very slow (hydrogen peroxide won't help anything here), and taper off over time, so the concentration of acid at the end of the reaction will be very low.
Also, the dissolution of chlorine also produces hypochlorous acid in equal amounts as it generates hydrochloric acid, which is a considerable and highly undesirable impurity in most cases.
Will live to see you make sodium from sodium hydroxide
One of these days I'll be brave enough
Ph check at 22:41
Hi . Someone out there who knows how to make Sodium Chlorite NaClO2 effectively. THANKS.
Here is a link I found. Needs to be revised, involves electrolysis of salt water I don't know how that would work. Hope it helps you get closer to what you need.
sciencing.com/make-sodium-chlorite-5188671.html
how can i make sodium hydroxide on a larger scale. please help
what are your contact details
I have other videos on scaling up this process here:
ruclips.net/video/OrEQkBOxmxg/видео.html
ruclips.net/video/iZH5fB0iM7U/видео.html
Can you make a nuclear reactor with the smoke detector's radioactive sensor please
I'm afraid it's not feasible. Even if it were legal and I actually wanted to do it, a self-sustaining nuclear reaction from the americium in smoke detectors would require at least ten billion smoke detectors, and that's being very generous with the numbers.
Should add that the salt u use is iodine free. As end product uses could potentially be sensitive
The benefit is not the sodium hydroxide, it is the chlorine. You could make massive amounts of chlorine for dirt cheap and for very long periods of time. Every other process for generating chlorine, if used over days or weeks it is very expensive.
So at the start you made bleach ...
At 13:00 i find myself watching a U-tube.
Thx but u kinda took like half an hr fr just 1 rea^n...time consuming though informative...so gud job
Wow this guy bought youtube
A U-Tube on RUclips.
The clay pot gives you a bleach cell.
Make sodium chlorate pls😌
He already made a potassium chlorate cell, the procedure should be identical for sodium chlorate
new industrial processes, replace with simple if necessary
experimental then eh
why dont you just update the potentials, no freaking overpot
try ionized electromagnetic separation methods
u-tube, insulated, high voltage static electric charged, y-tube, to feed in, u-tube outputs are electrons and ions
solid state electrolyte
Great stuff but I'll give you a dollar if you use a tripod
If you choose to watch any of the more recent videos I've made (anything within the past 20 months or so), I'm sure you'll be a lot more satisfied with the stability of the footage.
The white autobalancing is killing my eyes u.u
Hes talking aboyt guman expirementation. We r watching you. Mr gr@phene oxide
You talk too much and you don’t get to the project by doing people understand it when you do not a whole Lotta lip
Translation: I was too stupid to understand