A hydrogen sulfide generator using... a candle

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  • Опубликовано: 11 сен 2024
  • I explore an alternative way of generating H2S for an upcoming project that uses the reaction between paraffin and sulfur to generate the toxic gas. It doesn't feel like real science though. Subreddit: / explosionsandfire
    Join the Discord!! / discord
    Twitter: / explosions_fire
    Patreon: / explosionsandfire
    Music is as usual from the Aphex Twin soundcloud dump, track names are:
    - 40 Lannerlush Full
    - 17Elb1
    - 18Elb2
    Paper reference:
    "The Production of Hydrogen Sulphide by Heating Paraffine and Other Hydrocarbon Mixtures with Sulphur" (1930)
    journals.iupui...

Комментарии • 1 тыс.

  • @shekel8245
    @shekel8245 3 года назад +1594

    Upside down science man does mist magic

    • @EnRandomSten
      @EnRandomSten 3 года назад +37

      @redxpen that heart warming should not occur.... Have you made sure you still have your sense of smell?

    • @Dockhead
      @Dockhead 3 года назад +17

      @@EnRandomSten im thinking of a spray bottle you spray hydrogen sulfide with and it will block the smell of farts, you know if you have a lot of trapped wind sometimes.

    • @Alex_Was_Taken
      @Alex_Was_Taken 3 года назад +18

      ʇxǝʇ uʍop ǝpᴉsdn sǝɹᴉnbǝɹ uɐɯ ǝɔuǝᴉɔs uʍop ǝpᴉsdn

    • @dashingdave2665
      @dashingdave2665 3 года назад +9

      I keep watching to see inside out man...

    • @implausibleimpossiblehypot4006
      @implausibleimpossiblehypot4006 3 года назад +11

      @@dashingdave2665 look up Florida man I believe that’s as close to “inside out man” as your gonna get

  • @jeppekjer6138
    @jeppekjer6138 3 года назад +1761

    Always good to stop and think "How could this experiment have killed me?". It trains your critical thinking and builds up your paranoia levels at the same time!

    • @quint3ssent1a
      @quint3ssent1a 3 года назад +96

      Yeah, that thing with "maybe i shouldn't use air as a carrier gas in making H2S" got me laughing too.

    • @ngobmx
      @ngobmx 3 года назад +100

      Chemistry isn't chemistry without a healthy dose of 'fuck is this trying to kill me?'

    • @PotionsMaster666
      @PotionsMaster666 3 года назад +2

      @@ngobmx 😂

    • @jozkomrkvicka1281
      @jozkomrkvicka1281 3 года назад +12

      Don’t let NileRed see this comment xd

    • @AlpineTheHusky
      @AlpineTheHusky 3 года назад +8

      It builds your yolo levels too

  • @pavelkryl457
    @pavelkryl457 3 года назад +1761

    You really dodged a bullet by using a blue candle and not a yellow one. Imagine all the things that could have gone wrong!

    • @ExtractionsAndIre
      @ExtractionsAndIre  3 года назад +911

      Exactly! The blue was to counter the yellow of the sulfur, that's how the science works

    • @SteveEh
      @SteveEh 3 года назад +59

      @@ExtractionsAndIre but...but...you said it wasn't real science.

    • @Metalhammer1993
      @Metalhammer1993 3 года назад +122

      @@ExtractionsAndIre perfect alchemy response. this wasn't chemistry this was alchemy^^

    • @Death_of_Sound
      @Death_of_Sound 3 года назад +86

      @@ExtractionsAndIre blue + yellow = green, hydrogen sulfide is actually sneaky chlorine confirmed.

    • @woosix7735
      @woosix7735 3 года назад +72

      Chemistry is all about -superstition- holding grudges

  • @Stoneman06660
    @Stoneman06660 3 года назад +870

    It's got yellow chem as an ingredient.
    It's got yellow chem as a byproduct.
    It's got flammable gas + oxidiser within a glass vessel.
    It's got ratios measured in thumbs.
    It's got hardware, dinner party and fireplace ingredients.
    It's gotta be the hardest damn thing to clean up before you even start the reaction.
    What's not to like?!?

    • @alert2
      @alert2 2 года назад +2

      Everything

    • @TestECull
      @TestECull Год назад +14

      It's just missing the tar. Depressingly low amounts of tar in this one. And not all that much use of shitty plastic cups either.

    • @chemistryofquestionablequa6252
      @chemistryofquestionablequa6252 Год назад

      ​@@TestECullcleaning that flask is going to be about as tough as cleaning tar at least.

  • @robmckennie4203
    @robmckennie4203 3 года назад +872

    There are several quests involving chemistry in RuneScape, and this is definitely on that level

    • @johndoe1778
      @johndoe1778 3 года назад +21

      Runescape let’s go! Lots of gems on that game

    • @devynguitnwr1766
      @devynguitnwr1766 3 года назад +20

      I’ve been playing RuneScape since 2002 lol. A year or so after RS2 released. I have taken long breaks but you can never quit RuneScape. Old school now is the only way to go.

    • @hugmynutus
      @hugmynutus 3 года назад +15

      You make napalm in one quest lol

    • @dragofill2808
      @dragofill2808 3 года назад +4

      Buying GF xD

    • @youtubeSuckssNow
      @youtubeSuckssNow 3 года назад +7

      @@dragofill2808 you're in the wrong place to buy one of those man lol go back to the ge

  • @ruairidhdavidson288
    @ruairidhdavidson288 3 года назад +167

    Ah yes, as expertly demonstrated in the reaction of Al and S (w/ steel wool), a timber shed with lots of dry wood makes a good location for conducting exothermic reactions.

  • @newvocabulary
    @newvocabulary 3 года назад +434

    It's extremely important that you ONLY use BLUE candles. Don't fuck it up.

    • @calvaryassemblyofgodsouthi8046
      @calvaryassemblyofgodsouthi8046 3 года назад +54

      Yellow candles are bad!!! Actually isn’t sulfur yellow??

    • @ExtractionsAndIre
      @ExtractionsAndIre  3 года назад +204

      @@calvaryassemblyofgodsouthi8046 yeah that's why you gotta counteract it with a blue candle. This is exactly how real science works yes

    • @nobodynoone2500
      @nobodynoone2500 3 года назад +30

      @@ExtractionsAndIre Yellow + Blue = Green Science. Everyone knows this.

    • @crackedemerald4930
      @crackedemerald4930 3 года назад +16

      The blue reacts with the evil tree spirits imbued in the charcoal.

    • @chrisking4616
      @chrisking4616 3 года назад +3

      😂 I’m so glad I’m not the only person that thought “does the candle need to be blue”?

  • @joker0174
    @joker0174 3 года назад +63

    I remember taking a safety course (H2S alive) for working in the oil field. Apparently one of the scary things about H2S is that if you get exposed to a lethal dose (even without a knockdown), it might not kill you right away. So you may think you're fine, but it can build up in your system because it'll dissolve in your blood and then later that night or the next day your lungs start to fill with fluids and shut down due to damage from the gas, and that's what will kill you. Really nasty stuff, the instructor who was teaching this stuff was very adamant that there was no "safe" exposure limit to H2S despite different regions having "safe exposure levels". His argument was that you take a look at the regions that have oil and gas industries, vs the regions that don't, and the regions that have these industries "for some reason" have a higher safe exposure limit than regions without this industry.

  • @SocialDownclimber
    @SocialDownclimber 3 года назад +273

    If you calculate the H2S content you need and only put in enough sulphur for three or four equivalents, you can add an excess of wax to make the cleanup easier. Once your reaction is done, just heat to the melting point of the wax and then pour the rest of the wax out. You can reuse the wax if you really want to, as long as you don't use a literal burnt stick for a nucleation site lol. Should also stop the sulphur fouling your precious precious Claisen Adapter (and everything else).

    • @tyber_roman313
      @tyber_roman313 3 года назад +37

      Is he rich enough to get 4 blue candle sticks?

  • @CKOD
    @CKOD 3 года назад +46

    >Uses powder that was yellow from the start
    >Reaction flask and condenser is fucked with yellow and tar black
    >Success!
    refreshing change!

  • @7411y
    @7411y 3 года назад +226

    I love old chemistry papers, since they often used chemicals really easy to get hold of (considering it might have been the best they could do at the time) and the process ends up being pretty manageable for modern Australians in sheds to do

    • @Ethelgiggle
      @Ethelgiggle 3 года назад +8

      Easy as dicks just use some 4-Hydroxybenzoic acid 4-O-glucoside

    • @horatio2560
      @horatio2560 Год назад +9

      i wish australerans were real

    • @opalishmoth8591
      @opalishmoth8591 Год назад +3

      “Pretty manageable for modern Australians in shed to do”
      That gave me a good chuckle

    • @TheH4rtz
      @TheH4rtz Год назад +3

      Im from central coast NSW AUSTRALIA, this is true, bunnings and pool shops have a bloody lot of things needed

    • @jonomoth2581
      @jonomoth2581 Год назад

      ​@@TheH4rtz paid actor right here

  • @theSILKROAD210
    @theSILKROAD210 3 года назад +130

    Chemagic is real but very dirty.
    Nice tar synthesis Tutorial!

  • @hugeshows
    @hugeshows 3 года назад +242

    After watching like 50 of your videos I finally have a useful suggestion: Don't use candles as your paraffin source. There are weird (cheap) formulations used in candles that often contain residues of all sorts of things including perfumes used in the same molds. Just buy a block of canning wax to be sure you have purity. It's cheap.

    • @KyleJones734
      @KyleJones734 3 года назад +38

      I always love when random useless facts become usefull at random times in life.

    • @chemistryofquestionablequa6252
      @chemistryofquestionablequa6252 2 года назад

      @@KyleJones734 it makes me love my autistic fact storing brain

    • @YounesLayachi
      @YounesLayachi 2 года назад

      @@chemistryofquestionablequa6252 oh no... don't tell me fact storing brain = autistic :(

    • @noah4822
      @noah4822 2 года назад +13

      @@YounesLayachi not usually. a lot of autistic people are exceptionally good at fact storing brain tho.

    • @filonin2
      @filonin2 2 года назад +10

      Not cheaper than some candle you took from your mum.

  • @jameshowarth4801
    @jameshowarth4801 3 года назад +192

    The extractions & Ire editing style is getting more explosions & fire shit posty. I approve :D

    • @steam6626
      @steam6626 3 года назад +22

      The claisen adapter 📯🎵 🎆
      Seriously the editing style is something i always loved about this channel

    • @jameshowarth4801
      @jameshowarth4801 3 года назад +9

      @@steam6626 it's why I watch this way more than NileRed or any other science youtuber!@

    • @steam6626
      @steam6626 3 года назад +3

      @@jameshowarth4801 same

  • @RandallStephens397
    @RandallStephens397 3 года назад +204

    That argon cylinder, peeking around the corner like a doggo at the kitchen threshold. XD

    • @brokentos4546
      @brokentos4546 3 года назад +2

      Literally staring you down in the corner

    • @Treebark1313
      @Treebark1313 3 года назад

      @redxpen I've had a cylinder sitting in my garage for years now, originally it was for an ion engine that wasn't meant to be.

  • @tarjeidavidsen7611
    @tarjeidavidsen7611 3 года назад +103

    For some reason "12 grams candle" really cracked me up

    • @evanlabrant5448
      @evanlabrant5448 3 года назад +16

      "12 grams candle" in a scientific protocol would get the fuck out of my attention. I'd probably try a "12 grams candle" experiment before any of those fancy "12 grams petroleum-based high melting point mineral wax (CAS number, company/supplier)" type protocols

  • @NachozMan
    @NachozMan 3 года назад +111

    "Combine the candle with the burnt twig"
    Classic survival gameplay!

    • @jpolowin0
      @jpolowin0 2 года назад +5

      "Look around you… can you fashion some sort of rudimentary lathe?" -- _Galaxy Quest_ parodying the makeshift cannon from Star Trek's "Arena".

    • @trollmcclure1884
      @trollmcclure1884 Год назад

      what is it good for tho?
      A chemical weapon keeping predator animals out of your camp?

  •  3 года назад +58

    "Well, this is not real chemistry - this looks like potion making from some RPG" is a phrase you can build an entire channel upon =]

    • @pfzht
      @pfzht 3 года назад +9

      No stoichiometry were harmed in the creation of this alchemy.

    • @mudskipperloverskkk743
      @mudskipperloverskkk743 2 года назад

      Hello Everyone, anybody who gives suggestions that how can I detect H2S gas from Soil and which method gives a meaningful result?

  • @Samonie67
    @Samonie67 3 года назад +96

    "In todays video were making the chemical compound most feared by the petroleum industry"

    • @StabbyJoe135
      @StabbyJoe135 3 года назад +19

      Yet somehow, not the chemical they *SHOULD* be most concerned about. The selfish fucks.

    • @altaccout
      @altaccout 3 года назад +3

      @@StabbyJoe135 Nitrogen oxides? Lead?

    • @photonicpizza1466
      @photonicpizza1466 3 года назад +18

      @@altaccout I think they mean crude oil, fossil fuels being an environmental disaster and all

    • @nibblrrr7124
      @nibblrrr7124 3 года назад +4

      iT'S BACK!! oh wait wrong chemical sorry

    • @I_Automate
      @I_Automate 3 года назад +4

      @@StabbyJoe135 yawn....

  • @amansharma2870
    @amansharma2870 3 года назад +76

    The last time I was this early, we were still using carbon tet for doing chemistry.

    • @bluekiwi42nd12
      @bluekiwi42nd12 3 года назад +11

      Theres always time for carbon tet chem, just remember to recover your solvent

    • @md4luckycharms
      @md4luckycharms 3 года назад +12

      Fuckin love the 60's

    • @ExtractionsAndIre
      @ExtractionsAndIre  3 года назад +40

      Ah yeah, those were the days, 2019 was a good year

    • @bagniacz3264
      @bagniacz3264 3 года назад +7

      @@bluekiwi42nd12 And then go recover from liver damage.

    • @jeremymcadams7743
      @jeremymcadams7743 3 года назад +3

      @@ExtractionsAndIre was it?

  • @riccardogrigolato874
    @riccardogrigolato874 3 года назад +80

    Since carbon and sulphur already are elements I demand that Blue candle receive an "ad honorem" element status.

    • @bagniacz3264
      @bagniacz3264 3 года назад +22

      I believe that blue candle is an allotrope of element candle, rather than separate element.

    • @SharpAssKnittingNeedles
      @SharpAssKnittingNeedles 2 года назад

      @@bagniacz3264 haha spot on 👌

  • @JamesChurchill
    @JamesChurchill 3 года назад +155

    "This isn't real science" Of course not, it's yellow...

    • @plasticraincoat1
      @plasticraincoat1 3 года назад +1

      I’m demonstrating lots of yellow chemistry on my channel- check it out...sulphur chemistry 😀

  • @TheBigFormerlyPurpleT
    @TheBigFormerlyPurpleT Год назад +7

    DnD idea attained. One blue candle, sulfur, and some charcoal from last night's campfire. Lizardfolk hold breath for 15 minutes to make it and to deploy it, and they also know when to leave it before everyone else, as they are more sensitive to the smell.

  • @asdakuhi8h
    @asdakuhi8h 3 года назад +50

    I know 0 chemistry but I always love watching your videos

  • @noalear
    @noalear 3 года назад +11

    I made a whole bunch by using a protein skimmer on my saltwater aquarium. The bacteria in the skimmer started churning it out one day and when I took the lid off to figure out what was making the smell- blam, the whole house smelled like rotten eggs. I laid on the floor, scrubbing out the protein skimmer and tank having very little idea that was actually dangerous and not just known-to-the-state-of-California-dangerous like I'd assumed. The smell is fucking gnarly.

  • @microwavetechnician7493
    @microwavetechnician7493 3 года назад +14

    Finally, you're making something I know what it is! Known to laymen as sour gas. I took a safety course for working around it (oilfield work) and they told us "if you can't smell it, it's either not there, or you're already dead." Fun!

  • @bagniacz3264
    @bagniacz3264 3 года назад +24

    We have a lot of yellow here, alchemy-ish reactants, stinky poisonous gas and potential fire hazard. Nearly perfect. I couldn't ask for more, really.

  • @soundtrancecloud5101
    @soundtrancecloud5101 3 года назад +11

    “I’m actually going to turn this down” :puff: YELLOW

  • @jasonstewart8612
    @jasonstewart8612 3 года назад +34

    Staying up till 4am was worth it. I have some bad memories of H2S forming in our water heaters.

    • @brokentos4546
      @brokentos4546 3 года назад +4

      Can I ask what thats about?

    • @bagniacz3264
      @bagniacz3264 3 года назад +6

      Eee... you guys must have a shitload of sulphur in water, or what?

    • @jasonstewart8612
      @jasonstewart8612 3 года назад +1

      @@bagniacz3264 idk exactly how but we had water sitting in the heater for a long time without use. Smells terrible.

  • @Ye-Hu
    @Ye-Hu 3 года назад +10

    Chemical label: Extremely toxic and painful.
    Ex&F: Oh no!, anyway...

  • @rubywest5166
    @rubywest5166 2 года назад +3

    "For our sulfur we just have... Sulfur"
    Very informative, 10/10 would watch again

  • @jamesgilbert124
    @jamesgilbert124 3 года назад +37

    "It's not real science."
    It's CLASSICAL SCIENCE.

  • @therealjammit
    @therealjammit 3 года назад +18

    This is much easier than my eggs and beans method.

  • @littlelimepenguin6184
    @littlelimepenguin6184 3 года назад +65

    After this content drought, I reckon there will be some mice incoming

    • @hanelyp1
      @hanelyp1 3 года назад +9

      Gas the mice in the shed with H2S?

    • @quint3ssent1a
      @quint3ssent1a 3 года назад +2

      @@hanelyp1 ouch
      GAS THE MICE
      RACE CAR NOW

  • @juliankandlhofer7553
    @juliankandlhofer7553 3 года назад +24

    3:10
    > lights H2S with Aluminium and Steel wool on fire
    > puts it under a pile of wood
    staying on brand, i see. that's why we fucking love you :D

  • @An_Average_Arsonist
    @An_Average_Arsonist 3 года назад +40

    Your actions today are notable contributions to the scientific community! We're going to learn so much about cancers studying you in thirty years!
    The difficult part will be differentiating between the "I live in Australia so this was inevitable" cancer and the "I worked around chemicals all my life" cancer.

  • @timmulm
    @timmulm 3 года назад +5

    Here in Germany you can actually buy pre-made pellets that you can heat and generate H2S. They are called "Sulfidogen". They can be easily homemade:
    25 parts by weight of paraffin oil are mixed with 15 parts of sulfur, then it is melted on the water bath. 7 parts of kieselguhr (very fine SiO2 basically, the same you can use for filtering, then its called "Diatomaceous earth" I think) are stirred into the homogeneous melt. The mass is brittle at room temperature, but plastically deformable at approx. 40 ° C. Small portions can be pierced with the cork drill.
    This might be cleaner to work with and make less problems. Also, maybe less heat is required as they use already liquid oil instead of wax.

    • @ipodhty
      @ipodhty 3 года назад

      What are they sold for?

    • @timmulm
      @timmulm 3 года назад +1

      @@ipodhty I cannot say for sure, I think as an individual it cannot be purchased. However the manufacturing is easy, and they say at 170 C, 0,5g of the mixture releases 120mg H2S. So calculation is easy as well

  • @ex-dk3cj
    @ex-dk3cj 3 года назад +13

    i was gonna finally get some sleep at 7:40am eastern time but you had to go and drop this video

    • @ExtractionsAndIre
      @ExtractionsAndIre  3 года назад +17

      I did this just to spite you

    • @ex-dk3cj
      @ex-dk3cj 3 года назад +3

      @@ExtractionsAndIre thanks bb i appreciate it 😘

  • @windigo000
    @windigo000 3 года назад +26

    it's nice to see SOMEONE is at least thinking about safety 😊👍

  • @yvoibby
    @yvoibby 3 года назад +23

    My night shift is perfect for me, I come home and my fav mad scientist posts

    • @Dockhead
      @Dockhead 3 года назад

      damn, i wish when i was on night shift i had these videos to come home to, it was normally watching re runs of buzzfeed episodes and trying not to cry with a pack of 4 budget beers.

    • @TheSHJGaming
      @TheSHJGaming 3 года назад

      I'm working during the day and I'm still watching haha

    • @chemistryofquestionablequa6252
      @chemistryofquestionablequa6252 3 года назад

      @boyo your mistake was watching Buzzfeed shows and only having four beers

  • @MrCrazyChemist
    @MrCrazyChemist 3 года назад +22

    Maybe add some glass wool in the neck of the flask to stop sulfur getting in the condenser. I also wonder if parrafin oil would do the same with easier cleanup.

    • @ExtractionsAndIre
      @ExtractionsAndIre  3 года назад +14

      I think it might actually, that's a good thought. Although I'm not sure it would 'turn off' as easy as it won't solidify and completely stop the reaction very well maybe

    • @MrCrazyChemist
      @MrCrazyChemist 3 года назад +2

      I'd give it a try in a test tube but I don't feel the need to stink up my lab :) Would be awesome if the temperature controls the production rate then

    • @etuanno
      @etuanno 3 года назад +5

      @@ExtractionsAndIre Measure the temperature at which it starts generating?
      I do suspect that the reaction temperature if used with paraffine oil could be a bit lower.

  • @Girvo747
    @Girvo747 3 года назад +17

    “12 grams candle” was way funnier than it should’ve been. And yeah I’d stick with argon for the next run if it’s not too much of a pain. You’re likely right, with enough air you’re below the flammability threshold, but why risk it and/or rely on your small air pump and hope you’re below the threshold of your air/HS glass shrapnel bomb detonating

    • @roelant8069
      @roelant8069 Год назад

      Wouldn't nitrogen gas be a better choice in this case? It's much cheaper than argon gas as far as I'm aware

  • @Thee_Sinner
    @Thee_Sinner 3 года назад +9

    Yep, the inside of a woodshed is where I prefer to do my exothermic reactions as well.

  • @dylane8422
    @dylane8422 3 года назад +81

    I mean, WE are generators. Just fart on an h2s monitor 😉
    Oilfield truckers get bored sometimes lol

    • @blackferrets820
      @blackferrets820 3 года назад +3

      For real?

    • @lairdcummings9092
      @lairdcummings9092 3 года назад +2

      For reals.
      Not joking.
      Really.

    • @calyodelphi124
      @calyodelphi124 3 года назад +10

      @@blackferrets820 Yea, forreal. Part of the distinct smell of farts is hydrogen sulfide.

    • @pixelpatter01
      @pixelpatter01 3 года назад +23

      I was present at a demonstration of a very expensive gas meter where I worked. It was to measure low O2, flammable gas in CH4 equivalents, H2S. This meter was supposedly made to be used in a work environment so I put the thing to my butt and ripped one off. The meter squealed and went into alarm and quit working! The guy selling the meters said " I can't believe you did that". We didn't buy those meters. Thanks for the memory, LOL.

    • @calyodelphi124
      @calyodelphi124 3 года назад +2

      @@pixelpatter01 Oh my god that story is brilliant xDDD

  • @xEclipse56x
    @xEclipse56x 3 года назад +8

    This feels like a Minecraft crafting recipe more than a chemical reaction

    • @MadScientist267
      @MadScientist267 3 года назад

      The real world called.

    • @xEclipse56x
      @xEclipse56x 3 года назад

      @@MadScientist267 Huh?

    • @MadScientist267
      @MadScientist267 3 года назад

      @@xEclipse56x 🤦‍♂️ Exactly

    • @xEclipse56x
      @xEclipse56x 3 года назад

      @@MadScientist267 I don’t understand why you have a problem with me relating something to a game

    • @MadScientist267
      @MadScientist267 3 года назад

      @@xEclipse56x It's a much longer story than can fit into a RUclips comment... Don't lose sleep over it.
      Suffice to say I've seen a few "de-evolutions" (one in particular very disturbing) caused by games and detachment... You just happen to have the right wording combo to tap the nail on the way by 🤣

  • @Sokar12345
    @Sokar12345 3 года назад +10

    ah yes. lets have the exothermic reaction take place right next to giant pile of wood.

  • @fail0r
    @fail0r 3 года назад +3

    regarding cleaning the flask: at uni when I made sulfur chlorides once, I used salt in ethanol as an abrasive to get most of the yucky residue out. fill it in, stopper, shake the hell out of it. got the idea from an online guide on how to clean tarred up bongs. ;)

  • @Chiberia
    @Chiberia 4 месяца назад +2

    candlemaking dude here - just FYI most candles aren't pure paraffin - they very often have soy and other waxes in them, even coconut oil, to get different properties, strengths, glass adhesion properties, etc. I'm not sure what side reactions this may cause, with all the added amino acids, but just FYI if you do this in the future - it's pretty easy and cheap to just get paraffin from candle suppliers or even camping stores, for waterproofing. it should actually be quite slimy at room temperature... which the "dry" candle tells me there's probably a decent amount of soy additives in that candle.

  • @MySuperhappyfuntime
    @MySuperhappyfuntime 3 года назад +29

    Two videos in like a week!? I love it (but don't burn yourself out!)

    • @ExtractionsAndIre
      @ExtractionsAndIre  3 года назад +19

      It was 10 days ago I think! But yes, I'm just impatient!

    • @The_Keeper
      @The_Keeper 3 года назад +3

      @@ExtractionsAndIre I would like to add;
      Not only don't burn yourself out, but also don't blow yourself up.

  • @hetaira62080
    @hetaira62080 3 года назад +4

    Your video quality as in the quality of the overall product has come so far in just the past year or two even. Seems professional in all the right ways while still holding onto that boyish charm we’ve come to know and love

  • @MrJon1157
    @MrJon1157 2 года назад +3

    I used H2S liquid as a sulfur donator when I was growing MoS2 on Graphene (i also grew the graphene and transferred it onto silicon wafers) because the ATTM (Ammonium tetrathiomolybdate) reaction sometimes wouldn't happen. I used a PARR vessel to create high pressure temperatures which drove the reaction. The whole goal was to show that if the MoS2 seeded properly and grew on the graphene, the graphene could serve as the electron transport layer in a Hydrogen Evolution Reaction. which it did. Point being, H2S is the most putrid rotten egg smell i have ever had the pleasure to work with.
    I did notice that in one of the shots of your reaction there were distinctly large "bubbles" of gas forming, but i think the surface tension of the molten liquid was very strong and trapped it. The clip where you had a burst of gas was when 4 or 5 of those "bubbles" burst open. So i think that you could safely say that this generates a ton of H2S immediately, but because of that surface tension it traps it until there is enough heat to break the tension and then it releases the gas that accumulated over time.

  • @zobrombie3023
    @zobrombie3023 Год назад +2

    One professor told me safety advice that I carry with me always, and it's somewhat applicable here. The gist was that if you get that feeling coming from your subconscious that you're being unsafe, you should listen to it. Because mammals are well-evolved to develop patterns to predict future survival situations. Considerations to safety and building that survival sense is never a fool's pursuit.

    • @firstmkb
      @firstmkb Год назад

      The woodworking version is “If an operation feels unsafe, it probably is.”

  • @ablancas10
    @ablancas10 3 года назад +22

    Tom: uploads a video showing a better way to make HS
    FBI: 👁️👄👁️

  • @imikla
    @imikla 3 года назад +2

    Wow, that brings back memories. I evacuated our Jr. High School when I was in 8th grade (US) in the '70s, heating paraffin and sulfur in a test tube over a Bunsen burner in the science class. I found the procedure in an old book I bought at a university "get rid of old books" sale. I just wanted to make "smell of rotten eggs" 😬.

  • @atharvavibhute1213
    @atharvavibhute1213 3 года назад +8

    Instead of cleaning u can jusst name the flask H2S generation flask and use it only for that. No clean up needed. XD

    • @ExtractionsAndIre
      @ExtractionsAndIre  3 года назад +8

      If I used H2S more, then you're right I'd probably do this! But knowing me and how much I jumpnaround with projects, I probably won't use it again for another year at least

  • @Alexander_Sannikov
    @Alexander_Sannikov 2 года назад +1

    RE on your sense of smell getting oversaturated when the concentration is too strong. The same thing happens with most geiger counters when you measure the radiation level: when it gets too high, they completely stop counting pulses because pulses become just a continuous internal discharge that does not produce impulses or sound. If you ever encounter that, you know you fked up.

  • @brown56765
    @brown56765 3 года назад +14

    Charcoal, Sulphur, and a candle...
    That ain't science, that's witchcraft baby! B)

  • @niconeuman
    @niconeuman 3 года назад +2

    This is a very nice method for making H2S, which by the way is a gasotransmitter apparently, like NO. You could make pellets out of wax, sulphur and carbon, maybe a couple of grams each. And melt one pellet at a time when you need H2S. And you can after some tests add different number of pellets depending on how much gas you want to make

  • @jeremymcadams7743
    @jeremymcadams7743 3 года назад +5

    Extractions&Ire. Give the flask a soak in vinegar for a good hour and come back. The charcoal should readily scrub off.

  • @Alexander_Sannikov
    @Alexander_Sannikov 2 года назад

    3:15 classic violent exothermic reaction next to a firewood stack, keep it up

  • @BackMacSci
    @BackMacSci 3 года назад +4

    Unique reaction! I heard somewhere that a mix of sulfur, carbon, and potassium nitrate in a ratio of 10:15:75 works even better! ;)

  • @admdubya2107
    @admdubya2107 5 месяцев назад +1

    I come from the area of Texas where roughly all of the crude refining and chemical production was done. Exxon, Shell, Dow and Co. There are actual air raid sirens scattered about to alert the surrounding cities to various refinery disasters…“unscheduled gas vents” and “some of your parents blew up” etc etc etc. They test them weekly on Thursdays. Always a big hit with the dogs. H2S smells just mfn awful and it’s everywhere. It goes from a bad fart to completely overwhelming and then yea…when you can’t smell it anymore you done messed up. Headaches and nausea and such.

  • @stephensteele3553
    @stephensteele3553 3 года назад +5

    The sign of a true chemist is putting off cleaning the glassware for another day when you don't have any grad students around.

  • @Sariusify
    @Sariusify 3 года назад +1

    If you want to find out whether the oxygen/H2S mix is dangerous would be to find out the rate at which the H2S is produced, i.e. by measuring the pressure in the reaction setup whilst the rxn is running.
    With that you could probably calculate some type of steady state concentration based on your carrier gas flow rate.
    Also, technically, just pumping the carrier gas at ludicrous speeds would give you the lowest concentrations, so you'd probably end up with a safer mixture at higher carrier gas pressures

  • @yuut8434
    @yuut8434 3 года назад +6

    It was only yesterday when I learned that farts with a high enough hydrogen sulphide concentration can kill

    • @pauliusUwU
      @pauliusUwU 3 года назад +1

      A big enough fart is lethal.

  • @kitteecatt4681
    @kitteecatt4681 2 года назад

    really nice of you to show the bong- i mean reaction flask- cleaning. hygiene is important on repeated use of glassware :)

  • @patrick247two
    @patrick247two 3 года назад +5

    Bit closer to the firewood next time, wouldn't want to be too safe.

  • @MrCheezeNip
    @MrCheezeNip 2 года назад

    I used to work out on the pipelines of Alberta. H2S was the most common killer. You are a brave man.

  • @CTRLaltKNIFE
    @CTRLaltKNIFE 3 года назад +3

    thats a really nice saab in the background :D

  • @Maharani1991
    @Maharani1991 3 года назад +1

    The Aphex Twin soundtrack is so perfect for your videos. I love how the bit at 9 minutes is a completely frayed and decayed continuation of the earlier bit. The music adds so much to your production value!

  • @timediamond3921
    @timediamond3921 3 года назад +4

    Reminder from the Ruthenium Tetroxide video, you wanted to to a video extracting calcium from bones.

  • @johnpenguin9188
    @johnpenguin9188 3 года назад +2

    I always appreciate the Aphex Twin tracks.👍🏻👍🏻

  • @Xari.04
    @Xari.04 3 года назад +5

    Somehow this has been one of your scariest videos lmao. The sudden kind of explosion at 9:26 was something that would have made me shit my pants while in uni. Also 100% agree, using a carrier gas is really nice in a case like this but I would definitely not do it with air again, especially considering that the reaction was kind of a bitch to handle properly. Cheers

  • @hoggif
    @hoggif 3 года назад +2

    Nose can get used to low levels too. I was distilling liquids some time ago and it had a slight hydrogen sulfide smell (nothing for me to get worried about, a very slight smell). However, after long time sitting by and taking fractions I got slight sympthoms that turned into light head ache, moved to fresh air and it turned into a large headache followed by dizziness. For large concentration it can make you not smell it almost at all.
    I'd rate H2S closer to cyanides in danger (I can possibly disable you pretty quickly too). The difference to me is that at least you can smell it unlike CO or if you're like me, HCN at least in slow levels (but yet high enough to give slight dizzyness).

  • @mtndewisawsome-kn1je
    @mtndewisawsome-kn1je 3 года назад +4

    What a weird method for making hydrogen sulfide, really intriguing. I usually make hydrogen sulfide by boiling sulfur and sodium hydroxide followed by acidification with hydrochloric acid, super easy and to my surprise, a very easy cleanup, so long as you use excess sodium hydroxide that is.

    • @The_Keeper
      @The_Keeper 3 года назад

      Ahh, but his method seems to produce anhydrous Hydrogen Sulfide.
      That is probably useful in some cases. (I don't know enough chem to even begin guessing if that make a difference).

    • @mtndewisawsome-kn1je
      @mtndewisawsome-kn1je 3 года назад

      @@The_Keeper Yea, I guess but most of the time for me it's not necessary, fair point though

  • @maximiliandaschner3120
    @maximiliandaschner3120 3 года назад +1

    OP I love your Channel.
    Im interested in science but havent looked up much chemistry on youtube yet. Am from Germany and saw you in my recommendations 1-2 Weeks ago.
    Am binge watching your vids since, love your unique flavor. A really well done blend of "science/chemistry" and "what people want to see on youtube" for me. Great character and great example of how robust some of the chemical processes are in terms of tolerance, which I like very much.

  • @ChaosPootato
    @ChaosPootato 3 года назад +3

    If your chemistry goes yellow, chuck some charcoal in there and you'll be fine

  • @mrjcaudy
    @mrjcaudy 3 года назад +1

    Bro the way you caress that fractionating column at 8:06, damn... you finna make me act up

  • @kassadus2499
    @kassadus2499 3 года назад +11

    Yellow chem saving the day once again.

  • @omanafire
    @omanafire 2 года назад

    I love how it just takes off all of a sudden and you start playing boss music.

  • @MattJohnVO
    @MattJohnVO 3 года назад +3

    Favorite Australian chemist on yt

  • @RiffRaffMama.
    @RiffRaffMama. Год назад

    Love your cleaning tool of choice. You know what they say - everything's a hammer. Unless it's a screwdriver, then it's a chisel.

  • @xghale9073
    @xghale9073 3 года назад +6

    Madlad Aussie makes smelly egg air using paraffin...things?

    • @thegermanguy-it3ek
      @thegermanguy-it3ek 3 года назад

      How can u write 12 mins ago, it just came out

    • @opiatatee
      @opiatatee 3 года назад

      @@thegermanguy-it3ek illuminati that's why

    • @rainbianca8625
      @rainbianca8625 3 года назад +1

      @@thegermanguy-it3ek it's tom's alt account actually

    • @xghale9073
      @xghale9073 3 года назад +1

      @@thegermanguy-it3ek I'm a wizard

    • @xghale9073
      @xghale9073 3 года назад +1

      @@rainbianca8625 I wish I was that cool :c

  • @aonomus
    @aonomus 3 года назад +1

    I spent 2 years working on a project that involved condensing H2S into an organic solvent at cryogenic temperatures, followed by a warming ramp to allow it to react gradually. We did tons of process safety work to ensure that the H2S was fully consumed at every point in the warming ramp. Worst case scenario for scale up to a 2000L vessel would have been if the plant forgot to charge the reaction partner to the vessel. Full charge of H2S would have gone in with no reaction, then upon warming it exceeds the solubility limit for H2S in that solvent.
    We did the math, it would have been enough H2S to evacuate the town should the worst possible branch of the FMEA occur, so we put administrative and engineering controls to make it nigh impossible to occur. Never been so glad to see a project die though, that reaction step always put me on edge.

  • @brokentos4546
    @brokentos4546 3 года назад +4

    That aphex twin always gets me

  • @weepingwell
    @weepingwell Год назад

    i learn so much when i watch these vids. i had never even heard of a re-juicing gas before.

  • @dcaonoek
    @dcaonoek 3 года назад +6

    Making the thing I've been taught to fear. Lad.

  • @sambotlon8652
    @sambotlon8652 Год назад +1

    Casually incinerates some aluminum and sulfide right next to a burn pile. That’s my man

  • @SerumCRM114
    @SerumCRM114 3 года назад +3

    RIP the flask that will never get clean again. 😅

  • @aetius31
    @aetius31 3 года назад +2

    I think this is a common reaction that should occur with any hydrocarbons, i remember visiting a gas desulfurization unit from a natural gas producer where the molten sulfur had still some methane/ethane mixed in and it produced quite a lot of H2S.
    Also worth mentionning it also produced a strange mineral they called Carbsulf (not much info about this) which i assume was some kind of carbon polysulfide, it was somewhat translucent and flaky (i still got some in my collection).

  • @SocialDownclimber
    @SocialDownclimber 3 года назад +4

    So easy it should be on RUclips Kids!

  • @ormarion552
    @ormarion552 3 года назад +1

    Thank you for sharing it Tom ! I already knew this methode but never heards about adding charcoal to it. The cleaning kinda traumatised me as it took a entire liter of xylene and maybe 200ml of piranah to fully clean the jar from my side. What i recomment to people using this methode is to just rapidely clean it to remove big junk and keep it as a jar specially for this reaction. Anyway will be very helpful for my 24h bubbling of H2S for making thiobenzophenone ^^

  • @barthooghwerff1682
    @barthooghwerff1682 3 года назад +3

    Well that worked... nice stuff
    Btw carbon in the trees doesnt come from the ground right, thats stupid;)

    • @barthooghwerff1682
      @barthooghwerff1682 3 года назад +2

      Unless its from a burned out fire and you picked it up later that would count as 'from the ground'

    • @ExtractionsAndIre
      @ExtractionsAndIre  3 года назад +4

      True thought... charcoal from the air??? I did just pick it up off an old fire though

    • @barthooghwerff1682
      @barthooghwerff1682 3 года назад +2

      @@ExtractionsAndIre So yeah charcoal from the ground, carbon from the air... whatever, its all the same in the end

  • @GERntleMAN
    @GERntleMAN Месяц назад

    I like how he tested the steel wool version right inside a firewood shed surrounded by crisp and tasty dry wood in case someone needed warmth

  • @chasenk00019
    @chasenk00019 3 года назад +3

    A couple guys on a job at a refinery died to h2s because someone didn't torque a flange properly.

  • @elizabethvaux4420
    @elizabethvaux4420 3 года назад +2

    In the discord, I had theorized that using walnut shell-based sand blasting media could be used to clean glassware. Basically dump some in and shake it up a bunch. Doesn't scratch it, is disposable, still abrasive and is generally quite dry. Could even use it in conjunction *with* water. Figured I'd mention it here just in case it makes a difference and maybe if people agree it'll get noticed? In the states I got like 10 lbs for something like 20 freedom bucks and 10 lbs of dry ass walnut shell is quite a lot more than I realized.
    edit: Also maybe use a cheese grater for the wax/charcoal next time so you dont end up accidentally pulverizing it lmao.

  • @Doping1234
    @Doping1234 3 года назад +5

    "I'll do it another day, I swear"
    There's a cheap thesis writing joke in there, isn't it?

  • @TheRakerr
    @TheRakerr Год назад

    I did this reaction as an unsupervised pre-teen in the early 90's. That hand me down 1960s chemistry set without instructions was great fun!

  • @markholub97
    @markholub97 2 года назад +2

    Not gonna lie, I clicked on this video because I thought you were holding an M67 Frag grenade in the thumbnail.

  • @evandrochaves9596
    @evandrochaves9596 2 года назад

    Good to know that H2S has a safe "bad smell gotta runaway" threshold, because somehow trying to resuscitate a dead car battery, my job colleagues almost managed to poison the entire area with this gas, that I had to shut down the breaker to stop the battery charger from building more poison