Stereoselective Michael addition|Michael addition reaction mechanism|Examples|Carruthers chapter 1

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  • Опубликовано: 26 окт 2024

Комментарии • 128

  • @JChemistry
    @JChemistry  4 года назад +101

    Hi !
    I'm very happy; and at the same time, a bit nervous.
    Our J Chemistry is now getting blessings from Professors of prestigious institutes as well. I got an e-mail yesterday regarding part-7 of Carruthers series video that I uploaded a week back. It was from a kind professor, who took out time to send me blessings and few research papers regarding stereochemistry of Michael Addition.
    I really felt honoured. I went through those research papers and realised that I've made few mistakes while teaching this topic.
    I've deleted that video and this is the correct version.
    Not revealing the name of the professor and the institute, but J Chemistry is really blessed to have such viewers, such well-wishers 🙏.
    Thank you.
    I, genuinely, mean it :)

    • @sonalkhaitan469
      @sonalkhaitan469 4 года назад +2

      Blessed to have you as a teacher ✍

    • @buddhadebmondal5531
      @buddhadebmondal5531 4 года назад +3

      At 37 I did not understand why the major was that having Me nd OtBu grp.... Bcz in clayden it was trans... According to Houk model thecis is unstable I think..One thing you can say that THF is not Li+ chelating agent thus repulsion betn LDA moiety nd Me.. may be that is the main driving force... Again if it is reported then ok as we all know in Organic we get the product then we make the reason😂😜

    • @buddhadebmondal5531
      @buddhadebmondal5531 4 года назад +1

      Ok mam I have one idea... You can make that molecule in chemdraw nd then by mm2 calculation we can see the PE of those 2 molecules from there we can conclude... I have chemdraw version 2012 where we can't run the structure... If you have 2019 version you can check mam... Thank you😊

    • @archita5236
      @archita5236 3 года назад +1

      Maam 58:43 par apne conme2 jasa bulky group axial par kyu lagya?

  • @malikurfiurfi4557
    @malikurfiurfi4557 4 года назад +10

    Really all rounder ..💞 multi-talented Mam👍

  • @primechemm..3246
    @primechemm..3246 3 года назад +3

    Madam ji, aap ki best ability is that you enjoying while teach👏👏👏👌👌👌 not only that you are trying give us best. 🌷🌷🌷

  • @bidhankumbhakar7771
    @bidhankumbhakar7771 4 года назад +3

    Didi apne jo correction kiya aur sbke samne bola , Jabra fan ho gya ❤️

  • @nazirchemistry846
    @nazirchemistry846 4 года назад +2

    Best ever teacher i had ever seen.. Multi talented mam.. May god bless u..

  • @sunilk917
    @sunilk917 4 года назад

    Your knowledge is very best.....
    Your need for rural student..
    They don't attaining coaching in city...
    Thanku so much.......

  • @vinayakwalhekar2089
    @vinayakwalhekar2089 4 года назад +2

    Hello, I was waiting for this part of the lecture because you covered the stereochemistry part of Micheal Addition reaction, very few teachers in the colleges teach this topic, this made my concepts more clear and I learnt some new concepts also. Thank you and we appreciate your hard work 👍👍

  • @AartiSingh-lp2sk
    @AartiSingh-lp2sk 3 года назад +11

    Mam , 38:25 min p O-butyl ko preference nhi milagi compare to O-Li

    • @swatisharma4956
      @swatisharma4956 2 года назад

      Yes, I think the same

    • @subhashisrout9220
      @subhashisrout9220 2 года назад

      Yes o- tbu is more preferred as compared to o. So anti product is formed

    • @swatisharma4956
      @swatisharma4956 2 года назад

      @@subhashisrout9220 I have seen CIP rules O-M always get first preference except how much bigger the other group. So, video is right.

    • @subhashisrout9220
      @subhashisrout9220 2 года назад

      @@swatisharma4956 a/c to cip rule bond pair is more preferred as compared to loan pair and if u think OLi then also o- tbu is more preferred as compared to oLi.

  • @user-bx5zj1xy7v
    @user-bx5zj1xy7v 4 года назад +2

    Very helpful video ma'am ur teaching is very nice

  • @user-bx5zj1xy7v
    @user-bx5zj1xy7v 4 года назад +3

    Thanku so much ma'am for uploading this video

  • @brijeshgangwar3624
    @brijeshgangwar3624 4 года назад +2

    Madam meri aaj bhu ki answer key aayi hai jisme mere 224 marks aiye hai msc ke liye iye sara aap ki video dekh kar hi huaa hai thank you so much madam

  • @GoldCattt
    @GoldCattt Год назад

    Thank you mam.

  • @siddharthashankarkashyap1531
    @siddharthashankarkashyap1531 4 года назад +1

    Maa'm please do make a video on Robinson annulation also!

    • @JChemistry
      @JChemistry  4 года назад +1

      This has been covered. Watch next parts of Carruthers series.
      You'll find it

  • @nagateja8822
    @nagateja8822 4 года назад +5

    Tq so much mam, and please complete coordination chemistry

  • @joysarkar3808
    @joysarkar3808 3 года назад

    Mam, in 6:09 min only LDA is mentioned , no low temperature is mentioned so why don't we made TCP that means more substituted enamine for attack

  • @vaishalisingh5964
    @vaishalisingh5964 4 года назад +1

    Thanks a lot mam. 👍🙏

  • @priyankabhardwaj6867
    @priyankabhardwaj6867 4 года назад +1

    Thankiu mam for teaching please start thermo from physical please mam

  • @Sohitrao234
    @Sohitrao234 Год назад

    Ma'am acid ke presence me Michale addition hoga kya ??

  • @sukhjeetkaur6421
    @sukhjeetkaur6421 4 года назад

    Mam you are best

  • @prazveesingh5999
    @prazveesingh5999 4 года назад +2

    mam plz complete coordination chemistry. We request you.

  • @pallavibhosale6001
    @pallavibhosale6001 4 года назад +1

    Thanku you mam❤️......

  • @monikakherwal3917
    @monikakherwal3917 4 года назад

    Mam ...please make a video on previous year questions of association and dissociation reaction mechanisms in coordination compounds

  • @swetank4606
    @swetank4606 Год назад

    In 43:07 how oxygen attached to Si shows conjugation instead of oxygen attached to Me? As Si has empty d-orbital so here oxygen has less tendency to donate its lone pair in the conjugation.

  • @sumaiyyasayyad6977
    @sumaiyyasayyad6977 3 года назад

    So helpful mam🙏👍🙏👍

  • @bhartimakhija07
    @bhartimakhija07 4 года назад +1

    Maam disconnection approach par videos bna dijiye kuch

  • @shreemabehera
    @shreemabehera 4 года назад

    Mam app bahat achha explain karte hai per mujhe inorganic, physical aur organic mein doubt rehta hai

  • @hrishikeshpaul7540
    @hrishikeshpaul7540 4 года назад

    Mam jo enamine wala system mei conjugate addition hua fir H3O+ ke sath workup kiye to ismei iminium ion ketone mei convert ho gaya par nitrile group carboxylic acid mei convert nahi hoga??????

  • @koushiksantra1270
    @koushiksantra1270 3 года назад

    In this, since temperature is not given, it indicate that the product formed should be thermodynamically stable. so the thermodynamically stable product will be the one in which the proton is removed from carbon which is attached to ch3 i.e more substituted double is formed. isn't it?

  • @vrushalipanchal3528
    @vrushalipanchal3528 4 года назад +1

    earlier exmpl mai explain kiya tha ki More stable carbanion less reactive na.. then y here (52:00 exampl mai ) most stable carbanion react

  • @firdosjahanzabiullah6707
    @firdosjahanzabiullah6707 4 года назад +1

    Thnk u maam❤️

  • @HarshitSharma-sh7ju
    @HarshitSharma-sh7ju 4 года назад

    Thank you so much mam 😊

  • @chanchalsharma2738
    @chanchalsharma2738 4 года назад

    Mam jis question m aapne carbon count m mistake batayi tha kya usme last step m CN ka hydrolysis nhi hoga kya

  • @rishabhmaurya5439
    @rishabhmaurya5439 4 года назад +1

    Mam you asked a question that if there are 5 ligands instead of 6 what is splitting energy please upload the solution
    If a
    ny one know this please tell e

  • @schoolofchemistry6376
    @schoolofchemistry6376 4 года назад

    Thanks a lot maim

  • @realityoflife53
    @realityoflife53 4 года назад

    Ma'am u are very good☺😍🤗

  • @kimmygarg1229
    @kimmygarg1229 4 года назад

    Mam, good evening .I have a doubt. Agr double bond ki side me carbonyl or nitrile dono group hain like at timing 16.00 , dono k pass hi double bond hai.. to 1,4 addition kis side major Product dega??

  • @topicalchemistry3320
    @topicalchemistry3320 4 года назад

    Enamine me last step me CN ka hydrolysis keu nahi huya mam.

  • @rounakraj7943
    @rounakraj7943 4 года назад

    Mam physical chemistry ke sare important formula ka video banae na for IIT JAM mam!!

  • @chemstarclasses2622
    @chemstarclasses2622 4 года назад

    Ma'am ye book comolete krva dijiye yha plz bhut achhe se krva rhe ho aap streo hi smjh nhi aa rhi thi jo aapne bta di achhe se so plz ma'am NET exam se phle complete krva dijiye

  • @brotherstrust5189
    @brotherstrust5189 4 года назад

    Mam aap na mara chemistry ka prti lagaw ko bhuat jada kar diya, aap na hama bata diya ki agar ham acha sa chemistry padta h to life ma bhuat kuch kar sakta h, muja lagta ta bas profeser hi ban sakta h.

  • @bestisyettocome2590
    @bestisyettocome2590 4 года назад

    Thank you ma'am

  • @devashishsingh1994
    @devashishsingh1994 4 года назад

    Mam what happened with j chemistry telegram group?

  • @swatichafle6067
    @swatichafle6067 4 года назад

    Mam jaise tbutyl grp me E enolate aapne major bataya waise har case me bulky group rha to kya E enolate hi major rhega kya

    • @JChemistry
      @JChemistry  4 года назад +2

      Agar wahan Ot-Bu ke place pe t-Bu hota, toh Z major banta

    • @swatichafle6067
      @swatichafle6067 4 года назад

      @@JChemistry thank you so much mam for ur reply❤️❤️❤️❤️

    • @ajay_kumar233.
      @ajay_kumar233. 4 года назад

      Mam mere ko bi ye samaj nhi aaya

  • @kalpanakolhe8671
    @kalpanakolhe8671 4 года назад

    58:26 min pr, both -me and -ome group equatorial position pr aa sakte h na to bhi trans hota....

  • @queendresses3166
    @queendresses3166 4 года назад +1

    Thnx👍👍😊

  • @juberchoudhury9881
    @juberchoudhury9881 4 года назад

    M'am, please try to complete the chapter 1 before Nov exam

  • @SainiShubham7500
    @SainiShubham7500 4 года назад

    Mam please tell me ki gate ma kitna questions krne chahiya ......idea base pr ki clear ho jy

  • @madhurishelke3864
    @madhurishelke3864 4 года назад

    Ma'am Carruthers series bohot achhi hai.... Thank you so much dear Ma'am... Love you.. 💟😍

  • @Alvi_moinudinbapu
    @Alvi_moinudinbapu 4 года назад

    Please make vedio on iit jam 🙏🙏. Please guide us on booklist and etc.

    • @YogeshMaurya34
      @YogeshMaurya34 4 года назад

      Mam ke sare vedio Dekh lo
      Top Ka pta nhi
      Ha selection पक्का हो गा

  • @gopalsrivastavateaches6878
    @gopalsrivastavateaches6878 4 года назад

    5:06 why is less saturated product choosen here when no heating is done? Wy is not H next to me not removed? Please explain

  • @vivekanandchaubey510
    @vivekanandchaubey510 Год назад

    38:34 ye o-c>0-li to z hoga na

  • @pavithraNarasiman
    @pavithraNarasiman 3 года назад

    45:01 in presence of Lewis acid chelation happen , when incoming gp does not have any het atom then in that case how it will chelate

  • @harshittripathi735
    @harshittripathi735 4 года назад

    Thanku mamm🥰

  • @Rahul_Thakur8630
    @Rahul_Thakur8630 4 года назад +2

    Did First view
    Thank you❤❤😊😊😊😊 Didu

    • @archita5236
      @archita5236 3 года назад +1

      Kya apko pata hai 58:21 par mam ne conme2 jase bulky group axial position par kyu lagya?

    • @archita5236
      @archita5236 3 года назад +1

      Sorry 58:42 par

  • @Kitanber_illoo
    @Kitanber_illoo 4 года назад

    Well defined stereo

  • @rabinarayanabehera2154
    @rabinarayanabehera2154 4 года назад

    Mam jo elimination hua ester ka kyun nahi hua. S=Oph ka kyun hua

  • @souviksarkar9315
    @souviksarkar9315 3 года назад

    mam hydrolysis me ome ku nehi attack kar raha instead of h2o 6:06 me

  • @radhekrishna5138
    @radhekrishna5138 4 года назад +1

    Thanku mam..1st comment😊

  • @renukakeshwer2214
    @renukakeshwer2214 4 года назад

    I wish ki life m ek baar aapse jaroor milu🤗🤗🤗

  • @chemistrymanthan9909
    @chemistrymanthan9909 4 года назад +2

    Nice mam 👍

  • @bikitalkschem0608
    @bikitalkschem0608 4 года назад

    Mam..... upload more vedio lessons of Caruthers

  • @asifseikh8541
    @asifseikh8541 4 года назад

    Mam electrochemistry k baad ap dusra kaun sa topic start karwane wale ho ?

  • @amitbarsiwal4841
    @amitbarsiwal4841 4 года назад

    Mam C-C double bond kab start karwaoge ...?

  • @hellohello-fo9on
    @hellohello-fo9on 4 года назад

    Mam inorganic chemistry bhi start kra do 😐 chapterwise starting se

  • @ritika1490
    @ritika1490 4 года назад

    Mam topic on demand me stereo of Ene reaction bta dijye...plzz...🙏

  • @sharanunhiremath9514
    @sharanunhiremath9514 4 года назад

    Mam full coordination chemistry video karo mam pls....

  • @subhradeepkar6468
    @subhradeepkar6468 4 года назад

    Can anyone please help me. I want to buy the test series. Are they valid now?

  • @ajay_kumar233.
    @ajay_kumar233. 4 года назад

    Thankuu so much mam
    Mam one reply plzz

  • @sarswatibhadre9920
    @sarswatibhadre9920 4 года назад

    Thx mam 😊

  • @arpitabal3477
    @arpitabal3477 4 года назад

    Mam 2020 me tifr ka application form kab start hogi

  • @KAVITASINGH-wo4ve
    @KAVITASINGH-wo4ve 4 года назад

    Good afternoon Mam
    Mam mujhe IIT JAM 2022 Ke exam ka preparation krna h eske liye mai apka online coaching join krna chahti hu .
    Mam mujhe fee ke bare me kuchh pta ni h kya ap mujhe btao skti h plz

  • @dchemistry7978
    @dchemistry7978 4 года назад +1

    So brilliant teaching mam 👍👍

  • @anuradhachaurasiya5640
    @anuradhachaurasiya5640 4 года назад

    Means last class ki video ko consider nhi krna h ??

  • @sibashankarjena8426
    @sibashankarjena8426 4 года назад +1

    Mam app bhi live class kijiye mam plz plz plz plz 🙏 🙏 🙏

  • @bhartisahu4665
    @bhartisahu4665 4 года назад

    Mam memo mical addition m much problem h ....Jo ap tersary butail wala exam btaye ho usme E form liye ho WO glt lg RHA h oxigen ko fist preorty deye ho ap WO Kaiser mam

    • @NMfiles348
      @NMfiles348 4 года назад

      Mam ne 10th part of carruthers series bataya h ki agar oxygen kisi metal ke sath hoga to use first priority di jayegi jaise oxygen lithium ke sath h

    • @prayagrajvloggersahai6141
      @prayagrajvloggersahai6141 4 года назад

      Jo methyl ke side oxygen hai uske priority 2 kyu hai

    • @NMfiles348
      @NMfiles348 4 года назад

      @@prayagrajvloggersahai6141 kaun se question me

    • @prayagrajvloggersahai6141
      @prayagrajvloggersahai6141 4 года назад

      @@NMfiles348 jisme E bataye thi Me and ots ek side me tha or H ir O_ ek side per

    • @NMfiles348
      @NMfiles348 4 года назад

      @@prayagrajvloggersahai6141 Kya tum us ex. Ki baat kr rahi ho jisme o_and ot-bu ek side aur Me and H ek side h

  • @medicalbiochemistry_
    @medicalbiochemistry_ 4 года назад

    Great

  • @pijushdhali624
    @pijushdhali624 4 года назад

    15.38- jaldi main sayed COOEt likh diya COOMe hogaa didi😅

  • @sibashankarjena8426
    @sibashankarjena8426 4 года назад +2

    First like first comment first view

  • @princekumar-pj7bq
    @princekumar-pj7bq 4 года назад

    मैंम यह क्या पढ़ा रही है? हम ऐसे QUESनहीं देखे है ¡

  • @Makeover_bysimran
    @Makeover_bysimran 4 года назад +1

    hello ma'am

  • @anuradhachaurasiya5640
    @anuradhachaurasiya5640 4 года назад +2

    ❤️❤️

  • @kiranmdn9979
    @kiranmdn9979 4 года назад +1

    First viewer😃

    • @kiranmdn9979
      @kiranmdn9979 4 года назад

      Mam j chm lab to aahi nhi rhi kb se wait kr rhi😒

  • @Subha_Karmakar
    @Subha_Karmakar 4 года назад +1

    👍👍👍👍👍👍👍

  • @susantamaity598
    @susantamaity598 4 года назад +1

    1st viewer 😁

  • @62.thoithoiproton65
    @62.thoithoiproton65 4 года назад

    Please teach in english medium

  • @vidyajangid7277
    @vidyajangid7277 4 года назад +1

    U r very gorgeous mam

  • @ponmanikuppusamy3511
    @ponmanikuppusamy3511 4 года назад

    Please make videos in English 😭

    • @YogeshMaurya34
      @YogeshMaurya34 4 года назад

      Kyu Hindi nhi aati क्या
      English man😠😠😠😠😠

  • @chemistry9131
    @chemistry9131 4 года назад

    Mam one small enquiry mam,,,is BD Gupta and Ajay Kumar is enough for coordination chemistry and OMC,,, and for chemical Bonding, bioinorganic ke liye ap konsi book prefer karogi

    • @JChemistry
      @JChemistry  4 года назад +2

      Yes these books are more than enough
      Just practice previous year questions once you complete the theory portion.
      Bioinorganic bhi you can do from Ajay Kumar.
      For chemical Bonding, there is no specific book as such.

    • @chemistry9131
      @chemistry9131 4 года назад +1

      @@JChemistry thanks mam

  • @jatinpatro3541
    @jatinpatro3541 4 года назад

    Thank you mam.

  • @chhaganlal7617
    @chhaganlal7617 4 года назад

    Thank you so much mam🙏🙏🙏🙏

  • @sonubala7400
    @sonubala7400 4 года назад

    Thanks a lot mam 🥰

  • @prithapal3340
    @prithapal3340 4 года назад

    Thank you mam❤️