Random Villain Defeats 45

[@NumberOneMikeFan]

Thanks for Using Arch Knight and Lui. Catchy as heck song too.
Arkham Knight from The Rise Of The Batcoon.
Totoko, Chibita, and Iyami from Osomatsu-san: The Movie.
Mal From Total Drama All-Stars.
Darth Vader: thechocobro: The Arcade Section Vs. The Galactic Empire: Conclusion.

[@josealfredobautistabautist1850]

Thanks for Striker and Bowser
Ryo Ogino from Buddy Daddies
Voltar and Skullossus from League of Super-Evil
The Radiance from Hollow Knight

[@ma3mc3mu-X]

Malt from Larva Pendant
Gargan from HarmoKnight
The Curious Cat and Neopolitan from RWBY
Ganondorf from The Legend Zelda: Tears of the Kingdom

[@WhitNotWhite]

Thanks for Striker, Moff Gideon, The Marquis de Gramont, and Bowser