René M. Williams
René M. Williams
  • Видео 41
  • Просмотров 110 318
Light Activated Molecular Motors: Rotaxanes and Cis-Trans Isomerization of Feringa Rotors Nobel 2016
#nanomaterials #education #photochemistry #nobelprize2016 #molecular #motor #nobelprize
#molecularstructure #motormolecules #Feringa
This is an on-site lecture (recorded with Zoom) at the MSc level for chemistry students that are interested in Nanomaterials and Supramolecular Chemistry. Nanotechnology and Photoactive materials.
This lecture introduces molecular machines and their properties are discussed.
Molecular motor molecules that do a translational motion as well as systems that have a rotational operation are discussed.
This lecture starts with rotaxane work performed in Amsterdam (Buma, Brouwer, Woutersen, Leigh).
Than the work of Nobel prize winners Jean-Piere Sauvage, Fraser Stoddart...
Просмотров: 663

Видео

Quantum dots and the "particle in a box" model. Nobel prize of 2023 "in a nutshell". Nano-particles.
Просмотров 437Год назад
#nanomaterials #education #photochemistry #nobelprize2023 This is a recorded Zoom lecture at the MSc level for chemistry students that are interested in Nanotechnology and Supramolecular Chemistry. Nanotechnology and Photoactive Nanomaterials. This lecture introduces quantum dots, as semi-conductor nanoparticles. Their structure and properties are discussed. Nanoparticle synthesis. This lecture...
Perovskite on Silicon Tandem Solar Cells: 34.6% PCE, Composition, Components, Hole Transporting SAM
Просмотров 2,4 тыс.Год назад
#tandemsolar #perovskite #solar #photovoltaics #nanomaterials #solarcell #education #photochemistry This is an "on site" lecture (recorded with zoom and edited) at the MSc level for chemistry students that are interested in Nanotechnology and Supramolecular Chemistry. Nanotechnology and Photoactive Nanomaterials. READ FOR FREE: rdcu.be/drNEw This lecture introduces the tandem solar cell materia...
Glow Nation Phosphorescence
Просмотров 61Год назад
This video shows the long lived emission of commercial powders obtained from GlowNation. They work with charge transfer. Slow charge recombination gives the long-lived emission.
Molecular Symphony: asymmetrically substituted perylene bisimides for energy and electron transfer
Просмотров 197Год назад
This is a "molecular symphony" of asymmetrically substituted perylene bisimides. Adapted from a presentation given on Cyprus in 2009. Publications that feature in this presentation are: A highly soluble asymmetric perylene-bis (dicarboximide)-acceptor system incorporating a methylene bridged methoxybenzene-donor: solvent dependence of charge transfer interactions doi.org/10.3906/kim-0811-33 Tri...
Long-lived Green Photo-luminescence of Heat Treated Human Bones: the Glow of Cremated Remains
Просмотров 354Год назад
This video shows the emission of human bone fragments, that were heated at 600 degrees Celsius for a short time. Timing is "real live", size is ~half a centimeter, or ~3 centimeter. Recorded with a Nikon camera (D3300), using a UV photo-flash for excitation. This was obtained during the internship of Emma Schut, as part of the Master of Forensic Science program. With a dark adapted human eye, t...
Reactivity of Molecular Oxygen in Ground and Excited State: Why is Singlet Oxygen Super-Reactive?
Просмотров 7 тыс.2 года назад
#chemistry #photochemistry #molecular #education #oxygen #anticancer #quantumphysics #quantumtheory #molecularorbitaltheory This is an edited video-lecture for chemists that are interested in molecular oxygen, photochemistry and singlet oxygen. The triplet ground state of molecular oxygen and the excited state, singlet oxygen, are discussed. (A similar lecture has been presented for BSc student...
Metal Coordination Effects on the Photophysics of Dipyrrinato Photosensitizers. Paula C. P. Teeuwen
Просмотров 9472 года назад
#education #chemistry #photochemistry #anticancer #molecular #inorganicchemistry #organometallics #theory #chargetransfer This is a recorded (edited) zoom lecture by Paula Teeuwen, presenting her Literature Thesis for her Master of Science degree at the University of Amsterdam. It is intended for chemistry students, PhD students and researchers interested in photochemistry, photodynamic therapy...
Shivan Bissesar presenting on Spin Orbit Coupling in Orthogonal Charge Transfer States: UvA 2021
Просмотров 3132 года назад
This is a recorded (edited) zoom lecture by Shivan Bissesar about his internship at UvA. It is related to the following scientific publication: Spin Orbit Coupling in Orthogonal Charge Transfer States: (TD-)DFT of Pyrene-Dimethylaniline by Shivan Bissesar Davita M. E. van Raamsdonk Dáire J. Gibbons René M. Williams Molecular Photonics Group, van ’t Hoff Institute for Molecular Sciences (HIMS), ...
Perovskites II; Crystals, Orbitals and Trap-states in Perovskites-Structural and Electronic Aspects
Просмотров 3,1 тыс.2 года назад
#perovskite #solar #photovoltaics #nanomaterials #solarcell #education #photochemistry #orbitals #structure This is a recorded Zoom lecture at the MSc level for chemistry students that are interested in Nanotechnology and Supramolecular Chemistry. Nanotechnology and Nanomaterials. Photoactive Nanomaterials. There are ~15 video's in this course In this second lecture on perovskites structural fa...
Using Computational Chemistry to Describe & Understand the SOCT-ISC mechanism -Davita van Raamsdonk
Просмотров 4252 года назад
This is a recorded (edited) zoom lecture of Davita van Raamsdonk on her Literature Thesis, on the application of computational chemistry to the SOCT-ISC mechanism. This is part of the MSc program at the University of Amsterdam. Her literature thesis work is incorporated into the following publication: Her work is used in the main text, but especially in the Supplementary Material, where her Lit...
Spin Orbit Coupling in Orthogonal Charge Transfer States: TD-DFT of Pyrene-Dimethylaniline. RMW-UvA
Просмотров 1 тыс.3 года назад
#education #photochemistry #orbitals #electrons This is a recorded (edited) zoom lecture related to the following scientific publication: Spin Orbit Coupling in Orthogonal Charge Transfer States: (TD-)DFT of Pyrene-Dimethylaniline by Shivan Bissesar Davita M. E. van Raamsdonk Dáire J. Gibbons René M. Williams Molecular Photonics Group, van ’t Hoff Institute for Molecular Sciences (HIMS), Univer...
"A colourful_ phd" - Instagram report - Dáire J. Gibbons - Porphyrin Research in POLYTHEA
Просмотров 2203 года назад
This is an edited screen recording of the instagram page of Dáire J. Gibbons. "A Colourful_PhD" is the name of this instagram page. colourful_phd The PhD Thesis of Daire can be found here: hdl.handle.net/11245.1/59fd71af-9b84-4225-9e6d-8cb70f7c1a17 He worked within www.polythea.eu/news-2/ Music: "By the Fireplace", (from RUclips Editor). Daire 4 Insta Publish 24-01-2022
Black Silicon Solar Cell materials: Genesis, Development and Nano-structure: from Mazur to MACE-RMW
Просмотров 6993 года назад
This is a recorded hybrid Zoom lecture at the MSc level for chemistry students that are interested in Nanotechnology and Supramolecular Chemistry. Nanotechnology and Nanomaterials. Photoactive Nanomaterials. There are ~15 video's in this course This lecture introduces Black Silicon as solar cell material for photo-detectors, photo-catalysis and anti-bacterial materials. Their structure and meth...
The Photochemistry of Pyrene II - Nature of the Excimer, Orbitals, Vibronic Coupling - Williams, UvA
Просмотров 1,6 тыс.3 года назад
This is a lecture at the MSc level for chemistry students that are interested in molecular photochemistry. From the nature of the excimer to the orbitals and configuration interaction to interaction of electronic transitions and vibrational transitions. Learning objectives: The nature of the excimer is an excitonic interaction with only a slight charge transfer interaction. The exciton is deloc...
Marcus Waves: Marcus theory in 3 dimensions with changing parameters
Просмотров 843 года назад
Marcus Waves: Marcus theory in 3 dimensions with changing parameters
Marcus Waves: Marcus theory in 3 dimensions
Просмотров 1643 года назад
Marcus Waves: Marcus theory in 3 dimensions
The Photochemistry of Photodynamic (anti-cancer) Therapy: Singlet Oxygen, Reactive Oxygen Species
Просмотров 8 тыс.3 года назад
The Photochemistry of Photodynamic (anti-cancer) Therapy: Singlet Oxygen, Reactive Oxygen Species
Photoinduced Electron Transfer - The Semi-Classical Marcus-Levich-Jortner Theory. RE-EDIT - RMW, UvA
Просмотров 1,8 тыс.3 года назад
Photoinduced Electron Transfer - The Semi-Classical Marcus-Levich-Jortner Theory. RE-EDIT - RMW, UvA
The Exciplex: Charge Transfer Emission and Absorption of Pyrene and Fullerene aniline complexes
Просмотров 1,9 тыс.3 года назад
The Exciplex: Charge Transfer Emission and Absorption of Pyrene and Fullerene aniline complexes
The Shockley-Queisser Limit: Theoretical limits of solar cells and how to surpass them. RMW-UvA
Просмотров 6 тыс.4 года назад
The Shockley-Queisser Limit: Theoretical limits of solar cells and how to surpass them. RMW-UvA
My lectures in CHINESE! How to translate and change subtitles in YouTube (No Sound, see settings!)
Просмотров 4184 года назад
My lectures in CHINESE! How to translate and change subtitles in RUclips (No Sound, see settings!)
Charge Recombination and Intersystem Crossing in PMI-Carbazole Dyads, Davita van Raamsdonk, MSc, UvA
Просмотров 8084 года назад
Charge Recombination and Intersystem Crossing in PMI-Carbazole Dyads, Davita van Raamsdonk, MSc, UvA
Photoinduced Energy Transfer, Re-Edit, René M. Williams, UvA. Förster and Dexter mechanims. FRET.
Просмотров 2,4 тыс.4 года назад
Photoinduced Energy Transfer, Re-Edit, René M. Williams, UvA. Förster and Dexter mechanims. FRET.
Perovskite Solar Cell Materials: Introduction, Structure, Composition, Doping, Defects -Edit RMW-UvA
Просмотров 42 тыс.4 года назад
Perovskite Solar Cell Materials: Introduction, Structure, Composition, Doping, Defects -Edit RMW-UvA
Making Triplets from Photo-generated Charges, Observations, Mechanisms and Theory, (Edited) RMW, UvA
Просмотров 2 тыс.4 года назад
Making Triplets from Photo-generated Charges, Observations, Mechanisms and Theory, (Edited) RMW, UvA
Organic Solar Cells: Photo-active Nanomaterials - Nanotechnology and Nanomaterials 8, RMW, UvA
Просмотров 5914 года назад
Organic Solar Cells: Photo-active Nanomaterials - Nanotechnology and Nanomaterials 8, RMW, UvA
Artificial Supramolecular Systems Inspired by Nature - Nanotechnology and Nanomaterials 7, RMW, UvA
Просмотров 5304 года назад
Artificial Supramolecular Systems Inspired by Nature - Nanotechnology and Nanomaterials 7, RMW, UvA
Gecko's Feet and Stealth Airplane Coating - Nanotechnology and Nanomaterials 6, R. M. Williams, UvA
Просмотров 2884 года назад
Gecko's Feet and Stealth Airplane Coating - Nanotechnology and Nanomaterials 6, R. M. Williams, UvA
Moore's Law and Transistor Size - Nanotechnology and Nanomaterials 5, René M. Williams, UvA.
Просмотров 3324 года назад
Moore's Law and Transistor Size - Nanotechnology and Nanomaterials 5, René M. Williams, UvA.

Комментарии

  • @ibrahimmuhammad3445
    @ibrahimmuhammad3445 3 месяца назад

    Congratulations for the success recorded

  • @renem.williams9257
    @renem.williams9257 3 месяца назад

    Finally!! It seems my “prayers” have been heard! Recent work (of Gratzel, Sargent and Yuan) shows METHYLAMMONIUM-FREE perovskite materials can give excellent single junction devices with more than 26% PCE: doi.org/10.1038/s41586-024-08103-7 Not formate but acetate is one of the essential additives/components! doi.org/10.3390/molecules29020516 doi.org/10.1007/s43630-023-00500-7 rdcu.be/drNEw

  • @Anna-dw3jo
    @Anna-dw3jo 4 месяца назад

    Congratulations !! Thank you for Your step by step presentation. Thanks to YOU it is possibile to understand the topic.

  • @thayhuongchuyenhoalekhietq6803
    @thayhuongchuyenhoalekhietq6803 4 месяца назад

    Great lecture!

  • @ThreeTwentysix
    @ThreeTwentysix 4 месяца назад

    A very elegant description with Lewis diagrams. Thank you.

  • @arindamnandy6167
    @arindamnandy6167 5 месяцев назад

    Thank you sir for your explanation. Can you please share the ppt? Thanks in advance

  • @michaelarulanantham8833
    @michaelarulanantham8833 8 месяцев назад

    What would be the Shockley-Queisser limit with monochromatic light and a single junction solar cell tuned to that frequency?

    • @renem.williams9257
      @renem.williams9257 8 месяцев назад

      The SQ-limit always refers to a (standard) solar spectrum, not to a single wavelength. But EQE or IQE curves can come close to 100%, or certainly way above 90%. They report the efficiency at every wavelength. see for instance ruclips.net/video/6gYXdHs5Sfo/видео.html at ~ 10:00

    • @michaelarulanantham8833
      @michaelarulanantham8833 8 месяцев назад

      @@renem.williams9257 Many thanks for the personal reply and the link.

  • @michaelarulanantham8833
    @michaelarulanantham8833 8 месяцев назад

    Great video, will have to watch it a few times

  • @PravdaSeed
    @PravdaSeed 8 месяцев назад

    🧞 perovskite 💙🌀🇷🇺🌀💙

  • @saddiqueakbar4774
    @saddiqueakbar4774 9 месяцев назад

    Dear Professor I am searching postdoc in solar Cells. Please help me to find a research position. Thank u

  • @XiaoranHu-u9k
    @XiaoranHu-u9k 10 месяцев назад

    Thanks from a peer professor! Great video.

  • @hichamcharifi9634
    @hichamcharifi9634 10 месяцев назад

    TOP

  • @TrulyNaturalMom
    @TrulyNaturalMom 11 месяцев назад

    Thank you for this information of biochemistry’s use of photonic light. I use a device to introduce light & frequency to heal. This is a great explanation- because NO2 is the best way to heal inflammation and pain.

  • @petevenuti7355
    @petevenuti7355 Год назад

    Has FRET ever been experimentally evaluated in a medium with an index of refraction less than one? (FTL phase velocity)

    • @renem.williams9257
      @renem.williams9257 Год назад

      FRET in Metamaterials is rather popular in research: doi.org/10.1038/s42005-023-01347-1 doi.org/10.1021/acsphotonics.8b00484 doi.org/10.1016/j.nanoen.2020.105226 Meta materials can have a negative refractive index.

  • @petevenuti7355
    @petevenuti7355 Год назад

    Not long ago I saw a demonstration of a simple organic solar cell (fruit juice on TiO) , it got me really thinking. I took some chemistry before switching to computer science, so I knew you needed molecules with lots of conjugate bonds, and spectra in the energy level above the band gap of the semiconductor electrode. So I thought, I'll just get some peryline green from the art store, mix it up with some aniline, maybe some anthraquinone then turn it into a conductive polymer and I might have something better. I was thinking like why hasn't anyone else thought if it... That's an example of the Dunning Kruger effect. Classic. The more I looked into how to do such a solar cell, the more I learned, the more I realized I still need to learn. I am so glad to have found your channel! Very helpful, clearly understandable and very educational thank you very much! Is there a specific video of yours that specificly covers the energy transfer directly into redox reactions? Any intermediate level reading recommendations for my self education? Ideally I would like to design a system for an organic flow battery where the electrolyte gets charged directly by light, therefore removing many conversion steps, charge controllers & other ancillary electronics.. hence greater reliability simplicity and lower cost (given chemical stability) Seeing now how much more is known and how much more research has been done then I initially thought, I still have to ask why hasn't this already been done? What problem hasn't been solved yet?

    • @renem.williams9257
      @renem.williams9257 Год назад

      You could read this: dx.doi.org/10.13140/RG.2.2.16547.30244

  • @petevenuti7355
    @petevenuti7355 Год назад

    Regarding solar cells, with solid state electronics I understand the concept of a "band gap", but I believe with organic chemistry is referred to by different terms and measured in different units , something to do with homo and lumo between the excited states in the absorption & emission spectrum overlaps (I've been thinking of covalently coupling chromophores to conductive polymers) So, my question, _What is the equivalent term in biochemistry and what units does it use?_ I only took a year of chemistry before I switched to computer science so take it easy on me please 😉

    • @renem.williams9257
      @renem.williams9257 Год назад

      Marcus theory applies to photosynthesis: ruclips.net/video/YFzeMMOvhl0/видео.html See also text below this video; the Gunner paper is all about this. ruclips.net/video/GnPIbH6nM9o/видео.html

  • @ru1h
    @ru1h Год назад

    Great video. I'm still quite confused on the significance of the different acceptors that Miller and Closs used. Im I know they becoming more electron withdrawing does that make the transfer go quicker?. It appears that a few parameters are being investigated

    • @renem.williams9257
      @renem.williams9257 Год назад

      The acceptor strength changed the driving force, transfer goes faster and faster, up to the optimal rate, than it slows down!!! Inverted region.

    • @renem.williams9257
      @renem.williams9257 Год назад

      A vibration that mediates the transfer is determined, as well as the internal reorganization energy. Together they form the Huang Rhys factor.

    • @renem.williams9257
      @renem.williams9257 Год назад

      See also my lecture on Classical Marcus theory.

  • @ru1h
    @ru1h Год назад

    Would it be right to say that the rate constant of dexter's mechanism inversely proportional to the exponent of the distance between the donor and acceptor while for forster's mechanism; the rate constant is inversely proportional to sixth power of the distance

    • @renem.williams9257
      @renem.williams9257 Год назад

      Regarding the distance dependence of energy transfer: If we plot the natural logarithm of the rate vs distance, we get al linear curve for the Dexter mechanisms. The slope is negative and gives the beta value. doi.org/10.1021/ja990044b The abscissa gives the fastest rate at close contact. Similar observation have been made for photo-induced electron transfer. doi.org/10.1021/ja00245a014 If we do the same for the Forster mechanism, the curve is not straight, but is curved. www.wiley-vch.de/contents/jc_2111/2008/f800156_s.pdf The rate is proportional to 1/R^6 (see also at 27:00) Only changing the distance in molecular systems, keeping all other parameters the same, is often not that easy. SEE ALSO ADDITION IN TEXT BELOW VIDEO. (identical text). I would say that this agrees with your statement!!

  • @indirakafle7134
    @indirakafle7134 Год назад

    Thank you so much for your explanation!!

  • @oguzcangokce7636
    @oguzcangokce7636 Год назад

    Thank you for your detailed presentation!!

  • @saidaidsa1891
    @saidaidsa1891 Год назад

    If tesla panel can generate 350 watt how much perovskites panel can generate per watt ?🤔🤔

    • @renem.williams9257
      @renem.williams9257 Год назад

      You can not buy perovskite panels yet!! Tesla panels have a PCE of about 22%. Perovskite on silicon can give more than 30% PCE!! (see NREL chart, 33.7% PCE record). Maybe in ten years you can buy those panels. Now just hero cells in research.

  • @neilryan6258
    @neilryan6258 Год назад

    You explained this concisely and brilliantly, cheers

  • @gustavomoreira4882
    @gustavomoreira4882 Год назад

    Professor, excellent lecture! Greetings from the University of Minas Gerais in Brazil. I love the UvA, hope to do a PhD there and have the pleasure of seeing you speak in person.

    • @Anna-dw3jo
      @Anna-dw3jo Год назад

      Indeed the excellent explanation. All your lectures are a special piece of work.

  • @foroozanfaraji594
    @foroozanfaraji594 Год назад

    It was covering all the subjects around it as well and also incredibly brief and to the point. I'm so greatful

  • @arijeetsarangi2076
    @arijeetsarangi2076 Год назад

    Hello Sir , nice explanation. I am also working on Perovskites. There are lot of paper who does defect calculation, they are doing chemical potential phase diagram. Can you provide a tutorial for how to plot a phase diagram..

  • @panananananana
    @panananananana Год назад

    i thought the direct transition from triplet oxygen to singlet oxygen was spin forbidden?

    • @renem.williams9257
      @renem.williams9257 Год назад

      Yes indeed! The absorptive and emissive transitions of molecular oxygen are spin-forbidden!! Forbidden transitions still occur! But with a low probability. This implies that the molar absorption coefficient is very low (for the absorption) and the emission is very long lived. The latter is especially influenced by vibronic coupling to the solvent. See: ruclips.net/video/gbSQkrs49ss/видео.html at ~44 to 46 minutes. The absorptive transitions of pyrene to S1 are also forbidden: ruclips.net/video/OPRLcTzjc_8/видео.html

  • @eisvogel.1481
    @eisvogel.1481 Год назад

    Thank you very much for your explanations!😍

  • @fmoney
    @fmoney 2 года назад

    Very Interesting How can we create that photovoltaic or photodetector device that Aalto University researchers made? 132% efficiency?

    • @renem.williams9257
      @renem.williams9257 2 года назад

      Thanks. 132% Power Conversion Efficiency for solar is impossible, according to the Laws of thermodynamics, and the Shockley Queisser limit. ruclips.net/video/KsP90hT41t4/видео.html www.nrel.gov/pv/cell-efficiency.html

  • @jhansidumala
    @jhansidumala 2 года назад

    what was the software that was used to determine those parameters

    • @renem.williams9257
      @renem.williams9257 2 года назад

      The interactive graphs in this video were made with Mathematica modules, that are now freely available at Wolfram: demonstrations.wolfram.com/author.html?author=Ren%C3%A9%20M.%20Williams They are intended as useful tools to easily apply the theory.

  • @Muzeemkhankamaal
    @Muzeemkhankamaal 2 года назад

    Amazing

  • @DocLow
    @DocLow 2 года назад

    Great presentation! Thank you for sharing. I had read about Fluorine additive helping improve perovskite stability but I had not heard about the theory of strain relaxation to explain it. Its good to know Zinc and Calcium and other elements could be used too. Vert interesting.

  • @1nammashale
    @1nammashale 2 года назад

    Excellent presentation. Thank you. I have a question, in PDT why do you want to enhance the generation of triplet state with less QY. I mean what is the purpose? I am curious.

    • @renem.williams9257
      @renem.williams9257 2 года назад

      The excited triplet state can interact with ground state molecular oxygen (a triplet) and form the very reactive excited state of oxygen (called singlet oxygen). Singlet oxygen can destroy tumor cells. See ruclips.net/video/gbSQkrs49ss/видео.html

    • @1nammashale
      @1nammashale 2 года назад

      Thank you ❤️

  • @renem.williams9257
    @renem.williams9257 2 года назад

    It has been a great pleasure to help such a brilliant student to share her talent with the whole world! Flabbergasted by such splendour...

  • @srestsomay3533
    @srestsomay3533 2 года назад

    Hi Professor. Always a pleasure to see you explaining the complex perovskite chemistry in a simplified way. Thanks for the lecture. I hope you are doing well.

  • @mahsashksh1884
    @mahsashksh1884 2 года назад

    Thank you so much for your nice lecture. I have a question, how we can consider the molecular orbitals of the octahedral part of perovskites? for instance, [PbBr6]-4, the 5d is completely full, so, we need to consider 6d for interaction? if yes, what its molecular orbital will look like? Thank you, professor.

    • @renem.williams9257
      @renem.williams9257 2 года назад

      In the second perovskite lecture you can see the orbitals!!

  • @peter.a.tanner
    @peter.a.tanner 2 года назад

    I listened until 2:18 and it was enough. 1. An excited state is not an exciton (as written later accidents); 2. Dexter (not Dextrer) transfer is not double electron exchange. The orbitals are overlapping before the incident photon comes. 3. There are more than 2 theoretical frameworks for nonradiative energy transfer. 4. Forster and Dexter are not singlet and triplet energy transfer..

    • @peter.a.tanner
      @peter.a.tanner 2 года назад

      Unfortunately, this type of thinking pervades the chemical literature

    • @renem.williams9257
      @renem.williams9257 2 года назад

      1: wikipedia: “When a molecule absorbs a quantum of energy that corresponds to a transition from one molecular orbital to another molecular orbital, the resulting electronic excited state is also properly described as an exciton.” OK, excitons are mainly used in solid state physics, but sometime we want to talk to them. There are many types of excitons. I prefer using the words “excited states”. There are also many types of excited states!! 2: Thanks for helping to improve the captioning provided by Google/RUclips. I now corrected these mistakes. Dexter is often described as double electron transfer. It is also called the exchange mechanism, electron exchange. Yes, orbital overlap plays an important role here. The orbitals mediate the interaction. The transfer is triggered by the photon, the interaction is already there. 3: As written below the video; “There are two important theoretical frameworks that can be used for energy transfer: the Coulomb based Förster Resonance Energy Transfer (FRET) and the Exchange based Dexter mechanism.” There are indeed more mechanism. Even TODAY MSc students presented about energy transfer between graphene and molecules that did not follow Förster. 4: Förster is often used for singlet-singlet energy transfer. Dexter for triplets. But there are examples where both play a role at the same time, competing with each other, as I tell later-on in the video.

    • @peter.a.tanner
      @peter.a.tanner 2 года назад

      @@renem.williams9257 Thanks for quoting Wikipedia to me. That is about it.

    • @peter.a.tanner
      @peter.a.tanner 2 года назад

      @@renem.williams9257 Anyway, it's good to put science on RUclips. Keep it up

    • @lineakristensen1821
      @lineakristensen1821 2 года назад

      @@peter.a.tanner you ok mate?!

  • @StochasticCockatoo
    @StochasticCockatoo 2 года назад

    omg so relevant for clarice quantum biology

    • @renem.williams9257
      @renem.williams9257 11 месяцев назад

      Than this might interest you too: doi.org/10.34133/icomputing.0072

  • @dmajumdar2059
    @dmajumdar2059 2 года назад

    i have been looking for a detailed video on FRET for a very long time! Great to finally have one!!

  • @mohsentamtaji9130
    @mohsentamtaji9130 2 года назад

    Great talk

  • @loveall2941
    @loveall2941 2 года назад

    What is the possible commercial values of doping concentration in methyl ammonium tin triiodide perovskite solar cells?

    • @renem.williams9257
      @renem.williams9257 2 года назад

      The optimal doping percentages depend on the materials. Below 3 mol% relative to Sn (or Pb) is often optimal. Reports between 0.15% and 2.5% can be found, for Pb materials.

    • @loveall2941
      @loveall2941 2 года назад

      @@renem.williams9257 can you answer like what is the upper limit of experimentally achievable doping concentration of methyl ammonium tin triiodide as an absorber layer? Is it 3.5 x 10*18 or more?

    • @renem.williams9257
      @renem.williams9257 2 года назад

      @@loveall2941 It is not p-doping and n-doping like with silicon, it is compositional engineering. Perhaps similar to alloying of steel with carbon. You can choose the amount of dopant / alloy composition during the fabrication. More than 5% often results in segregation.

  • @yinonderee3666
    @yinonderee3666 2 года назад

    Dear Rene', if I may i have further questions. 1) in this video you focus on that orthogonality is critical for ISC but we need to satisfied another criterion that is the proximity of the energy of the T1 and the C.T orthogonal state, is that right? 2) can in that case of C.T state and T1 state be in equilibrium? or maby C.T state that is singlet and C.T that is triplet? best regards, Yinon.

    • @renem.williams9257
      @renem.williams9257 2 года назад

      The energy difference plays a role. It is basically Marcus theory, so Delta G and lamdba are important. If T1, singlet CT and triplet CT are close, equilibrium can play a role. See also video of Peter Hore on magneto reception in avian navigation. in Playlist. ruclips.net/video/FytxLiHlah4/видео.html

  • @mhd112211
    @mhd112211 2 года назад

    Cheers!

  • @yinonderee3666
    @yinonderee3666 2 года назад

    The requirement for the orthogonality of the D-A groups does not exist in the exited state?(the process is fro LE(1) to CT(1) ) so why focus on the angles in the ground state? best regards, Yinon.

    • @renem.williams9257
      @renem.williams9257 2 года назад

      Dear Yinon, it is indeed even better to look at the conformations in the excited states! Especially if we go from CT(1) to LE(3) (local triplet excited state, also called T1). In fact we have recently reported on such excited state geometries: ruclips.net/video/x-nfr7pFmcc/видео.html ruclips.net/video/FlbV6tRUlYc/видео.html doi.org/10.3390/molecules27030891

    • @ינוןדרעי-ל7ת
      @ינוןדרעי-ל7ת 2 года назад

      Thank you!

  • @harshaagrawal2473
    @harshaagrawal2473 3 года назад

    How to understand in ur absorption spectra charge transfer band is there?

    • @renem.williams9257
      @renem.williams9257 3 года назад

      For a good electron donor acceptor pair it is a new absorption band, red-shifted relative to the separate components. For instance: tetracyanoethylene (TCNE) in toluene, anisole and veratrole solvent (solvent is donor here).

  • @mohammadrahil9678
    @mohammadrahil9678 3 года назад

    Thank You Sir, for sharing such a valuable information video.

  • @alexandreteodoro6570
    @alexandreteodoro6570 3 года назад

    I was studying this topic by myself and just found this video. Thank you very much professor, it was very helpfull.

  • @mattkunq
    @mattkunq 3 года назад

    Thumbnail at 54:00

  • @MohammedIslamElshiekhElsmani
    @MohammedIslamElshiekhElsmani 3 года назад

    Interesting!!

  • @amit9837
    @amit9837 3 года назад

    Prof René M. Williams your talks are so amazing! thank you!!

  • @DanielAlejandroHeredia
    @DanielAlejandroHeredia 3 года назад

    Great lecture!!!