Selenium. Red-Black Transformations

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  • Опубликовано: 12 сен 2024

Комментарии • 196

  • @pyr0duck676
    @pyr0duck676 Год назад +31

    Two reasons I love your videos:
    1. They are AMAZING works of art! Have you considered entering in a scientific art competition?
    2. I love that you explore lesser known reagents and compounds. There are so many chemistry RUclipsrs who have videos on nitric acid, sulfuric acid, magnesium combustion, thermite, etc. But how many RUclipsrs demonstrate selenium compounds reacting with anhydrous hydrazine? Only Chemical Force! Keep up the wonderful work!!!
    Also, could you do a video exploring the various xenon compounds? That might be interesting!

    • @prapanthebachelorette6803
      @prapanthebachelorette6803 Год назад

      Because he IS the force 😉

    • @helldad4689
      @helldad4689 Год назад +3

      Who would even compete against him in an art competition? He is a league of his own

    • @ChemicalForce
      @ChemicalForce  Год назад +7

      Creating a video about xenon chemistry would be quite expensive, considering the average number of views on the channel :(
      Currently, I don't have plans to produce such a video, but I hope to cover this topic in the future to close that gestalt :D

    • @SciDOCMBC
      @SciDOCMBC Год назад

      I also think that his videos are great, especially because he sometimes combines very exotic reaction partners. In defense of the other chemistry RUclipsrs however one has to admit that reagents such as thionyl chrlord for example, which is very often used in labs, are sometimes very difficult to obtain for private individuals.

    • @SciDOCMBC
      @SciDOCMBC Год назад +1

      ​@@PaonporteurTo be honest, I don't really understand your hateful words against NileRed. In any case, I am also deeply disappointed by Chemical Force's reaction to your comment. What did NileRed do to get overthrown? He has over 5.6 million subscribers. So many RUclipsrs seem to be interested in it. Many users here are only interested in the reactions shown being as violent as possible. However, NileRed subscribers are interested in syntheses and their explanation and not that it splashes, cracks and burns as violently as possible. There should be enough space for everyone on RUclips and with your comment you only make yourself look ridiculous. This is not about a royal title, but about science. Your comment alone shows that you are not interested in the science itself, but in the loud boom.

  • @AJ-qv9yo
    @AJ-qv9yo Год назад +38

    Beautiful as always. You manage to get the most beauty out even "dull" elements. Se sits in my element collection, and now I enjoy all the beauty of it. Every element has its own internal beauty and fascination one only needs to get it to shine.

    • @herrhaber9076
      @herrhaber9076 Год назад +1

      Selenium ? Dull ? Watch the movie Evolution with David Duchovny ;)
      (Or if you have pityriasis versicolor then SeS2 is a lifelong friend)
      Joke aside, you are right and as always I saw reactions I wouldnt even have thought of without Chemical Force.

    • @ajingolk7716
      @ajingolk7716 2 месяца назад

      ☣☢⚠️

  • @lucasfortier3682
    @lucasfortier3682 Год назад +10

    Shit i didn't want the video to end.
    Chemistry community loves you man.

  • @daltonsoutherland8836
    @daltonsoutherland8836 Год назад +73

    Why do you not have 10 million subscriber your the best chemistry channel on RUclips bro 😉❤️

    • @elliotwilliams7523
      @elliotwilliams7523 Год назад +2

      Got to be the accent. We really like what we see. So many reactions we knew could happen just didn’t get to try. I love it

    • @procactus9109
      @procactus9109 Год назад +1

      *you're

    • @ignilc
      @ignilc Год назад

      because people like to watch nilered's stupid videos

    • @DerVerschlinger
      @DerVerschlinger Год назад +3

      ​@@elliotwilliams7523the accent makes it more authentic

    • @daltonsoutherland8836
      @daltonsoutherland8836 Год назад

      @@procactus9109 thanks for the correction dickhead 😂

  • @pezboy715
    @pezboy715 Год назад +7

    1:25 “resembling erythrocytes”??? Damn, you’re a well-educated man beyond just chemistry, it seems! Best chemistry channel on YT

  • @raiyiar
    @raiyiar Год назад +8

    the sculpture of the molten selenium poured into water first gave me praying mantis vibes, then you turned it on its side, and it resembled a keith haring style drawing :O love the stuff

  • @Kyu_97
    @Kyu_97 Год назад +6

    Your videos should be used by universities and highschools to showcase the different elements in class, for real I looove your work, I wish chemistry was a more popular topic on RUclips 😢

  • @executive
    @executive Год назад +3

    it's amazing seeing the solid, liquid and gas phases of a metalloid all together at relatively low temperatures. Fantastic footage.

  • @alexhatfield2987
    @alexhatfield2987 Год назад +4

    Peerless. I await CF new uploads like an 8 year old boy waiting for Xmas, and I’m never disappointed.

  • @aformalevent
    @aformalevent 6 месяцев назад +1

    I absolutely love your work. The videography is such high quality that it's a joy to watch these beautifully captured reactions. Be proud of what you do man! Elevating youtube chemistry to be heights on style.

  • @natuhaysertkaya3391
    @natuhaysertkaya3391 Год назад +10

    I would have loved to see selenium and sulphur melted together in varying ratios and tested for its material properties. Also would have liked to see arsenic and selenium reactions.

  • @mikestewart4752
    @mikestewart4752 Год назад +6

    Selenium was used in photocopiers just before I got into the industry. Would love to see some electro/photochemical reactions!

    • @takingthescenicroute1610
      @takingthescenicroute1610 Год назад +4

      One probably still finds a coating of it on the print drums of laser and LED printers.
      The drum is first charged with a high voltage corona wire or charging roller.
      The Se becomes conductive and locally grounds out the charge wherever light contacts it.
      The parts of the drum still charged attract the oppositely-charged toner particles.

    • @mikestewart4752
      @mikestewart4752 Год назад +3

      @@takingthescenicroute1610 I believe selenium was phased out due to toxicity concerns. I worked for a Japanese manufacturer and anything manufactured post 2010 had switched to a photosensitive polymer coating that would, like you say, take on an electrical charge from the corona wire. I believe the digitalization of the process that also contributed to selenium’s falling out of use. I’ve definitely seen what you are referring to though… The “Good Ol’ Days” 🙂☮️ from 🇨🇦

  • @Fredpotts
    @Fredpotts Год назад +11

    Organo-selenium compounds are easily absorbed through the skin. I once did an oxidation or an aldehyde with SeO2. I must have absorbed some of the reaction products because I smelled like a skunk for two weeks.

    • @chriswalford4161
      @chriswalford4161 Год назад

      …., whereas you normally smell like what?

    • @Fredpotts
      @Fredpotts Год назад

      @@chriswalford4161 More like a civet...

    • @ukeedge2761
      @ukeedge2761 6 месяцев назад

      ​@@chriswalford4161i guessing not a skunk, dont be du mb. Please not here.

    • @TheDriller-Killer
      @TheDriller-Killer 6 месяцев назад

      @Fredpotts It's the same with Tellurium, there's an old saying amongst chemists, that you can tell if somebody has been working with the stuff, when they enter a room. 😂😂😂

  • @terribleterrier1685
    @terribleterrier1685 Год назад +2

    Always the best surprise to see a new ChemcalForce in my notifications. Your editing, visual fidelity, and music are honestly amazing.

  • @Vile_Entity_3545
    @Vile_Entity_3545 Год назад +2

    You have just gotta love this channel

  • @robertmonroe9728
    @robertmonroe9728 Год назад +4

    The easiest way of getting red selenium is dissolving the black one in concentrated hot alkali or even melt with it. Then dissolveing in water you will get bright red solution of polyselenites and polyselenides. After adding any acid, sulphuric or muriatic, you will get red form

  • @GrumpyOrc
    @GrumpyOrc Год назад

    Beautiful reaction footage as always, the way red Selenium forms such larger crystals was especially interesting.
    And I'm never going to get tired of watching anhydrous hydrazine react with things.

  • @mysock351C
    @mysock351C Год назад +4

    I wonder how it smells outside? Selenium rectifiers had their own unique stench when they burned out. I can imagine it being perhaps a bit malodorous in a similar fashion if the fume hood doesn't have some sort of scrubber.

    • @Calilasseia
      @Calilasseia 3 месяца назад +1

      Organoselenium compounds are famous for their vomit inducing stenches. See Derek Lowe and his chemistry blog for more on this.

  • @rhagchem3650
    @rhagchem3650 Год назад +2

    Your interpretation is very simplistic. What is red selenium?
    1) There are two allotropes of selenium. Crystalline monoclinic red forms of Se8 and gray hexagonal. Then we have amorphous forms that can appear red, therefore quickly turn black when heated. Crystalline forms cannot be prepared by reducing Se4+ (N2H4, SO2).
    Gray selenium is produced by very slow crystallization of liquid selenium.
    Red selenium Se8 can be obtained from a "solution of selenium in sulfuric acid" and its recrystallization from carbon disulfide. "Amorphous red selenium" is not soluble in carbon disulfide.
    Rapid cooling of the melt yields amorphous selenium as a glassy mass...sometimes called vitreous selenium, which is usually sold to chemists.
    2) The reaction with sulfuric acid can be complicated:
    8 Se + H2SO4 = (Se8 2+) + 2 (HSO4 -) + 2 H2O + SO2
    and reaction with water:
    (Se8 2+) + SO2 + 2 H2O = Se8 + H2SO4 + 2 (H +)
    SO2:
    (only what remained in solution after the reaction)
    or
    8 (Se8 2+ ) + 8 H2O = 7 Se8 + 8 H2SeO3 + 16 (H + )
    The green solution is because it probably contains ions (Se 82+) and probably also others, e.g. (Se4 2+) ...

    • @ChemicalForce
      @ChemicalForce  Год назад +1

      I really wanted to obtain crystalline selenium to demonstrate it in the video. However, I encountered a challenge: selenium is only slightly soluble in CS2, requiring a large amount of the solvent to yield noticeable results.
      When shaking red selenium with CS2, the latter turns yellowish, possibly due to its dissolution.
      An alternative approach could involve using SeOCl2 to obtain crystalline red selenium, as it dissolves it much more effectively. However, I couldn't find information about this method, which may be attributed to the rarity of the reagent.

    • @GenosseRot
      @GenosseRot Год назад +1

      @@ChemicalForce The black amorphous selenium is slightly soluble in CS2. If you mix the black selenium (I strongly advise to use the black selenium you made from quickly cooling the molten selenium) ground it up to a fine powder and let it stir for a while in CS2 at least some of it should go into solution. The you can let the solution evaporate slowly (maybe in a crystallizing dish with a watch glas over it, so that only a small opening is left) you should see the formation of red crystals which are either alpha or beta red selenium (depends on the evaporation speed and temperature). I can imagine that it can look quite nice.
      Another thing to think about is the forgotten third but most important modification of selenium: Gray selenium. This is the most stable form of selenium and it is a metalloid with semi-conducting properties. It was the first material where the photovoltaik-effect was observed. If you connect 2 wires to it and give it a little bit of voltage you should see that the current changes greatly depending on the amount of light that gets to the material. Grey selenium can be made by heating any form of selenium to ~ 180 °C for some time or by cooling down molten selenium slowly. This stuff is then not so glassly like the black selenium (amorphous) you have shown.
      Either way: Great video! I'm a selenium chemist and it was a great joy to see you making some stuff with it. Maybe selenium won't have its last show on your channel with the H2SeO4 video? I would like it very much. It is a very interessting element and I would like to see more ;)

    • @rhagchem3650
      @rhagchem3650 Год назад

      @@GenosseRot Beautiful gray selenium crystals can be found on tailings coal dumps.

    • @rhagchem3650
      @rhagchem3650 Год назад

      @@ChemicalForce Yes, it's a bit of a problem! Selenium is not a big chemical topic. :) SeOCl2 is a relatively exotic substance. I used to be looking for information about this. Maybe here, you probably know. Publication: Monoclinic selenium crystal growth (cannot insert doi). Where it is claimed that selenium is "well" soluble in methylene iodide.

    • @ChemicalForce
      @ChemicalForce  Год назад

      ​@@GenosseRot there will be at least two more videos about selenium chemistry ;)

  • @masterluc
    @masterluc Год назад +1

    I enjoy the beauty of - and cannot imagine the effort that goes into your videos.

  • @SaunaShruti
    @SaunaShruti Год назад +3

    U explain and demonstrate the experiments so well. U r really a genius guy. Keep up with your good work.

  • @artsmith1347
    @artsmith1347 8 месяцев назад

    Very nice photography and good choice of music. Thank you.

  • @evilotis01
    @evilotis01 Год назад +1

    7:53 me: wonders what'd happen w anhydrous hydrazine, but figures that'd prob be too difficult/dangerous
    Feliks: i gotchu fam

  • @paranoiia8
    @paranoiia8 Год назад +1

    Amazing red color... So deep and vivid.

  • @drhaese
    @drhaese Год назад

    Many thanks for the exciting demonstration of the fascinating world of Se and its inorganic reactions.

  • @DragonsAndDragons777
    @DragonsAndDragons777 Год назад +1

    I never even knew about Selenium
    Edit: Those explosions are amazing!

  • @j_sum1
    @j_sum1 Год назад

    Intriguing and unusual colours. Amazing shapes formed. Just beautiful.

  • @KomradZX1989
    @KomradZX1989 Год назад

    Your videos are absolutely the best bar none ❤❤❤

  • @gerry4b
    @gerry4b Год назад

    It's rare to discover true beauty in life... thanks for sharing.

  • @ИванГригорьев-х4б

    Beautiful! Fantastic work! 👍👍👍

  • @TrippyMCT
    @TrippyMCT Год назад

    Great video as always. Love the hoodie!

  • @TheTransporter007
    @TheTransporter007 Год назад +1

    Always a good day when ChemForce posts!

  • @trishblackman7403
    @trishblackman7403 Год назад

    Since I can’t blow shit up here at home….I’ll let you do it and sit back n watch the best stuff on tv!😊

  • @matze1389
    @matze1389 Год назад

    Damn... i just discoverd your channel. I love your videos, this is chemical art and informative reactions and so on😮😀

    • @ChemicalForce
      @ChemicalForce  Год назад +1

      Yes, you missed a lot! :D
      Well, welcome to the board!

    • @matze1389
      @matze1389 Год назад

      @@ChemicalForce :) now i have to watch so many Videos from you

  • @jimsvideos7201
    @jimsvideos7201 Год назад

    Gorgeous cinematography.

  • @amiralozse1781
    @amiralozse1781 Год назад

    your videos are a form of art:
    Chemical Art !

  • @shrivanth6774
    @shrivanth6774 Год назад

    Akh I am not ready for this it's extremely heart 💓 warming

  • @procactus9109
    @procactus9109 Год назад

    Absolutely one of the most bizarre elements. As usual excellent showcase

  • @reverendtfg6802
    @reverendtfg6802 Год назад +2

    *How does this guy not have millions of subscribers???*

  • @lugarial
    @lugarial Год назад +2

    Great video, as always :)
    I still have a question, what differs structurally between red and black selenium ?

    • @dmsnch
      @dmsnch 11 месяцев назад

      Red Se is similar to yellow Sulfur with eight-membered rings. Black Se is long chains of atoms, apparently in giant rings of around 1000. See Wikipedia.

  • @Grateful.For.Everything
    @Grateful.For.Everything 7 месяцев назад

    👏👏👏👏👏👏👏👏👏👏👏 really nice visuals!!!

  • @matiastripaldi406
    @matiastripaldi406 Год назад +1

    I've never seen anyone clip a lapel mic to their beard. Cool!

  • @transistor754
    @transistor754 Год назад +1

    thank you for a great video... please could you do "Touch Powder" as we used to make at school? If you have done iodine Crystals and Ammonia before, please could you place the link? I could not find one? It was supersonic (i thought) and could cause successive detonation, when samples were placed too close. A great thing too see on your Slo Mo camera? good fun.

  • @arnavtete7793
    @arnavtete7793 Год назад +1

    thanks for this video!

  • @jhyland87
    @jhyland87 Год назад

    Hey, off topic, but your English is getting much better. :-)

  • @jansenart0
    @jansenart0 Год назад +1

    Hydrazine, lovely!

  • @borgmardunkleson2225
    @borgmardunkleson2225 Год назад

    how this channel doesnt have more subs is criminal

  • @decepticonne
    @decepticonne Год назад

    you take a great chemistry picture man, you're like the klapheck of chemistry youtube

  • @84xxComeGetSomexx84
    @84xxComeGetSomexx84 Год назад +2

    Can you do any reactions with Superoxides? I find oxygen generation really interesting

  • @b33cux
    @b33cux Год назад

    This is ART!

  • @julienweems6166
    @julienweems6166 Год назад +2

    All of these selenium reactions look like something you would find in the bottom of a slavic pond.

  • @iswm
    @iswm Год назад

    the lapel mic clipped to your beard is quite the flex.

  • @Anar10n
    @Anar10n Год назад

    Ah yes. The Dark Mastery. Didn't think I will see one practicing it ever again

  • @BhushanWagh-ed9pm
    @BhushanWagh-ed9pm Год назад

    Demonstrate all chemical elements in the modern periodic table.
    For each element 7 min of a video is enough.
    Uses in day to day life also

  • @williambradley611
    @williambradley611 Год назад +1

    Love your vids

  • @spiderdude2099
    @spiderdude2099 Год назад +1

    Selenium is so cool. I wish it was less toxic

  • @Emm1738
    @Emm1738 Год назад

    Yo, I see that WVU shirt, my man! Mountaineers represent

  • @tracybowling1156
    @tracybowling1156 Год назад

    Felicks, your videos are superb. My only concern is that you need a UVA or VT shirt. 😂

  • @cpchehaibar
    @cpchehaibar Год назад

    If there's a measure of how long it takes for a viewer to like, I'm sure you get pretty good on it.

  • @echothebot
    @echothebot Год назад +1

    Oooh yes Nice Video, Thank you!

  • @ingorichter649
    @ingorichter649 Год назад

    I simply like this material.

  • @jayday4879
    @jayday4879 Год назад

    Very educational I would like to see more violent decompositions back when I was a boy when dinosaurs existed only got interested in science and chemistry because my teacher would blow something up and leave all our ears ringing for hours

  • @patasalada.willproctor
    @patasalada.willproctor Год назад

    Literally the best chemistry pornographer on the internet, bar none.

  • @alystair
    @alystair Год назад

    10:02, are those selenium hairs growing on the end of the quartz tube? Remarkable photography

  • @vdvideocity
    @vdvideocity Год назад

    Beautiful blue colors. Thanks!

  • @captainchicky3744
    @captainchicky3744 Год назад

    This is amazing :D

  • @scrotiemcboogerballs1981
    @scrotiemcboogerballs1981 Год назад

    Very cool video thanks for sharing

  • @mahdiahmadi80
    @mahdiahmadi80 Год назад +1

    Soo nice and cool 👌👌👌👌🙏🙏🌹

  • @jonbob2
    @jonbob2 Год назад

    Good use of the beard as a mic attachment point!

  • @takingthescenicroute1610
    @takingthescenicroute1610 Год назад

    The semiconductive, photochemical, and electrochemical properties of Se might be worth exploring.

  • @xxz4655
    @xxz4655 Год назад

    This content is amazing beautiful presentation on selinium thank you

  • @Spectrolite1
    @Spectrolite1 Год назад

    Fantastic element, wow!

  • @kittty2005
    @kittty2005 Год назад

    AWESOME!

  • @trulyinfamous
    @trulyinfamous Год назад

    I really liked the music choice in thia video. I would've enjoyed having a list of music used in the description as some of these songs I might want to listen to on their own. What's the song at around the 5 minute mark?

  • @Yamazaki339
    @Yamazaki339 Год назад

    Love your videos so much! 🤗

  • @aaronsmith8073
    @aaronsmith8073 Год назад

    Really enjoy your videos!

  • @aqdrobert
    @aqdrobert Год назад +1

    Appreciate that RUclips does not emit selenium compound odors over my screen.

  • @Esterified80
    @Esterified80 Год назад +1

    Very cool element. Do organoselenium reactions with it.

  • @Chimicat7
    @Chimicat7 Год назад

    хорошо

  • @erics3737
    @erics3737 Год назад

    Beautiful and terrifying at the same time.

  • @dansheppard2965
    @dansheppard2965 Год назад

    Great video, as ever, ChemicalForce!

  • @comsigninc
    @comsigninc Год назад

    Nice work.

  • @mistercroc9407
    @mistercroc9407 Год назад

    Good stuff !

  • @Kargoneth
    @Kargoneth Год назад

    Interesting chemistry.

  • @bfm1q2w
    @bfm1q2w 4 месяца назад

    Goat.

  • @DonnyHooterHoot
    @DonnyHooterHoot Год назад

    Awesome video! Keep it up!

  • @yannisconstantinides7767
    @yannisconstantinides7767 Год назад

    So very cool.

  • @arbodox
    @arbodox Год назад

    Wow! I didn't know selenium is quite viscous in liquid form! Why does selenium form these red blood cell shaped biconcave disks when it solidifies in water?

  • @alberthofmann420
    @alberthofmann420 Год назад

    Excellent Microphone placing ;)

  • @pavelsejvl1072
    @pavelsejvl1072 Год назад

    Some chemistry with Wollins' reagent - sellenium derivate of Lawessons' reagent

  • @zeddlesnake8087
    @zeddlesnake8087 Год назад

    barium chemistry would be interesting, strontium chemistry would be interesting as well

  • @sxl-kb5zb
    @sxl-kb5zb Год назад

    Well,it is pretty good that I was so like it

  • @Dude3078
    @Dude3078 Год назад

    Primeiro Brasileiro a comentar no seu canal

  • @Kargoneth
    @Kargoneth Год назад

    Concoidal fractures. Might make a decent arrowhead.

  • @Ghost-dx8mm
    @Ghost-dx8mm Год назад

    DUDE, your wearing a WV jersey...I'm from Wv, are you from Wv by chance?

  • @Kargoneth
    @Kargoneth Год назад

    @17:00 Looks like a painting burning as it's being painted.

  • @Nomaditis
    @Nomaditis Год назад

    13:33 When he starts heating the Sulphuric Acid, its volume increases Quite noticeably. Does Sulphuric Acid expand that much when heated? Or does it have something to do with the reaction?

  • @mysock351C
    @mysock351C Год назад

    The real secret is all of his selenium came from 550 Central Park West after the Stay-Puft Marshmallow man knocked it down. True story.
    Of course if you think about it the whole thing makes no sense in real life since selenium is more a semiconductor than a structural material, and is very brittle. But it sounded cool in the movie.

  • @darkobul1
    @darkobul1 Год назад

    You should do experiment on selenium sensitivity to light and change of resistance.

  • @WetDoggo
    @WetDoggo Год назад

    Next time on chemical force: Tellurium vs Selenium and Sulfur... maybe oxygen?