The compound Os5(CO)15C has TEC 74 predicted structure is square pyramidal but it is a exception the structure is -edge capped tetrahedron.If you want to cross check refer to B.D Elias pg no. - 187 Thanks
Original structure was thought like octahedral with one removed vertex and it look likes either tetrahedral or square pyramidal, plz refer original research paper published in springer. Thank you.
@@TETRAHEDRONCHEMISTRYCLASSES Can you explain, what is the structure of the complex, because you mentioned n+3 is arachno, but in this case n-3 is coming. How did you conclude structure of the complex is arachno????
Sir,in problems number 2 i.e,Rh6(CO)16,the complex is closo ,but when we see TEC and n combination there are two possible geometry,since 86 and 6 are there for octahedral and capped square pyramidal.You choose actahedral.Can u please give me clear reason.
![Wade Rule and Wade-Mingo's rule[Simplest Explanation] | Finding Geometry of Metal Cluster](http://i.ytimg.com/vi/qypcvnf9k3I/mqdefault.jpg)
Thank you for the lecture!
Sir very good explanation and it is very easy understanding way keep it up sir for us
amazing lecture sir..
Very good lecture. Thank you very much sir.
awesome explanation sir.
Thankyou sir ji
Awesm lec
Thank you sir,
The compound Os5(CO)15C has TEC 74 predicted structure is square pyramidal but it is a exception the structure is -edge capped tetrahedron.If you want to cross check refer to B.D Elias pg no. - 187
Thanks
Original structure was thought like octahedral with one removed vertex and it look likes either tetrahedral or square pyramidal, plz refer original research paper published in springer. Thank you.
Very important for csir/gate
Sir can plz explain in example Os15(Co)16C, why we shouldn't consider carbon in number of metal atom
@anupama I think there is a mistake in writing the formula.
Sir, can u explain the geometry of [Os10(CO)24C]2-
Tetracapped octahedron.
@@TETRAHEDRONCHEMISTRYCLASSES
TEC is 134 and PEP is 7. Is it right sir?
Absolutely right.
@@TETRAHEDRONCHEMISTRYCLASSES
Can you explain, what is the structure of the complex, because you mentioned n+3 is arachno, but in this case n-3 is coming. How did you conclude structure of the complex is arachno????
Yes sir can you kindly explain how it will be Arachano.. I'm too getting n-3 for this complex
Sir boron complex B4H10 and Sn9 -charge 2 like k b capping and geometry explain krna
Thanks sir
For last question n-3 is coming sir so how can it be arachno
Tq very much sir
Thanks you sir ❣️❣️❣️🙏🏻🙏🏻🙏🏻
Sir,in problems number 2 i.e,Rh6(CO)16,the complex is closo ,but when we see TEC and n combination there are two possible geometry,since 86 and 6 are there for octahedral and capped square pyramidal.You choose actahedral.Can u please give me clear reason.
I refer standard text book to conclude this answer.
Plz follow capping rule
Sir please i need the slides..can you send me
Geometry determination is not clear.. You skiped it carefully
Plz mention time, I will try to explain in other lecture.
Sir, is there any method for calculation of number of capping atom...I mean it is monocapped, dicapped ....etc
Couldn't find anywhere....
Sir pls explain in english