Freeze In Arkham (Batman and Robin 1997)

This superhero adventure finds Batman (George Clooney) and his partner, Robin (Chris O'Donnell), attempting to the foil the sinister schemes of a deranged set of new villains, most notably the melancholy Mr. Freeze (Arnold Schwarzenegger), who wants to make Gotham into an arctic region, and the sultry Poison Ivy (Uma Thurman), a plant-loving femme fatale. As the Dynamic Duo contends with these bad guys, a third hero, Batgirl (Alicia Silverstone), joins the ranks of the city's crime-fighters.

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Jesse Ventura and Ralf Moeller are actually friends of Arnold Schwarzenegger I remember Arnold and Jesse doing predator together and Ralf starred in Conan the adventurer after Arnold played Conan the barbarian