Coupling Reactions Organic Chemistry|Stille|Negishi|Sonogashira|Suzuki| Hiyama|Heck Kumada Buchwald
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- Опубликовано: 15 сен 2024
- Coupling Reactions Organic Chemistry|Stille|Negishi|Sonogashira|Suzuki| Hiyama|Heck Kumada Buchwald Hartwig || Carbonylation || Cyanation
Carbon - Carbon Coupling Reactions: • Claisen-Schmidt Conden...
#couplingreactions#stillecoupling#sonogashiracoupling#suzukireaction#hiyamacoupling#negishicoupling #kumadacoupling #heckreaction #buchwaldhhartwigamination
Reformatsky Reaction: • Organozinc compounds|R...
#cyanation #carbonylation #organozincreagents#reformatskyreaction #jchemistry#negishicoupling
Related Other Name Reactions:
1. Aldol Condensation: • Differences of: Aldol...
2. Baeyer - Villiger Oxidation Rearrangement: • Baeyer Villiger Oxidat...
3. Beckmann Rearrangement: • Beckmann Rearrangement...
4. Benzil - Benzilic Acid Rearrangement: • Benzilic Acid Rearrang...
5. #Birch #Reduction of Aromatic rings, Alkynes, Conjugated Dienes, alpha beta unsaturated Ketones : • Birch Reduction of Aro...
6. #Cannizzaro #Reaction: • Cannizzaro Reaction Me...
7. #Claisen #Condensation, formation of Beta Keto Esters (Self Condensation vs Mixed Condensation) : • Claisen Condensation -...
8. #Claisen Rearrangement : • Claisen Rearrangement ...
9. #Claisen - #Schmidt Reaction Differences between Aldol reaction, Cannizzaro Reaction and Claisen reaction: • Claisen-Schmidt Conden...
10. #Clemmensen Reduction Reaction (Part 13): • Clemmensen Reduction -...
11. #Curtius Rearrangement Reaction (Part 14): • Curtius Rearrangement ...
12. #Dieckmann Condensation Reaction Mechanism (Part 15): • Dieckmann Condensation...
13. #Diels #Alder Reaction (Part 16): • Diels-Alder Reaction -...
14. #Dienone - #Phenol Rearrangement Reaction (Part 17): • Dienone Phenol Rearran...
15. #Favorskii Rearrangement Reaction (Part 18): • Favorskii Rearrangemen...
16. #Friedel #Crafts #Alkylation and #Acylation Reaction (Part 19): • Friedel Crafts Alkylat... #Fries Rearrangement Reaction: • Fries Rearrangement Re...
17. #Gabriel #Phthalimide Synthesis : • Gabriel Synthesis - Or...
18. #Hell - #Volhard - #Zelinsky (#HVZ) Reaction: • Hell Volhard Zelinsky ...
19. #Hoffmann #Bromamide Reaction (Hoffmann Rearrangement / Hoffmann Bromamide degradation): • Hoffmann Bromamide Deg...
20. #Houben - #Hoesch #Acylation: • Hoesch reaction Mechan...
21. #Gattermann #Koch and #Gattermann #Formylation Reaction: • Gattermann & Gatterman...
22. #Knoevenagel Reaction: • Knoevenagel Reaction |...
23. #Mannich reaction: • Mannich Reaction - Def...
24. #Meervein-#ponndorf-#verley (#MPV) Reduction reaction mechanism • Meerwein-Ponndorf-Verl...
25. #Michael #Addition #Reaction: • Michael Reaction Mecha...
26. #Oppenauer #Oxidation #Reaction || #Swern #Jones #Collins #Moffet #Sarett #Oxidation of #Alcohols: • Oppenauer Oxidation - ...
27. Palladium catalysed coupling reactions: • Coupling Reactions Org...
28. Perkin Reaction: • Perkin Reaction Mechan...
29. Pinacol-Pinacolone Rearrangement: • Pinacol pinacolone rea...
30. Reformatsky reaction : • Organozinc compounds|R...
31. Reimer-Tiemann Reaction: • REIMER TIEMANN Reactio...
32. #Ziegler #Natta Catalyst: • Ziegler Natta Polymeri...
#palladium catalysed coupling reactions pdf,palladium catalysed coupling reactions ppt, #heck reaction,#suzuki coupling,cross coupling reactions ppt,why pd is used in coupling reaction, #negishi coupling,aromatic coupling reactions, #stille coupling reaction,#kumada coupling mechanism, #hiyama coupling, #sonogashira coupling, #buchwald hartwig coupling reaction,j chemistry,Venus Academy,venusacademy,venus academy,venus chemistry academy,organic chemistry,gate,chemistry
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Short and sweetly explained all 10 reactions in 10 minutes excellent..
Thank you madam,
For more name reactions, please watch these video lectures of Venus Academy:
1. Aldol Condensation: ruclips.net/video/6vw9xRDrPkQ/видео.html
2. Baeyer - Villiger Oxidation Rearrangement: ruclips.net/video/bSIYN1TgNVg/видео.html
3. Beckmann Rearrangement: ruclips.net/video/90sPi0E0fws/видео.html
4. Benzil - Benzilic Acid Rearrangement: ruclips.net/video/uyYLpGUHe-s/видео.html
5. #Birch #Reduction of Aromatic rings, Alkynes, Conjugated Dienes, alpha beta unsaturated Ketones : ruclips.net/video/qJoDhV4DX98/видео.html
6. #Cannizzaro #Reaction: ruclips.net/video/uBCNEERmls8/видео.html
7. #Claisen #Condensation, formation of Beta Keto Esters (Self Condensation vs Mixed Condensation) : ruclips.net/video/UY2y_2UUus4/видео.html
8. #Claisen Rearrangement : ruclips.net/video/AZy5NgeTPpg/видео.html
9. #Claisen - #Schmidt Reaction Differences between Aldol reaction, Cannizzaro Reaction and Claisen reaction: ruclips.net/video/YqCH8AEccSw/видео.html
10. #Clemmensen Reduction Reaction (Part 13): ruclips.net/video/oIyUQBYEr44/видео.html
11. #Curtius Rearrangement Reaction (Part 14): ruclips.net/video/c23ys2XHUoI/видео.html
12. #Dieckmann Condensation Reaction Mechanism (Part 15): ruclips.net/video/OFQZLF95e4I/видео.html
13. #Diels #Alder Reaction (Part 16): ruclips.net/video/eWnkxlUOPpg/видео.html
14. #Dienone - #Phenol Rearrangement Reaction (Part 17): ruclips.net/video/65PG5VtGv24/видео.html
15. #Favorskii Rearrangement Reaction (Part 18): ruclips.net/video/0uWqtCi21N4/видео.html
16. #Friedel #Crafts #Alkylation and #Acylation Reaction (Part 19): ruclips.net/video/9KuYVo1sypg/видео.html #Fries Rearrangement Reaction: ruclips.net/video/Lat7VXgAJ8o/видео.html
17. #Gabriel #Phthalimide Synthesis : ruclips.net/video/-OGKqOfHGQY/видео.html
18. #Hell - #Volhard - #Zelinsky (#HVZ) Reaction: ruclips.net/video/NdhW0CBf8b4/видео.html
19. #Hoffmann #Bromamide Reaction (Hoffmann Rearrangement / Hoffmann Bromamide degradation): ruclips.net/video/piZALtdU3rI/видео.html
20. #Houben - #Hoesch #Acylation: ruclips.net/video/JJYLALhJ970/видео.html
21. #Gattermann #Koch and #Gattermann #Formylation Reaction: ruclips.net/video/kPP4PEhhdHU/видео.html
22. #Knoevenagel Reaction: ruclips.net/video/C_GKc7PXzgo/видео.html
23. #Mannich reaction: ruclips.net/video/PKw5JOgiy8E/видео.html
24. #Meervein-#ponndorf-#verley (#MPV) Reduction reaction mechanism ruclips.net/video/0dmKqDXqGbs/видео.html
25. #Michael #Addition #Reaction: ruclips.net/video/Q0lZtG9R_es/видео.html
26. #Oppenauer #Oxidation #Reaction || #Swern #Jones #Collins #Moffet #Sarett #Oxidation of #Alcohols: ruclips.net/video/O2Agjj5asgA/видео.html
27. Palladium catalysed coupling reactions: ruclips.net/video/Zas_JlccBNQ/видео.html
28. Perkin Reaction: ruclips.net/video/5KaYcNueuTI/видео.html
29. Pinacol-Pinacolone Rearrangement: ruclips.net/video/YjbnDV26jd0/видео.html
30. Reformatsky reaction : ruclips.net/video/r5qYVUF2A2E/видео.html
31. Reimer-Tiemann Reaction: ruclips.net/video/lI2UBsNbZkE/видео.html
32. #Ziegler #Natta Catalyst: ruclips.net/video/9ls6HZW4VrM/видео.html
Great work
Sir, very detailed explanation. Really liked the way you gave insights about the practical aspects of the reactions. Thank you Sir.
Thank you Dogra ji... wish you all the best.
extraordinary explanation
Thank you sir, wish you all the best.
The way you delivered the subject is very impressive.
Thank you for your compliments. Wish you all the best.
Sir happy to see you sir. Nice explanation sir. I have seen in Sapala organics pvt Ltd.
Thank you Laxmi madam...
The way of your explanation is so nice
Thank you sir... Please watch other videos of Name reactions.
ruclips.net/video/0uWqtCi21N4/видео.html
nice sir ,i enjoyed
Thank you Sir...
Negishi (Zn - Zinc) Coupling Reaction - 8:11 (timeline of this video)
Stille (Sn - Tin) Coupling Reaction - 7:13 (timeline of this video)
Suzuki (Boron) Coupling Reaction - 6:38 (timeline of this video)
Great explanation
Thank you Sir.. wish you all the best.
Excellent
Thank you Amin Baig ji,
For more name reactions please watch these videos:
1. Aldol Condensation: ruclips.net/video/6vw9xRDrPkQ/видео.html
2. Baeyer - Villiger Oxidation Rearrangement: ruclips.net/video/bSIYN1TgNVg/видео.html
3. Beckmann Rearrangement: ruclips.net/video/90sPi0E0fws/видео.html
4. Benzil - Benzilic Acid Rearrangement: ruclips.net/video/uyYLpGUHe-s/видео.html
5. #Birch #Reduction of Aromatic rings, Alkynes, Conjugated Dienes, alpha beta unsaturated Ketones : ruclips.net/video/qJoDhV4DX98/видео.html
6. #Cannizzaro #Reaction: ruclips.net/video/uBCNEERmls8/видео.html
7. #Claisen #Condensation, formation of Beta Keto Esters (Self Condensation vs Mixed Condensation) : ruclips.net/video/UY2y_2UUus4/видео.html
8. #Claisen Rearrangement : ruclips.net/video/AZy5NgeTPpg/видео.html
9. #Claisen - #Schmidt Reaction Differences between Aldol reaction, Cannizzaro Reaction and Claisen reaction: ruclips.net/video/YqCH8AEccSw/видео.html
10. #Clemmensen Reduction Reaction (Part 13): ruclips.net/video/oIyUQBYEr44/видео.html
11. #Curtius Rearrangement Reaction (Part 14): ruclips.net/video/c23ys2XHUoI/видео.html
12. #Dieckmann Condensation Reaction Mechanism (Part 15): ruclips.net/video/OFQZLF95e4I/видео.html
13. #Diels #Alder Reaction (Part 16): ruclips.net/video/eWnkxlUOPpg/видео.html
14. #Dienone - #Phenol Rearrangement Reaction (Part 17): ruclips.net/video/65PG5VtGv24/видео.html
15. #Favorskii Rearrangement Reaction (Part 18): ruclips.net/video/0uWqtCi21N4/видео.html
16. #Friedel #Crafts #Alkylation and #Acylation Reaction (Part 19): ruclips.net/video/9KuYVo1sypg/видео.html #Fries Rearrangement Reaction: ruclips.net/video/Lat7VXgAJ8o/видео.html
17. #Gabriel #Phthalimide Synthesis : ruclips.net/video/-OGKqOfHGQY/видео.html
18. #Hell - #Volhard - #Zelinsky (#HVZ) Reaction: ruclips.net/video/NdhW0CBf8b4/видео.html
19. #Hoffmann #Bromamide Reaction (Hoffmann Rearrangement / Hoffmann Bromamide degradation): ruclips.net/video/piZALtdU3rI/видео.html
20. #Houben - #Hoesch #Acylation: ruclips.net/video/JJYLALhJ970/видео.html
21. #Gattermann #Koch and #Gattermann #Formylation Reaction: ruclips.net/video/kPP4PEhhdHU/видео.html
22. #Knoevenagel Reaction: ruclips.net/video/C_GKc7PXzgo/видео.html
23. #Mannich reaction: ruclips.net/video/PKw5JOgiy8E/видео.html
24. #Meervein-#ponndorf-#verley (#MPV) Reduction reaction mechanism ruclips.net/video/0dmKqDXqGbs/видео.html
25. #Michael #Addition #Reaction: ruclips.net/video/Q0lZtG9R_es/видео.html
26. #Oppenauer #Oxidation #Reaction || #Swern #Jones #Collins #Moffet #Sarett #Oxidation of #Alcohols: ruclips.net/video/O2Agjj5asgA/видео.html
27. Palladium catalysed coupling reactions: ruclips.net/video/Zas_JlccBNQ/видео.html
28. Perkin Reaction: ruclips.net/video/5KaYcNueuTI/видео.html
29. Pinacol-Pinacolone Rearrangement: ruclips.net/video/YjbnDV26jd0/видео.html
30. Reformatsky reaction : ruclips.net/video/r5qYVUF2A2E/видео.html
31. Reimer-Tiemann Reaction: ruclips.net/video/lI2UBsNbZkE/видео.html
32. #Ziegler #Natta Catalyst: ruclips.net/video/9ls6HZW4VrM/видео.html
Good morning... Sir... Nice explanation what is the reference books for this topic please tell me sir...🙏🙏
This topic is prepared from Palladium catalysis book by Prof. Tsuji wish you all the best.
@@VenusAcademy thank you so much sir.... 🙏🙏
Heck reaction
Heck reaction is mediated by Pd to give new C C single bond.
Palladium was water soluble and organic halide is soluble in organic solvent. How come reaction proceeds.
Dear Babachary ji,
Heck reaction is performed in organic solvents using organic bases such as Et3N etc.
Suzuki reaction is performed in a mixture of organic solvents (dioxane, DMF etc) in water system.
Palladium catalysts are soluble in organic solvents e.g. Palladium acetate: Solubility: sol organic solvents such as chloroform, methylene chloride, acetone, acetonitrile, diethyl ether. Dissolves with decomposition in aq HCl and aq KI solutions. Insol water and aqueous solutions of NaCl, NaOAc, NaNO3 as well as in alcohols and petroleum ether. Decomposes when heated with alcohols.
However, when bases (inorganic bases like CsF, Cs2CO3, Na2CO3, K2CO3 are used then water also used).
Typically in a Suzki reaction the solvent system will be : 1,4-dioxane/water (9/1 ratio) and the Pd catalysts such as Pd(dppf)Cl2 and CsF are used.
Tq sir
Thank you Brahmi ji,
Please follow these videos for more name reactions: ruclips.net/video/0uWqtCi21N4/видео.html
Name Reactions alphabetical order: sites.google.com/site/venuschemistryacademy/home
Wish you all the best.
Palladium catalysed name reactions
10 Important Palladium catalyzed reactions are:
Suzuki Miyaura
Stille
Negishi
Kumada
Hiyama
Sonogashira
Heck
Buchwald Hartwig
Carbonylation
Cyanation
Why R-F,Ar-F compounds doesn't participate in palladium catalyzed couplings reactions, please give sutable reason
Dear Pureti ji,
Palladium catalyzed reactions involves a step of oxidative addition and this step is facilitated by high electron density compounds like organic (C-X) halides /pseudo-halides of sp2 carbons, and the rate of the addition decreases in the following order; C-I > C-Br >>> C-Cl >>> F. Aryl fluorides are almost inert.
It is clear from the above order that the R-Cl is less reactive and R-F is almost intact. However, recently, facile oxidative addition of sp2 C-Cl
bonds can be used by using electron-rich ligands such as P(t-Bu)3 or N-heterocyclic carbene
ligands, and electron-deficient
aryl fluorides can be coupled when PMe3 or biphenylylphosphines ligands are used.
In general, most of the halides/pseudo halides like Alkenyl, aryl halides, acyl halides, sulfonyl halides, Diazonium salts and triflates undergo facile oxidative addition.
I hope your question is answered.
wish you all the best.
Hiyama coupling
Stille coupling
Tin Sn mediated reactions are known as Stille coupling.
Suzuki Miyaura coupling
Boronic acid or boronate esters are coupled using Pd catalyst.
Negishi Coupling
Zinc mediated coupling reaction is known as Negishi coupling
Sonogashira coupling
Sonogashira uses CuI as co catalyst.
Kumada coupling
1. Aldol Condensation: ruclips.net/video/6vw9xRDrPkQ/видео.html
2. Baeyer - Villiger Oxidation Rearrangement: ruclips.net/video/bSIYN1TgNVg/видео.html
3. Beckmann Rearrangement: ruclips.net/video/90sPi0E0fws/видео.html
4. Benzil - Benzilic Acid Rearrangement: ruclips.net/video/uyYLpGUHe-s/видео.html
5. #Birch #Reduction of Aromatic rings, Alkynes, Conjugated Dienes, alpha beta unsaturated Ketones : ruclips.net/video/qJoDhV4DX98/видео.html
6. #Cannizzaro #Reaction: ruclips.net/video/uBCNEERmls8/видео.html
7. #Claisen #Condensation, formation of Beta Keto Esters (Self Condensation vs Mixed Condensation) : ruclips.net/video/UY2y_2UUus4/видео.html
8. #Claisen Rearrangement : ruclips.net/video/AZy5NgeTPpg/видео.html
9. #Claisen - #Schmidt Reaction Differences between Aldol reaction, Cannizzaro Reaction and Claisen reaction: ruclips.net/video/YqCH8AEccSw/видео.html
10. #Clemmensen Reduction Reaction (Part 13): ruclips.net/video/oIyUQBYEr44/видео.html
11. #Curtius Rearrangement Reaction (Part 14): ruclips.net/video/c23ys2XHUoI/видео.html
12. #Dieckmann Condensation Reaction Mechanism (Part 15): ruclips.net/video/OFQZLF95e4I/видео.html
13. #Diels #Alder Reaction (Part 16): ruclips.net/video/eWnkxlUOPpg/видео.html
14. #Dienone - #Phenol Rearrangement Reaction (Part 17): ruclips.net/video/65PG5VtGv24/видео.html
15. #Favorskii Rearrangement Reaction (Part 18): ruclips.net/video/0uWqtCi21N4/видео.html
16. #Friedel #Crafts #Alkylation and #Acylation Reaction (Part 19): ruclips.net/video/9KuYVo1sypg/видео.html #Fries Rearrangement Reaction: ruclips.net/video/Lat7VXgAJ8o/видео.html
17. #Gabriel #Phthalimide Synthesis : ruclips.net/video/-OGKqOfHGQY/видео.html
18. #Hell - #Volhard - #Zelinsky (#HVZ) Reaction: ruclips.net/video/NdhW0CBf8b4/видео.html
19. #Hoffmann #Bromamide Reaction (Hoffmann Rearrangement / Hoffmann Bromamide degradation): ruclips.net/video/piZALtdU3rI/видео.html
20. #Houben - #Hoesch #Acylation: ruclips.net/video/JJYLALhJ970/видео.html
21. #Gattermann #Koch and #Gattermann #Formylation Reaction: ruclips.net/video/kPP4PEhhdHU/видео.html
22. #Knoevenagel Reaction: ruclips.net/video/C_GKc7PXzgo/видео.html
23. #Mannich reaction: ruclips.net/video/PKw5JOgiy8E/видео.html
24. #Meervein-#ponndorf-#verley (#MPV) Reduction reaction mechanism ruclips.net/video/0dmKqDXqGbs/видео.html
25. #Michael #Addition #Reaction: ruclips.net/video/Q0lZtG9R_es/видео.html
26. #Oppenauer #Oxidation #Reaction || #Swern #Jones #Collins #Moffet #Sarett #Oxidation of #Alcohols: ruclips.net/video/O2Agjj5asgA/видео.html
27. Palladium catalysed coupling reactions: ruclips.net/video/Zas_JlccBNQ/видео.html
28. Perkin Reaction: ruclips.net/video/5KaYcNueuTI/видео.html
29. Pinacol-Pinacolone Rearrangement: ruclips.net/video/YjbnDV26jd0/видео.html
30. Reformatsky reaction : ruclips.net/video/r5qYVUF2A2E/видео.html
31. Reimer-Tiemann Reaction: ruclips.net/video/lI2UBsNbZkE/видео.html
32. #Ziegler #Natta Catalyst: ruclips.net/video/9ls6HZW4VrM/видео.html
Buchwald Hartwig Amination
Buchwald Hartwig amination reaction is an important reaction where aromatic amination is done mediated by Pd.
Cyanation
Cyanation is one of the reactions of Pd medium reactions to introduce CN group.
Carbonylation
Yes, carbonylation reactions can be done using palladium as catalyst.
C-C Bond & C=C Bond Formation Reactions with Stereochemistry
: ruclips.net/video/YqCH8AEccSw/видео.html
C-C Bond & C=C Bond Formation Reactions with Stereochemistry
: ruclips.net/video/YqCH8AEccSw/видео.html
Oxidation & Reduction Reactions with Stereochemistry: ruclips.net/video/qJoDhV4DX98/видео.html
Rearrangement Reactions with Stereochemistry
: ruclips.net/video/Lat7VXgAJ8o/видео.html
Oxidation & Reduction Reactions with Stereochemistry: ruclips.net/video/qJoDhV4DX98/видео.html
Rearrangement Reactions with Stereochemistry
: ruclips.net/video/Lat7VXgAJ8o/видео.html