Mass Spectrometry - Understanding M+, M+1 and M+2 Peaks

This lesson examines mass spectrometry in more detail when analyzing parent mass peaks. Specifically, we discuss the M+ peak as well as the M+1 and M+2 peaks associated with various isotopes. Some examples include carbon 13, nitrogen 15 and both chlorine and bromine isotopes.
Parent Peak versus Base Peak in Mass Spec Lesson:
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The Spectroscopy Solving Course: • Solving Structures wit...
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can we get M+3 peak in mass spectra and why?

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I am not understanding the difference between m/z value and mass of following compound please guide
Compound Name Retation Time(RT) m/z Mass Score Formula
Quadrigemine A 11.715 735.4126 690.4143 90.09 C44 H50 N8

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