At 6:38, mam i have a doubt that if heteroatom breaks due to repulsion so why , mcpba breaks hydrogen not from -0-0- bond or why it even exists so... If it eventually breaks up
Mam apne bola ki in baeyerr villiger oxidation the migrating aptitude is ph>h>r but mam if r is the tert-butyl group then the order will be same or different
Ma'am 6th example is mentioned in Carrothers ..but there they have given the migratory aptitude product mentioning it will give 'abnormal' product.. ma'am can u please explain it?? Ma'am is there any stereochemical change due to this reaction?? Specially in cyclohexane ring??
Mam sorry for that, but acc. to my view and your teaching the last 2 answer are wrong i think. Beacuse in Q- 7,8 both answer have 1 carbon missing on ring.
Actually C-atom less Nahi ho Gaya.mam fast bolaneke vajesi miss kardiya ... Number of Carbon atoms present is reactant should be equal to number of Carbon atoms in product
Mam , please suggest me reference Book for ...1,2 ketone to anhydride using Baeyer Villiger Oxidation...I didn't find it in clayden, Carruther, Nantz, MB smith , ji jack Lee, mundey , Normon coxon ,Laszlo Kurti ...under Baeyer Villiger Oxidation heading..& even in 12 th Std NCERT Book... Please suggest me any reference...
Thanks a lot for this awesome video on BVO. Especially, Loved the examples showing steric factor dominance over migratory aptitude..
Mam i am iit aspirant... Many times for mechanistic understanding of organic reactions I watch ur lecture... Lovely content mam... Thx.
Best video !!!!..poore youtube par merko kahi nahi mil raha tha BVO ka dhanka mechanism..thank god ye video mil gaya🙏🙏
Thanku thanku thanku thanku ma'am ap itna soachte h hamare bare mai, ma'am carbene kerwa dete usse mai bhut confusion hota .. please please ma'am.....
Very useful for IIT-JEE also, thanks!!!
you are so best teacher in my life. thanx
Madam , your Demonstration is so easy to realize. Thanks mam
Dhanyavaad ma"am 🙏🏻🙏🏻 JAM ke liye jitne bhi important name rxn h please main jaldi upload karne ka prayaas kijiye😊
S I understood very easily. Thanks a lot. U r good teacher.
Your videos are really helpful for iitjee too.
Mem aapka ye knowledge h sab vo aapne books me pad kar khud sikha ya aapko bhi teaching se aaya ... really I appreciate after this video
Best teacher ever 😍😘😘😘😘😘
At 6:38, mam i have a doubt that if heteroatom breaks due to repulsion so why , mcpba breaks hydrogen not from -0-0- bond or why it even exists so... If it eventually breaks up
Thank you mam
Very nice explaination 👍🏻👍🏻🙏🏻
SHORT TRICK WAS AMAZING 😍😍😍😍
Nice 1👌
Thank you didi🙏🏼🙏🏼 it's very helpful for us
Thnks a ocean to you.......Thnkuuuuuu so much mam for such a superb explanation
Ma'am I have a doubt about migratory aptitude. Some where it gives as tert,sec,phen and then prim. Which one is correct
Mam apne bola ki in baeyerr villiger oxidation the migrating aptitude is ph>h>r but mam if r is the tert-butyl group then the order will be same or different
Very nice explaination
Thanku mam
Love You Ma'am. Very nice explanation.
Mam your teaching is very excellent
Ma'am in product no. 7,8 one carbon atom each is missing. Please correct me if I am wrong
Yes
Mam,the order for migratory apptitude you taught is wrong. As 3degree alkyl has higher migratory aptitude than phenyl in Baeyer Villiger Oxidation.
Didi love you so much...aap itna axcha samjati ho
Tq so much very nice attractive and clear understanding video
Mam if aldehyde will result into carboxylic acid then migratory aptitude of H is greater than Ph
Hello ma'am,mai kai jagh dekhi ma'am migratory aptitude in BVO ,H is greater than pH and 3R is greater than pH hai ,ma'am I am totally confused
In clayden it is given 3°>ph >2° >1°
your videos are informative
Excellent questions
Gazab❤️
Ma'am Carruther me pg 400 pr BVO me aapke explanation se kuch variation h pls explain
Thanks di ,yahi Kara do,or practical inorganic chemistry ke bare me bata do
Is the migrating order
3°>2°>benzyl>phenyl>cyclopropyl>1°??
Mam, when will be answer key of CSIR NET December 2019 will upload?? And when result of the same will declare??
Really nice J mam
Very good mam😊
Your lecture is very nice. Can u please explain the example no. 6 in light of Carruthers page 400 example.
Mam ek confusion h aapne btaya ki ph ki m.g. power jyada hoti h.To first question me aapne usse migrate kyo nhi karaya..
Yeah I have the same confusion too
Ma'am 6th example is mentioned in Carrothers ..but there they have given the migratory aptitude product mentioning it will give 'abnormal' product.. ma'am can u please explain it??
Ma'am is there any stereochemical change due to this reaction?? Specially in cyclohexane ring??
amazing mam all clear
Is there same migratory order in cumene to phenol conversion mam?
Do you have any reference for migratory aptitude that you have shown... bcz I can see everyone is teaching different migratory apt. for BVO
Same here
Same
Order is H>pH>R not pH>H>R
U r best❤
Mam,migratory aptitude H ka jayda nhi hota kya ph se
Nicely explained
Thanks
If acid forms from aldehyde then migratory aptitude is higher for H then where is exception of Ph>H?
Mam sorry for that, but acc. to my view and your teaching the last 2 answer are wrong i think. Beacuse in Q- 7,8 both answer have 1 carbon missing on ring.
yes i also noticed the same one
ma'am 20:40 mein product me c-atom less kaise ho gya or o-atom waha nhi lagega
Actually C-atom less Nahi ho Gaya.mam fast bolaneke vajesi miss kardiya ...
Number of Carbon atoms present is reactant should be equal to number of Carbon atoms in product
👍👍
Best
Mam actually ist reaction me book me methyl benzoate main product bta rakha h.. Companion chemistry dinesh class +2 me
Mam alpha effect kya ha mam
Thanks mem but 7&8 Ans me aapne one carbon miss kiya hai
ma'am, your videos are really nice but i had a problem with the mechanism of anhydride formation from diketone: can you please help with that
Is there any possibility for a second bayer viliger oxidation on a cyclohexanone
Mam is reaction ka reduction vaala bhi bataiye plz
Ma'am how we will know when shd we apply steric factor or MA?
Plz ans this mam
In cyclic system
Order of migration aptitude is wrong. It is just H>3>2>ph>1>methyl
Mam u told that migration step i am still confusig methy prefer first than hydrogen Ya fr hydrogen prefer methy
I am student of class 11th mai app ka vedio kaha se suru karu chemistry
Mam (per acids ) se alkenes jo apke question mein hai wo epoxides
Bhi to ban sakta tha?Please reply🤔🤔🤔🤔🤔🤔🤔🤔
Arey wow🥰🥰🥰
Mam I think last 2 questions ka answers mey apna 1carbon galti sa kom likha hain
The langouge very dificult why you dont speak inglish but you are good teacher❤
Mam yaha pe benzene kyu migrate nahi kiya uska migratory aptitude jyada hai na
I think, in third question formate should be formed because all aliphatic aldehydes give acids not all aromatic aldehydes with peracids
Mam please make a video on perkins reaction
Mam hme kese pta chlega ki steric factor work krega Jo aapne examples krvyaye unke alava
Mam in Bayer willigar oxidation hydrogen has more priority than phenyl in migration
Good representation madam
The last two reactions, you missed one carbon atom for the products
Yes ..I had also doubt
Galti se mistake
Mam aap mcpba ae ke sath kyu h2o2 le rahe ha hamara sir ne bola ki h2o2 ke sath naoh lete hai
Excellent
Mam please linear and conversion synthesis , reterosynthetic approach wale topics pe bhi vedio upload kro please
Question 7, it is quarternary carbon as no 'H' is attached.
Even the compound she used to explain the mechanism has no hydrogen....
thank you so much sis
it helped me so much in my last minute revision for jee advanced 2020 .
Ma'am agar do ph group hai ne ek pr EDG laga h nd next ph pr EWG then kiska migratory aptitude jayada hoga ??? Which ph will migrate first ??
Thank you so much Mam. 😊
Mam plz share a video on dess martin reagent
Love you Jyoti di 😘😘😘
Why diaryl ketone doesn't show this reaction
Madam 7 & 8 answers oxygen add in between carbon and carbonyl carbon but you write in the place of carbon madam
Mam last 2 examples hv 1 lesser carbon.
Thank you ma'am 😊
Nyc ma'am
Mam last wale do reaction me Apne wrong product bnaya hai
Too good
Main bad mein to krta hi hu q paer dekh ke but agar to padate padate hota hai to its too better
Really mam ...your explanation is OSM ..tqsm 🤝❤️
Thank you very much mam 😊😍
Thank you ❤
Ph ka migratory aptitude zyada kyu ha ?
Teacher can you explain stesic factor
Thankyu soo much ma'am
Mam please its a request, hum Jo RUclips vale h jinhone J Chemistry app pe subscribe nhi kiya ,please unk liye videos thhodi aur bna do please
Mam , please suggest me reference Book for ...1,2 ketone to anhydride using Baeyer Villiger Oxidation...I didn't find it in clayden, Carruther, Nantz, MB smith , ji jack Lee, mundey , Normon coxon ,Laszlo Kurti ...under Baeyer Villiger Oxidation heading..& even in 12 th Std NCERT Book...
Please suggest me any reference...